0000000000083906
AUTHOR
Antonino Laudani
Toxicological investigations in a fatal and non-fatal accident due to hydrogen sulphide (H2S)poisoning
Hydrogen sulphide (H2S) is one of the most toxic natural gas and represents a not rare cause of fatal events in workplaces. We report here a serious accidental poisoning by hydrogen sulphide inhalation involving six sailors. Three of them died while the other three survived and were transported to the emergency room. No greenish discolouration of the body, that could be a feature of these type of deaths, was observed at autopsy. Given that blood and/or urine H2S detection does not allow to discriminate if it is related to inhalation or to putrefactive processes, the determination of thiosulphate, H2S main metabolite, is decisive. The succession of fatal events reported here can be rebuilt b…
One diode circuital model of light soaking phenomena in Dye-Sensitized Solar Cells
Abstract In this work, we report on the modelling of light soaking effect on Ruthenium-based Dye Sensitized Solar cells (DSSCs). Such a phenomenon can be detected when exposing the cells at increasing hours of illumination and produces a reversible performance increase. Starting from the results obtained through the electro-optical characterization of the cells, we applied a one-diode circuital-model. Our results show a good agreement between the experimental and the simulated data, with a mean square error in the order of 10−12 and a maximum error in current lower than 0.6%. Finally such results allowed us to infer some precise trends followed by the cells main electrical parameters and of…