The Effects of 3d Admixtures on Properties of Relaxor PLZT8/65/35 Ceramics

A study of the effects of the 3d dopants Mn, Fe, Co, Ni, and Cu on relaxor behavior and other properties of the ferroelectric PLZT8/65/35(La8) ceramic compound by X-ray diffraction, electron microscopy and other techniques is reported. The complex dielectric permittivity ϵ* = ϵ′-iϵ′′ is measured in the 20–400°C range of temperature at frequencies within the range of 102 – 106 Hz. Essential changes caused by the admixtures in the behavior of dielectric permittivity with frequency and temperature are observed along with changes in the XRD SEM patterns are observed. The mechanisms of the phenomena are discussed.

EPR Study of Manganese-Doped PLZT-8/65/35 Ceramics

The electron beam induced short lived absorption in PLZT optical ceramics

Abstract The short lived absorption induced by a pulsed electron beam in the led–lanthanum–zirconate–titanate (PLZT) optical ceramics was studied. The measured absorption spectrum covers 1.1–2.9 eV energy range and consists of several strongly overlapping peaks. The rise of the absorption is delayed with respect to the excitation pulse, due to charge carrier migration before trapping at centers responsible for the absorption. The formation rate of absorption centers and decay rate of absorption depend on the photon energy. The kinetics of short lived absorption varies over spectrum and can be approximated with a stretched exponent. The stretched exponent parameters indicate that the local d…

The nature of the defect structure of solid solutions based on lead zirconate titanate (PZT): Evidence from EPR and NMR

The nature of intrinsic and impurity point defects in lead zirconate titanate (PZT) ceramics has been explored. Using electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) methods several impurity sites have been identified in the materials, including Fe3+-oxygen vacancy (VO) complex and Pb ions. Both of these centers are incorporated into the PZT lattice. The Fe3+-VO paramagnetic complex serves as a sensitive probe of the local crystalline field in the ceramic; the symmetry of this defect is roughly correlated with PZT phase diagram as composition is varied from PbTiO3 to PbZrO3. NMR spectra 207Pb in PbTiO3, PbZrO3 and PZT with iron content from 0 to 0.4 mol % showed t…

Thermo-Optical Investigation of Sodium-Bismuth Titanate Single Crystal and PLZT Ceramics

Thermal lensing in relaxor type ferroelectrics as a function of temperature has been investigated by using pulse/probe method. Enhanced thermo-optical (TO) properties had been observed in 3d elements (Cu, Co) doped PLZT ceramics and in sodium-bismuth titanate single crystals near phase transitions (PT). Comparison of TO signals for several doped PLZT materials reveals that 0.5 wt.% Cu doping is responsible for improved thermal lensing parameters interpreted by optimal light absorption, heat transfer and possible PT adjustment. TO experiments in sodium-bismuth titanate single crystals ([001] cut) show enhancement of TO properties in the region of PT and coexisting phases (rhombohedral and te…

Using the methods of radiospectroscopy (EPR, NMR) to study the nature of the defect structure of solid solutions based on lead zirconate titanate (PZT)

The nature of intrinsic and impurity point defects in lead zirconate titanate (PZT) ceramics has been explored. Using electron paramagnetic resonance (EPR), nuclear magnetic resonance (NMR), and X-ray photoelectron spectroscopy (XPS) methods, several impurity sites have been identified in the materials, including the Fe 3+ -oxygen vacancy (VO) complex and Pb ions. Both of these centers are incorporated into the PZT lattice. The Fe 3+ -V paramagnetic complex serves as a sensitive probe of the local crystal field in the ceramic; the symmetry of this defect roughly correlates with PZT phase diagram as the composition is varied from PbTiO 3 to PbZrO 3 . NMR spectra 207 Pb in PbTiO 3 , PbZrO 3 ,…

Aging and Memory Effects in PLZT 8/65/35 Ceramics Modified with 3d Transition-Metal Ions

The temperature and frequency dependencies of the dielectric susceptibility in relaxor electro-optical PLZT 8/65/35 modified with 3d transition-metal ions (Mn, Fe, Co, Ni) measured to study the aging and memory effects are reported. The studies of aging at room temperature show that 3d admixtures (Me) in PLZT 8/65/35 ceramics at small to medium concentration range (Me < 1.0 wt.%) change the depth of dispersion, the aging amplitude and the temperature range of the memory effect. At admixture concentrations Me →1.0 wt% the aging and memory effect are significantly reduced (or eliminated).The obtained results suggest that aging effects are determined by two substantial acceptor effects of the …

Electron-microscopy studies of pure and doped electrooptic PLZT ceramics

Abstract Data on chemical composition and spatial fluctuations thereof as well as fracture mode behaviour of pure and doped PLZT ceramics have been obtained.

EPR studies of Mn, Fe, Co, and Cu doped PLZT and PMN compositions

Results of Mn, Fe, Co, and Cu admixture EPR spectra studies in PLZT and PMN ceramics are discussed. The spectra of Mn, Fe, and Co ions with dominating absorption at geff = 2.0 and 4.3 are proposed due to d5 (S = 5/2) configurations (Mn2+, Fe3+, Co4+). The latter can be used as probes disclosing specific features (glass-like behaviour) of the structures. The Jahn-Teller ions (Mn3+, Fe4+, Co5+, Cu2+) are responsible for the dopant effect, e.g., the shift of the e(T) maximum to higher temperatures. The microscopic nature of differences of the dopant effect in PLZT and PMN materials and in the Mn Fe Co sequence is analyzed. [Russian Text Ignored].

Effects of Mn doping on dielectric properties of ferroelectric relaxor PLZT ceramics

This work has been supported by Latvian state research program IMIS2 .

Dielectric memory effects of (Mn, Fe, Co, Cu, Eu) doped PLZT ceramics

Abstract Dielectric memory effects—effect of thermal memory (ETM) and effect of electric field memory (EFM) have been studied in (Mn, Fe, Co, Cu, Eu) doped PLZT ceramics. The obtained results have been discussed on the assumption that the ETM and EFM depends on relaxation of domain and interphase (polar and nonpolar) boundaries influenced by changes of defects conditions at doping.