Author: Sylviane Mignonac

0000000000088403

AUTHOR

Sylviane Mignonac

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Palladium-Catalyzed Hydroxycarbonylation of Aryl and Vinyl Bromides by Mixed Acetic Formic Anhydride

2006

The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence of acetic anhydride and lithium formate as a carbon monoxide source has been developed. The combination of palladium(II) acetate with 1,1'-bis(diphenylphosphino)ferrocene (dppf) is an efficient catalytic system when the reaction is carried out at 120 °C.

inorganic chemicals010405 organic chemistryArylOrganic Chemistrychemistry.chemical_elementLithium formateGeneral Medicine010402 general chemistry7. Clean energy01 natural sciencesCatalysis0104 chemical sciencesCatalysischemistry.chemical_compoundAcetic anhydridechemistryFerrocenePolymer chemistryAcetic formic anhydrideOrganic chemistry[CHIM]Chemical SciencesCarbonylationComputingMilieux_MISCELLANEOUSCarbon monoxidePalladium

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