6533b7cffe1ef96bd1259b3b
RESEARCH PRODUCT
Palladium-Catalyzed Hydroxycarbonylation of Aryl and Vinyl Bromides by Mixed Acetic Formic Anhydride
Jean-claude CaillePhilippe BergerSylviane MignonacAlla Bessmernykhsubject
inorganic chemicals010405 organic chemistryArylOrganic Chemistrychemistry.chemical_elementLithium formateGeneral Medicine010402 general chemistry7. Clean energy01 natural sciencesCatalysis0104 chemical sciencesCatalysischemistry.chemical_compoundAcetic anhydridechemistryFerrocenePolymer chemistryAcetic formic anhydrideOrganic chemistry[CHIM]Chemical SciencesCarbonylationComputingMilieux_MISCELLANEOUSCarbon monoxidePalladiumdescription
The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence of acetic anhydride and lithium formate as a carbon monoxide source has been developed. The combination of palladium(II) acetate with 1,1'-bis(diphenylphosphino)ferrocene (dppf) is an efficient catalytic system when the reaction is carried out at 120 °C.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-09-11 |