0000000000088448

AUTHOR

Marcello Bitetto

0000-0003-0460-9772

showing 40 related works from this author

The crater lake of Ilamatepec (Santa Ana) volcano, El Salvador: insights into lake gas composition and implications for monitoring

2019

We here present the first chemical characterization of the volcanic gas plume issuing from the Santa Ana crater lake, a hyper-acidic crater lake (pH of − 0.2 to 2.5) in north-western El Salvador. Our results, obtained during regular surveys in 2017 and 2018 using a Multi-GAS instrument, demonstrate a hydrous gas composition (H2O/SO2 ratios from 32 to 205) and SO2 as the main sulfur species (H2S/SO2 = 0.03–0.1). We also find that gas composition evolved during our investigated period, with the CO2/SO2 ratio decreasing by one order of magnitude from March 2017 (37.2 ± 9.7) to November 2018 (< 3). This compositional evolution toward more magmatic (SO2-rich) compositions is interpreted in the c…

ratio010504 meteorology & atmospheric sciences/SOGeochemistry2FluxContext (language use)010502 geochemistry & geophysics01 natural sciencesVolcanic gas plumeGeochemistry and PetrologyCrater lakeWet volcanoGas compositionPrecipitation0105 earth and related environmental sciencesgeographygeography.geographical_feature_categoryPlumeSanta Ana volcanoCOVolcanoVolume (thermodynamics)Crater lakeGas scrubbingGeologyMulti-GAS
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Ultraviolet Imaging of Volcanic Plumes: A New Paradigm in Volcanology

2017

Ultraviolet imaging has been applied in volcanology over the last ten years or so. This provides considerably higher temporal and spatial resolution volcanic gas emission rate data than available previously, enabling the volcanology community to investigate a range of far faster plume degassing processes, than achievable hitherto. To date this has covered rapid oscillations in passive degassing through conduits and lava lakes, as well as puffing and explosions, facilitating exciting connections to be made for the first time between previously rather separate sub disciplines of volcanology. Firstly, there has been corroboration between geophysical and degassing datasets at &amp;asymp; 1 Hz e…

geographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesotherVolcanology010502 geochemistry & geophysicsmedicine.disease_cause01 natural sciencesAstrobiologyVolcano13. Climate actionmedicineGeologyUltraviolet0105 earth and related environmental sciences
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Mafic magma feeds degassing unrest at Vulcano Island, Italy

2022

AbstractThe benign fuming activity of dormant volcanoes is punctuated by phases of escalating degassing activity that, on some occasions, ultimately prelude to eruption. However, understanding the drivers of such unrest is complicated by complex interplay between magmatic and hydrothermal processes. Some of the most comprehensively characterised degassing unrest have recently been observed at La Fossa cone on Vulcano Island, but whether or not these episodes involve new, volatile-rich ascending magma remains debated. Here, we use volcanic gas measurements, in combination with melt inclusion information, to propose that heightened sulphur dioxide flux during the intense fall 2021 La Fossa un…

Vulcano unrest gasesGeneral Earth and Planetary SciencesGeneral Environmental Science
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Shallow magma dynamics at open-vent volcanoes tracked by coupled thermal and SO2 observations

2022

Open-vent volcanic activity is typically sustained by ascent and degassing of shallow magma, in which the rate of magma supply to the upper feeding system largely exceeds the rate of magma eruption. Such unbalance between supplied (input) and erupted (output) magma rates is thought to result from steady, degassing-driven, convective magma overturning in a shallow conduit/feeding dyke. Here, we characterize shallow magma circulation at Stromboli volcano by combining independent observations of heat (Volcanic Radiative Power; via satellite images) and gas (SO2, via UV camera) output in a temporal interval (from August 1, 2018 to April 30, 2020) encompassing the summer 2019 effusive eruption a…

Geophysicseffusive phaseSpace and Planetary ScienceGeochemistry and Petrologymagma budgetEarth and Planetary Sciences (miscellaneous)UV cameraStromboli volcanomild-explosive activityMODIS dataEarth and Planetary Science Letters
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First in-situ measurements of plume chemistry at mount garet volcano, island of gaua (Vanuatu)

2020

Recent volcanic gas compilations have urged the need to expand in-situ plume measurements to poorly studied, remote volcanic regions. Despite being recognized as one of the main volcanic epicenters on the planet, the Vanuatu arc remains poorly characterized for its subaerial emissions and their chemical imprints. Here, we report on the first plume chemistry data for Mount Garet, on the island of Gaua, one of the few persistent volatile emitters along the Vanuatu arc. Data were collected with a multi-component gas analyzer system (multi-GAS) during a field campaign in December 2018. The average volcanic gas chemistry is characterized by mean molar CO2/SO2, H2O/SO2, H2S/SO2 and H2/SO2 ratios …

010504 meteorology & atmospheric sciencesvolcanic gas compositionsGeochemistryFlux010502 geochemistry & geophysicslcsh:Technology01 natural scienceslcsh:ChemistryVanuatu[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/VolcanologyGeneral Materials ScienceGas composition[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces environmentlcsh:QH301-705.5Instrumentation0105 earth and related environmental sciencesFluid Flow and Transfer Processesgeographygeography.geographical_feature_categorySubductionlcsh:TProcess Chemistry and TechnologyGeneral Engineeringlcsh:QC1-999Gas analyzerComputer Science ApplicationsPlumelcsh:Biology (General)lcsh:QD1-999Mount GaretVolcanolcsh:TA1-2040SubaerialPeriod (geology)volatile fluxeslcsh:Engineering (General). Civil engineering (General)GauaGaua Mount Garet Multi-GAS Vanuatu Volatile fluxes Volcanic gas compositionslcsh:PhysicsMulti-GAS
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Rapid shifting of a deep magmatic source at Fagradalsfjall volcano, Iceland

2022

AbstractRecent Icelandic rifting events have illuminated the roles of centralized crustal magma reservoirs and lateral magma transport1–4, important characteristics of mid-ocean ridge magmatism1,5. A consequence of such shallow crustal processing of magmas4,5 is the overprinting of signatures that trace the origin, evolution and transport of melts in the uppermost mantle and lowermost crust6,7. Here we present unique insights into processes occurring in this zone from integrated petrologic and geochemical studies of the 2021 Fagradalsfjall eruption on the Reykjanes Peninsula in Iceland. Geochemical analyses of basalts erupted during the first 50 days of the eruption, combined with associate…

REYKJANES PENINSULA3705 GeologySOLUBILITY/140/128/140/125ERUPTION/704/2151/431/132Multidisciplinaryiceland volcanism volatiles Fagradalsfjall/704/2151/213/704/2151/598PRESSURESarticleCONSTRAINTS37 Earth SciencesEVOLUTION3703 GeochemistryINSIGHTS[SDU]Sciences of the Universe [physics]MIDOCEAN RIDGE BASALTSOLIVINE/704/2151/2093706 GeophysicsGENERATION
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Ground deformation reveals the scale-invariant conduit dynamics driving explosive basaltic eruptions

2021

The mild activity of basaltic volcanoes is punctuated by violent explosive eruptions that occur without obvious precursors. Modelling the source processes of these sudden blasts is challenging. Here, we use two decades of ground deformation (tilt) records from Stromboli volcano to shed light, with unprecedented detail, on the short-term (minute-scale) conduit processes that drive such violent volcanic eruptions. We find that explosive eruptions, with source parameters spanning seven orders of magnitude, all share a common pre-blast ground inflation trend. We explain this exponential inflation using a model in which pressure build-up is caused by the rapid expansion of volatile-rich magma ri…

010504 meteorology & atmospheric sciencesExplosive materialScienceGeneral Physics and AstronomyMagnitude (mathematics)VolcanologyDeformation (meteorology)010502 geochemistry & geophysics01 natural sciencestiltGeneral Biochemistry Genetics and Molecular BiologyArticlePhysics::Geophysicsground deformationElectrical conduitOrders of magnitude (specific energy)ground deformation conduit dynamics early warningAstrophysics::Solar and Stellar AstrophysicsStromboli0105 earth and related environmental sciencesgeographyMultidisciplinarygeography.geographical_feature_categoryExplosive eruptionQGeneral ChemistryGeophysicsVolcanoMagmaSeismologyGeologyNature Communications
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Flussi di evasione marina del mercurio elementare gassoso (Hg0) nell’atmosfera della Rada di Augusta

2015

Il mercurio (Ilg) è uno dei principali inquinanti emessi in atmosfera. La sua complessità geochimica, unitamente alla tossicità c agli effetti persistenti della sua presenza nell’ecosistema terrestre, lo hanno inserito nella lista delle priorità di un numero sempre crescente di accordi internazionali rivolti alla tutela ambientale e della stiline umana (The Arctic- Monitoring and Assessment Program, AMAR, United Nations - Economie Commission for Europe: Ileavy Metals Protocol, UN- ECE, The Helsinki Commission, IIELCOM, la convenzione OSPAR). I progressi raggiunti neH’ullimo decennio sullo studio del Hg come ‘global poi Intani '(Pirrone et al.. 2001; Hedgecock et al, 2000: Paeyna et al, 2006…

mercurio atmosfera inquinamentoSettore GEO/08 - Geochimica E Vulcanologia
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Spatially resolved SO2 flux emissions from Mt Etna

2016

We report on a systematic record of SO2 flux emissions from individual vents of Etna volcano (Sicily), which we obtained using a permanent UV camera network. Observations were carried out in summer 2014, a period encompassing two eruptive episodes of the New South East Crater (NSEC) and a fissure-fed eruption in the upper Valle del Bove. We demonstrate that our vent-resolved SO2 flux time series allow capturing shifts in activity from one vent to another and contribute to our understanding of Etna's shallow plumbing system structure. We find that the fissure eruption contributed ~50,000 t of SO2 or ~30% of the SO2 emitted by the volcano during the 5 July to 10 August eruptive interval. Acti…

event.disaster_typegeographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesSpatially resolvedFlux010502 geochemistry & geophysics01 natural sciencesVolcanic GasesGeophysicsCamera networkVolcanoImpact crater13. Climate actionSouth eastGeneral Earth and Planetary ScienceseventSystem structureGeologySeismology0105 earth and related environmental sciencesGeophysical Research Letters
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The structure of a hydrothermal system from an integrated geochemical, geophysical, and geological approach: The Ischia Island case study

2011

The complexity of volcano-hosted hydrothermal systems is such that thorough characterization requires extensive and interdisciplinary work. We use here an integrated multidisciplinary approach, combining geological investigations with hydrogeochemical and soil degassing prospecting, and resistivity surveys, to provide a comprehensive characterization of the shallow structure of the southwestern Ischia's hydrothermal system. We show that the investigated area is characterized by a structural setting that, although very complex, can be schematized in three sectors, namely, the extra caldera sector (ECS), caldera floor sector (CFS), and resurgent caldera sector (RCS). This contrasted structura…

GeophysicsGeochemistry and PetrologyElectrical resistivity and conductivityGeochemistryProspectingCalderaFluid circulationElectrical resistivity tomographyGeomorphologyHydrothermal circulationGeologyGeochemistry, Geophysics, Geosystems
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Il Mercurio nel suolo e in ambiente terrestre

2015

Le interazioni del Hg con l'ambiente costituiscono il ciclo geochimico di questo elemento che si esplica per mezzo di complessi processi fisico-chimici differenti per ciascun comparto geochimico. Si stima che circa i due terzi del mercurio presente in ambiente sia stato prodotto durante il ventesimo secolo, e che il carico di mercurio immesso attualmente sia aumentato di circa 3 volte rispetto agli inizi del 1900 (Mason et al.. 1994). Il comparto ambientale certamente più coinvolto dalle emissioni di mercurio è quello atmosferico, da cui poi l’elemento si diffonde anche negli altri comparti, suolo e sedimenti compresi (Filzgerald &amp; Clarkson, 1991). L’Atmosfera costituisce un importante …

Mercurio Augusta inquinamento biomonitoraggioSettore GEO/08 - Geochimica E Vulcanologia
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Elevated CO2 emissions during magmatic-hydrothermal degassing at Awu Volcano, Sangihe Arc, Indonesia

2020

Awu is a remote and little known active volcano of Indonesia located in the northern part of Molucca Sea. It is the northernmost active volcano of the Sangihe arc with 18 eruptions in less than 4 centuries, causing a cumulative death toll of 11,048. Two of these eruptions were classified with a Volcanic Explosivity Index (VEI) of 4. Since 2004, a lava dome has occupied the centre of Awu crater, channelling the fumarolic gas output along the crater wall. A combined Differential Optical Absorption Spectroscopy (DOAS) and Multi-component Gas Analyzer System (Multi-GAS) study highlight a relatively small SO2 flux (13 t/d) sustained by mixed magmatic&ndash

lcsh:GeologyCO2 emissionlcsh:QE1-996.5[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/VolcanologyAwu volcano CO2 emission Sangihe arc Volcanic degassingAwu volcano[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces environmentvolcanic degassingCO<sub>2</sub> emissionSangihe arc
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Spatio-temporal changes in degassing behavior at Stromboli volcano derived from two co-exposed SO2 camera stations

2022

Improving volcanic gas monitoring techniques is central to better understanding open-vent, persistently degassing volcanoes. SO2 cameras are increasingly used in volcanic gas studies, but observations are commonly limited to one single camera alone viewing the volcanic plume from a specific viewing direction. Here, we report on high frequency (0.5 Hz) systematic measurements of the SO2 flux at Stromboli, covering a 1-year long observation period (June 2017-June 2018), obtained from two permanent SO2 cameras using the same automated algorithm, but imaging the plume from two different viewing directions. Our aim is to experimentally validate the robustness of automatic SO2 camera for volcano …

Stromboli (Italy)volcano monitoringSO2 fluxGeneral Earth and Planetary SciencesUV cameraStrombolian activityvolcanic degassingFrontiers in Earth Science
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Sulfur Degassing From Steam-Heated Crater Lakes: El Chichón (Chiapas, Mexico) and Víti (Iceland)

2018

The composition of the gases released by El Chichón (Chiapas, Mexico) and Víti (Askja volcano, Iceland) volcanic lakes is examined by Multi-GAS for the first time. Our results demonstrate that H2S and SO2 are degassed by these pH 2–3 lakes. We find higher CO2/H2S and H2/H2S ratios in the lakes' emissions (31–5,685 and 0.6–35, respectively) than in the fumarolic gases feeding the lakes (13–33 and 0.08–0.5, respectively), evidencing that only a fraction (0.2–5.4% at El Chichón) of the H2S(g) contributed by the subaquatic fumaroles ultimately reaches the atmosphere. At El Chichón, we estimate a H2S output from the crater lake of 0.02–0.06 t/day. Curiously, SO2 is also detected at trace levels …

volcanic lake010504 meteorology & atmospheric sciencesGeochemistrychemistry.chemical_elementVíti010502 geochemistry & geophysicssulfur degassing01 natural sciencesSulfurEl ChichónGeophysicsImpact craterchemistryGeneral Earth and Planetary SciencesGeophysicEarth and Planetary Sciences (all)Multi-GASGeology0105 earth and related environmental sciencesGeophysical Research Letters
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Exploring the explosive‐effusive transition using permanent ultra‐violet cameras

2017

Understanding the mechanisms that cause effusive eruptions is the key to mitigating their associated hazard. Here we combine results from permanent ultraviolet (UV) cameras, and from other geophysical observations (seismic very long period, thermal, and infrasonic activity), to characterize volcanic SO2 flux regime in the period prior, during, and after Stromboli's August–November 2014 effusive eruption. We show that, in the 2 months prior to effusion onset, the SO2 flux levels are 2 times average level. We explain this anomalously high SO2 regime as primarily determined by venting of rapidly rising, pressurized SO2-rich gas pockets produced by strombolian explosions being more frequent and…

effusive eruptionVolcanic degassingStrombolian activitySettore GEO/08 - Geochimica E Vulcanologia
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Compositional measurement of gas emissions in the Eastern Carpathians (Romania) using the Multi-GAS instrument: Approach for in situ data gathering a…

2022

The Multi-GAS, a robust and low-cost instrument for real-time in-situ gas measurements, has previously been used mainly for compositional measurements of active volcanic plumes. Here we demonstrate novel use of a specially designed Multi-GAS instrument adapted to low temperature degassing areas. We performed compositional measurements in the Eastern Carpathians on dry and bubbling gas emissions using a sensor kit that allows measurement of CO2, CH4 and H2S (three major components of low-temperature hydrothermal/volcanic manifestations). Our results demonstrate good agreement between Multi-GAS measurements and independently obtained CO2 concentrations from gas chromatography. We also provide…

In-situ compositional measurementsCO2-rich gas emissionsGeochemistry and PetrologyEastern CarpathiansEconomic GeologyCO2Multi-GAS
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Escalating CO2 degassing at the Pisciarelli fumarolic system, and implications for the ongoing Campi Flegrei unrest

2019

Abstract This short communication aims at providing an updated report on degassing activity and ground deformation variations observed during the ongoing (2012–2019) Campi Flegrei caldera unrest, with a particular focus on Pisciarelli, currently its most active fumarolic field. We show that the CO2 flux from the main Pisciarelli fumarolic vent (referred as “Soffione”) has increased by a factor > 3 since 2012, reaching in 2018–2019 levels (>600 tons/day) that are comparable to those typical of a medium-sized erupting arc volcano. A substantial widening of the degassing vents and bubbling pools, and a further increase in CO2 concentrations in ambient air (up to 6000 ppm), have also been detec…

event.disaster_typegeographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesCo2 fluxInduced seismicityUnrest010502 geochemistry & geophysics01 natural sciencesGas monitoringAmbient airVolcanic GasesGeophysicsVolcanoGeochemistry and PetrologyCalderaeventvolcanic gases Campi FlegreiPetrologyGeology0105 earth and related environmental sciences
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In-situ analysis of the gas-emissions of the Eastern Carpathians (Romania) using the Multi-Gas instrument

2019

The Multi-Gas instrument is an important tool for the investigations and monitoring of volcanic systems world- wide, because it can be easily placed on a volcano and can provide real-time data on the compositional changes of the fluids that are released (Aiuppa et al., 2005, Shinohara et al., 2005). We used a specially designed Multi-Gas to gather in situ compositional information about low-temperature, CO2-rich gases, emerging from different manifestations like dry gas emissions (mofettes), bubbling pools and springs. The instrument is equipped with two IR sensors for CO2 (0-100%) and CH4 (0-7%) and one electrochemical sensor for H2S (0-200 ppm). The Multi-Gas was used during several field…

Multi-Gas instrument CO2 and CH4Settore GEO/08 - Geochimica E Vulcanologia
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Volcanic CO2 tracks the incubation period of basaltic paroxysms

2021

Description

BasaltgeographyEarth Environmental Ecological and Space SciencesMultidisciplinarygeography.geographical_feature_categoryGeochemistrySciAdv r-articlesGeologyIncubation periodGeochemistrybasaltic paroxysms CO2 fluxesVolcanovolcanic gasesGeologyResearch Article
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Combined ground and aerial measurements resolve vent-specific gas fluxes from a multi-vent volcano

2020

Volcanoes with multiple summit vents present a methodological challenge for determining vent-specific gas emissions. Here, using a novel approach combining multiple ultraviolet cameras with synchronous aerial measurements, we calculate vent-specific gas compositions and fluxes for Stromboli volcano. Emissions from vent areas are spatially heterogeneous in composition and emission rate, with the central vent area dominating passive emissions, despite exhibiting the least explosive behaviour. Vents exhibiting Strombolian explosions emit low to negligible passive fluxes and are CO2-dominated, even during passive degassing. We propose a model for the conduit system based on contrasting rheologi…

010504 meteorology & atmospheric sciencesScienceGeneral Physics and AstronomyVolcanology010502 geochemistry & geophysics01 natural sciencesGeneral Biochemistry Genetics and Molecular BiologyArticleStromboliPetrologylcsh:Science0105 earth and related environmental sciencesExplosive behaviourgeographyMultidisciplinarygeography.geographical_feature_categoryQNatural hazardsGas emissionsGeneral ChemistryStrombolian eruptionPlumeOutgassingVolcanoConduit systemvolcanic gasesEnvironmental sciencelcsh:Q
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The sea–air exchange of mercury (Hg) in the marine boundary layer of the Augusta basin (southern Italy): Concentrations and evasion flux

2013

Abstract The first attempt to systematically investigate the atmospheric mercury (Hg) in the MBL of the Augusta basin (SE Sicily, Italy) has been undertaken. In the past the basin was the receptor for Hg from an intense industrial activity which contaminated the bottom sediments of the Bay, making this area a potential source of pollution for the surrounding Mediterranean. Three oceanographic cruises have been thus performed in the basin during the winter and summer 2011/2012, where we estimated averaged Hg atm concentrations of about 1.5 ± 0.4 (range 0.9–3.1) and 2.1 ± 0.98 (range 1.1–3.1) ng m −3 for the two seasons, respectively. These data are somewhat higher than the background Hg atm …

Mediterranean climatePollutionBiogeochemical cycleEnvironmental EngineeringMercury evasion flux Atmospheric mercury concentrations Gaseous elemental mercury Sea–air evasion Marine boundary layer Augusta basinHealth Toxicology and Mutagenesismedia_common.quotation_subjectchemistry.chemical_elementStructural basinFlux (metallurgy)Sea airEnvironmental ChemistrySeawatermedia_commonAir PollutantsAtmospherePublic Health Environmental and Occupational HealthMercuryGeneral MedicineGeneral ChemistryPollutionMercury (element)OceanographyItalychemistryEnvironmental scienceSeasonsBayWater Pollutants ChemicalEnvironmental MonitoringChemosphere
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First simultaneous mercury and major volatiles characterization of atmospheric hydrothermal emissions at the Pisciarelli's fumarolic system (Campi Fl…

2020

Abstract Hydrothermal systems with active surface expressions are important natural source of atmospheric mercury. Here we report on the first simultaneous assessment of gaseous elemental mercury (GEM) and major volatiles (H2S and CO2) fluxes from the fumarolic system of Pisciarelli, currently the most active at the Campi Flegrei caldera (CFc), Naples (Italy). This was achieved via a GPS-synchronized Lumex and MultiGAS survey which extends similar investigations reported elsewhere. GEM concentrations measured in the fumarolic emissions were consistently above background air level close to the degassing area (mean ~ 8 ± 3 ng m−3 on average) and ranged up to 12,000 ng m−3. Our data evidenced …

geographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesMineralogychemistry.chemical_elementAtmospheric dispersion modeling010502 geochemistry & geophysics01 natural sciencesHydrothermal circulationFumarolePlumeMercury (element)GeophysicsFlux (metallurgy)VolcanochemistryGeochemistry and PetrologyCalderaGeology0105 earth and related environmental sciencesJournal of Volcanology and Geothermal Research
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Ultraviolet imaging of volcanic plumes: A new paradigm in volcanology

2017

Ultraviolet imaging has been applied in volcanology over the last ten years or so. This provides considerably higher temporal and spatial resolution volcanic gas emission rate data than available previously, enabling the volcanology community to investigate a range of far faster plume degassing processes than achievable hitherto. To date, this has covered rapid oscillations in passive degassing through conduits and lava lakes, as well as puffing and explosions, facilitating exciting connections to be made for the first time between previously rather separate sub-disciplines of volcanology. Firstly, there has been corroboration between geophysical and degassing datasets at ≈1 Hz, expeditin…

volcanic plumes010504 meteorology & atmospheric sciencesLavaEarth scienceFlow (psychology)010502 geochemistry & geophysicsmedicine.disease_cause01 natural sciencesVolcanic plumeInterdisciplinary volcanology; Ultraviolet cameras; Volcanic plumes; Earth and Planetary Sciences (all)medicineinterdisciplinary volcanology0105 earth and related environmental sciencesgeographygeography.geographical_feature_categoryultraviolet cameraslcsh:QE1-996.5Gas releaseVolcanologyGeophysicsPlumelcsh:GeologyDynamic modelsVolcano13. Climate actionGeneral Earth and Planetary SciencesEarth and Planetary Sciences (all)GeologyUltravioletUltraviolet camera
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Dynamics of outgassing and plume transport revealed by proximal Unmanned Aerial System (UAS) measurements at Volcán Villarrica, Chile

2019

Volcanic gas emissions are intimately linked to the dynamics of magma ascent and outgassing, and, on geological timescales, constitute an important source of volatiles to the Earth's atmosphere. Measurements of gas composition and flux are therefore critical to both volcano monitoring and to determining the contribution of volcanoes to global geochemical cycles. However, significant gaps remain in our global inventories of volcanic emissions, (particularly for CO2, which requires proximal sampling of a concentrated plume) for those volcanoes where the near‐vent region is hazardous or inaccessible. Unmanned Aerial Systems (UAS) provide a robust and effective solution to proximal sampling of …

Unmanned Aerial System010504 meteorology & atmospheric sciencessub-05dronevolcanic emissions010502 geochemistry & geophysicsAtmospheric sciences01 natural sciencesAtmosphereImpact craterGeochemistry and PetrologyGas composition0105 earth and related environmental sciencesgeographygeography.geographical_feature_categorydegassingunmanned aerial systemPlumeOutgassingGeophysicsVolcanoMagmaVillarricaCompositional dataGeology
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A CO2-gas precursor to the March 2015 Villarrica volcano eruption

2017

We present here the first volcanic gas compositional time-series taken prior to a paroxysmal eruption of Villarrica volcano (Chile). Our gas plume observations were obtained using a fully autonomous Multi-component Gas Analyser System (Multi-GAS) in the 3 month-long phase of escalating volcanic activity that culminated into the 3 March 2015 paroxysm, the largest since 1985. Our results demonstrate a temporal evolution of volcanic plume composition, from low CO$_2$/SO$_2$ ratios (0.65-2.7) during November 2014-January 2015 to CO$_2$/SO$_2$ ratios up to ≈ 9 then after. The H$_2$O/CO$_2$ ratio simultaneously declined to &lt;38 in the same temporal interval. We use results of volatile saturatio…

volcanic gaseGeochemistry and Petrologyvolcanic gasesVillarrica volcanolava lakelava lakesmulti-GASprecursor CO2/SO2variationGeophysicprecursor CO2/SO2 variations
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The fumarolic CO2 output from Pico do Fogo volcano (Cape Verde)

2020

The Pico do Fogo volcano, in the Cape Verde Archipelago off the western coasts of Africa, has been the most active volcano in the Macaronesia region in the Central Atlantic, with at least 27 eruptions during the last 500 years. Between eruptions fumarolic activity has been persisting in its summit crater, but limited information exists for the chemistry and output of these gas emissions. Here, we use the results acquired during a field survey in February 2019 to quantify the quiescent summit fumaroles' volatile output for the first time. By combining measurements of the fumarole compositions (using both a portable Multi-GAS and direct sampling of the hottest fumarole) and of the SO2 flux (u…

event.disaster_typeCape VerdeCO2 outputgeographyGEO/07 - PETROLOGIA E PETROGRAFIAgeography.geographical_feature_categoryPico do Fogo volcanoDirect samplingGeochemistryCape Verde CO2 output Pico do Fogo volcano Volcani gasesFluxGeology010502 geochemistry & geophysics01 natural sciencesFumaroleVolcanic GasesCape verdeVolcani gaseVolcanoImpact craterGEO/08 - GEOCHIMICA E VULCANOLOGIAArchipelagoGeneral Earth and Planetary Sciencesevent0105 earth and related environmental sciencesItalian Journal of Geosciences
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Insights Into the Mechanisms of Phreatic Eruptions From Continuous High Frequency Volcanic Gas Monitoring: Rincón de la Vieja Volcano, Costa Rica

2019

OVSICORI Understanding the trigger mechanisms of phreatic eruptions is key to mitigating the effects of these hazardous but poorly forecastable volcanic events. It has recently been established that high-rate volcanic gas observations are potentially very suitable to identifying the source processes driving phreatic eruptions, and to eventually detecting precursory changes prior to individual phreatic blasts. In February-May 2017, we deployed a Multi-GAS instrument to continuously monitor gas concentrations in the crater lake plume of Rincón de la Vieja, a remote and poorly monitored active volcano in Costa Rica, site of frequent phreatic/phreatomagmatic eruptions. Forty-two phreatic/phreat…

Costa RicaVOLCANOES010504 meteorology & atmospheric sciencesGeochemistryGASES010502 geochemistry & geophysics01 natural sciencesVOLCANIC ERUPTIONSHydrothermal circulationVolcanic GasesTURRIALBA VOLCANO NATIONAL PARK (COSTA RICA)Crater lakePhreatomagmatic eruptioneventERUPCIONES VOLCÁNICASPARQUE NACIONAL VOLCÁN TURRIALBA (COSTA RICA)lcsh:ScienceRincón de la ViejaVolcanic gasesPhreatic0105 earth and related environmental sciencesevent.disaster_typegeographygeography.geographical_feature_categoryPhreatic eruptionPlumeVolcanoVOLCANEScrater lakesCrater lakeGeneral Earth and Planetary Scienceslcsh:QPhreatic eruptionMulti-GASGeologyFrontiers in Earth Science
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Dukono, the predominant source of volcanic degassing in Indonesia, sustained by a depleted Indian-MORB

2017

Co-auteur étranger; International audience; Located on Halmahera island, Dukono is among the least known volcanoes in Indonesia. A compilation of the rare available reports indicates that this remote and hardly accessible volcano has been regularly in eruption since 1933, and has undergone nearly continuous eruptive manifestation over the last decade. The first study of its gas emissions, presented in this work, highlights a huge magmatic volatile contribution into the atmosphere, with an estimated annual output of about 290 kt of SO2, 5000 kt of H2O, 88 kt of CO2, 5 kt of H2S and 7 kt of H2. Assuming these figures are representative of the long-term continuous eruptive activity, then Dukon…

010504 meteorology & atmospheric sciencesDepleted mantle sourceLavaEarth sciencedegassing budget[ SDU.STU.VO ] Sciences of the Universe [physics]/Earth Sciences/Volcanology010502 geochemistry & geophysics01 natural sciencesMantle (geology)Geochemistry and Petrology[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistryevolution[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/VolcanologyDukono VolcanoSedimentologyComputingMilieux_MISCELLANEOUSMagma source0105 earth and related environmental sciencesDukono volcanogeographygeography.geographical_feature_categorySubductionGas emissionsmagma source evolution[ SDU.STU.GC ] Sciences of the Universe [physics]/Earth Sciences/GeochemistryVolcanodepleted mantle sourceDegassing budget13. Climate actionGeology
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Exploring the explosive-effusive transition using permanent ultraviolet cameras

2017

Understanding the mechanisms that cause effusive eruptions is the key to mitigating their associated hazard. Here, we combine results from permanent ultra-violet (UV) cameras, and from other geophysical observations (seismic very long period, thermal, and infrasonic activity), to characterize volcanic SO2 flux regime in the period prior, during, and after Stromboli's August-November 2014 effusive eruption. We show that, in the two months prior to effusion onset, the SO2 flux levels are two times average level. We explain this anomalously high SO2 regime as primarily determined by venting of rapidly rising, pressurized SO2-rich gas pockets, produced by strombolian explosions being more frequ…

event.disaster_typegeographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesExplosive materialUltra violetGeophysics010502 geochemistry & geophysics01 natural sciencesStrombolian eruptionVolcanic GasesGeophysicsEffusive eruptionFlux (metallurgy)VolcanoSpace and Planetary ScienceGeochemistry and PetrologyMagmaEarth and Planetary Sciences (miscellaneous)eventPetrologyGeology0105 earth and related environmental sciencesJournal of Geophysical Research: Solid Earth
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Etna International Training School of Geochemistry. Science meets Practice

2019

Also this year, the “Etna International Training School of Geochemistry. Science meets practice” took place at Mt. Etna, now in its fourth edition. The school was hosted in the historical Volcanological Observatory “Pizzi Deneri”, one of the most important sites of the INGV - Osservatorio Etneo for geochemical and geophysical monitoring. Mount Etna, located in eastern Sicily, is the largest active volcano in Europe and one of the most intensely degassing volcanoes of the world [Allard et al., 1991; Gerlach, 1991]. Mt Etna emits about 1.6 % of global H2O fluxes from arc volcanism [Aiuppa et al., 2008] and 10 % of global average volcanic emission of CO2 and SO2 [D’Alessandro et al., 1997; Cal…

Mt. Etna Geochemistry Volcanology Remote SensingSettore GEO/08 - Geochimica E Vulcanologia
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BVLOS UAS Operations in Highly-Turbulent Volcanic Plumes.

2020

Long-range, high-altitude Unoccupied Aerial System (UAS) operations now enable in-situ measurements of volcanic gas chemistry at globally-significant active volcanoes. However, the extreme environments encountered within volcanic plumes present significant challenges for both air frame development and in-flight control. As part of a multi-disciplinary field deployment in May 2019, we flew fixed wing UAS Beyond Visual Line of Sight (BVLOS) over Manam volcano, Papua New Guinea, to measure real-time gas concentrations within the volcanic plume. By integrating aerial gas measurements with ground- and satellite-based sensors, our aim was to collect data that would constrain the emission rate of …

gas sensingMeteorologyFlight operationslcsh:Mechanical engineering and machineryUAVBVLOSlcsh:QA75.5-76.95Volcanic GasesArtificial Intelligenceeventlcsh:TJ1-1570Original Researchevent.disaster_typeRobotics and AIgeographygeography.geographical_feature_categoryplumeTurbulenceaerial roboticManamNew guineaComputer Science ApplicationsPlumeaerial robotic Volcanic degassing aerial robotic gas sensing Manam plume UAV unmanned aircraft system (UAS) volcanovolcanoVolcanoVolcanic plumeSoftware deploymentEnvironmental scienceunmanned aircraft system (UAS)lcsh:Electronic computers. Computer scienceFrontiers in robotics and AI
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Changes in SO2 Flux Regime at Mt. Etna Captured by Automatically Processed Ultraviolet Camera Data

2019

We used a one-year long SO2 flux record, which was obtained using a novel algorithm for real-time automatic processing of ultraviolet (UV) camera data, to characterize changes in degassing dynamics at the Mt. Etna volcano in 2016. These SO2 flux records, when combined with independent thermal and seismic evidence, allowed for capturing switches in activity from paroxysmal explosive eruptions to quiescent degassing. We found SO2 fluxes 1.5&#8722;2 times higher than the 2016 average (1588 tons/day) during the Etna&#8217;s May 16&#8722;25 eruptive paroxysmal activity, and mild but detectable SO2 flux increases more than one month before its onset. The SO2 flux typically peaked during a lava fo…

010504 meteorology & atmospheric sciencesLava2SO<sub>2</sub> fluxesAutomatic processing010502 geochemistry & geophysicsAtmospheric sciencesmedicine.disease_causeUV Camerafluxe01 natural sciencesFlux (metallurgy)Thermalmedicinelcsh:Scienceexplosive basaltic volcanism0105 earth and related environmental sciencesSOExplosive eruptionEtna VolcanofluxesEtna volcanoGeneral Earth and Planetary Scienceslcsh:QEtna volcano; Explosive basaltic volcanism; SO; 2; fluxes; UV cameraGeologyUltravioletRemote Sensing
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The Magmatic Gas Signature of Pacaya Volcano, With Implications for the Volcanic CO2Flux From Guatemala

2018

Pacaya volcano in Guatemala is one of the most active volcanoes of the Central American Volcanic Arc (CAVA). However, its magmatic gas signature and volatile output have received little attention to date. Here, we present novel volcanic gas information from in-situ (Multi-GAS) and remote (UV camera) plume observations in January 2016. We find in-plume H2O/SO2 and CO2/SO2 ratios of 2-20 and 0.6-10.5, and an end-member magmatic gas signature of 80.5 mol. % H2O, 10.4 mol. % CO2, and 9.0 mol. % SO2. The SO2 flux is evaluated at 885 ± 550 tons/d. This, combined with co-acquired volcanic plume composition, leads to H2O and CO2 fluxes of 2,230 ± 1,390 and 700 ± 440, and a total volatile flux of ∼3…

event.disaster_typePacayageographyvolcanic gasegeography.geographical_feature_category010504 meteorology & atmospheric sciencescarbon isotopefluid inclusionCO2 fluxeGeochemistry010502 geochemistry & geophysics01 natural sciencesVolcanic GasesCO2fluxeGeophysicsVolcanoGeochemistry and PetrologyIsotopes of carbonFluid inclusionsevent3He/4HeSignature (topology)GeophysicGeology0105 earth and related environmental sciences
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Volcanic activity and gas emissions along the South Sandwich Arc

2020

AbstractThe South Sandwich Volcanic Arc is one of the most remote and enigmatic arcs on Earth. Sporadic observations from rare cloud-free satellite images—and even rarer in situ reports—provide glimpses into a dynamic arc system characterised by persistent gas emissions and frequent eruptive activity. Our understanding of the state of volcanic activity along this arc is incomplete compared to arcs globally. To fill this gap, we present here detailed geological and volcanological observations made during an expedition to the South Sandwich Islands in January 2020. We report the first in situ measurements of gas chemistry, emission rate and carbon isotope composition from along the arc. We sh…

geographygeography.geographical_feature_category010504 meteorology & atmospheric sciencesVolcanic arcSubductionGeochemistryCrust010502 geochemistry & geophysics01 natural sciencesSouth Sandwich Volcanic Arc Volcanic activity Volcanic gas emissionsHydrothermal circulationFumaroleVolcanoGeochemistry and PetrologyIsotopes of carbonArc systemGeology0105 earth and related environmental sciences
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Mercury’s Distribution in the Atmosphere, Soils and Plants of the Active Hydrothermal Area of Nisyros (Greece).

2014

biomonitoringNisyroMercuryMercury; Nisyros; biomonitoring
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Volcanic Gas Emissions Along the Colombian Arc Segment of the Northern Volcanic Zone (CAS-NVZ): Implications for volcano monitoring and volatile budg…

2019

Studying spatial and temporal trends in volcanic gas compositions and fluxes is crucial both to volcano monitoring and to constrain the origin and recycling efficiency of volatiles at active convergent margins. New volcanic gas compositions and volatile fluxes are here reported for Nevado del Ruiz, Galeras, and Purace, three of the most persistently degassing volcanoes located in the Colombian Arc Segment of the Northern Volcanic Zone. At Nevado del Ruiz, from 2014 to 2017, plume emissions showed an average molar CO2/S-T ratio of 3.9 +/- 1.6 (S-T is total sulfur, S). Contemporary, fumarolic chemistry at Galeras progressively shifted toward low-temperature, S-depleted fumarolic gas discharge…

geographyColombian Arc Segmentgeography.geographical_feature_category010504 meteorology & atmospheric sciencesMantle wedgeSubductionGaleraVolcanic beltGeochemistrySedimentarc volcanismNevado del Ruiz010502 geochemistry & geophysics01 natural sciencesPlumeArc (geometry)GeophysicsVolcanoGeochemistry and PetrologySubaerialvolatile fluxesGeologyPurace0105 earth and related environmental sciences
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Tracking Formation of a Lava Lake From Ground and Space: Masaya Volcano (Nicaragua), 2014-2017

2018

A vigorously degassing lava lake appeared inside the Santiago pit crater of Masaya volcano (Nicaragua) in December 2015, after years of degassing with no (or minor) incandescence. Here we present an unprecedented-long (3 years) and continuous volcanic gas record that instrumentally characterizes the (re)activation of the lava lake. Our results show that, before appearance of the lake, the volcanic gas plume composition became unusually CO 2 rich, as testified by high CO 2 /SO 2 ratios (mean: 12.2 ± 6.3) and low H 2 O/CO 2 ratios (mean: 2.3 ± 1.3). The volcanic CO 2 flux also peaked in November 2015 (mean: 81.3 ± 40.6 kg/s; maximum: 247 kg/s). Using results of magma degassing models and budg…

Convection010504 meteorology & atmospheric sciencesLava2Flux010502 geochemistry & geophysics01 natural sciencesGeochemistry and Petrologylava lakeMasayaPetrologyGeophysicvolcanic CO0105 earth and related environmental scienceslava lakes; Masaya; MODIS; Multi-GAS; scanning-DOAS; volcanic CO2 flux; Geophysics; Geochemistry and Petrologyscanning-DOASgeographygeography.geographical_feature_categoryvolcanic CO 2 fluxlava lakesPit cratervolcanic CO2 fluxPlumefluxGeophysicsMODISVolcanoMagmaGradual increaseMulti-GASGeologyGeochemistry, Geophysics, Geosystems
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Gas mass derived by infrasound and UV cameras: Implications for mass flow rate

2016

Abstract Mass Flow Rate is one of the most crucial eruption source parameter used to define magnitude of eruption and to quantify the ash dispersal in the atmosphere. However, this parameter is in general difficult to be derived and no valid technique has been developed yet to measure it in real time with sufficient accuracy. Linear acoustics has been applied to infrasonic pressure waves generated by explosive eruptions to indirectly estimate the gas mass erupted and then the mass flow rate. Here, we test on Stromboli volcano (Italy) the performance of such methodology by comparing the acoustic derived results with independent gas mass estimates obtained with UV cameras, and constraining th…

010504 meteorology & atmospheric sciencesInfrasoundMass flowVolcano acousticMagnitude (mathematics)ThrustGeophysicsMass flow rate010502 geochemistry & geophysics01 natural sciencesAtmosphereGeophysicsSulphur dioxide cameraThermal imagery13. Climate actionGeochemistry and PetrologyMass flow rateRange (statistics)WaveformGeology0105 earth and related environmental sciencesJournal of Volcanology and Geothermal Research
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Aerial strategies advance volcanic gas measurements at inaccessible, strongly degassing volcanoes

2020

Aerial measurements using unoccupied aerial systems (UAS) transform our ability to measure and monitor volcanic plumes.

010504 meteorology & atmospheric sciencessub-053705 Geology010502 geochemistry & geophysicsAtmospheric sciences01 natural sciencesMantle (geology)Carbon cycleVolcanic GasesFlux (metallurgy)eventResearch Articles0105 earth and related environmental sciencesevent.disaster_typegeographyMultidisciplinarygeography.geographical_feature_categorySciAdv r-articlesSampling (statistics)Sediment37 Earth Sciences3703 GeochemistryPlumeApplied Sciences and EngineeringVolcanoPhysical SciencesManam volcanic gases UASResearch ArticleScience Advances
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Understanding the SO 2 degassing budget of Mt Etna’s paroxysms: First clues from the december 2015 sequence

2019

The persistent open-vent activity of basaltic volcanoes is periodically interrupted by spectacular but hazardous paroxysmal explosions. The rapid transition from quiescence to explosive eruption poses a significant challenge for volcanic hazard assessment and mitigation, and improving our understanding of the processes that trigger these paroxysmal events is critical. Although magmatic gas is unquestionably the driver, direct measurements of a paroxysm’s gas flux budget have remained challenging, to date. A particularly violent paroxysmal sequence took place on Etna on December 2015, intermittently involving all summit craters, especially the Voragine (VOR) that had previously displayed no…

010504 meteorology & atmospheric sciences2Earth and Planetary Sciences(all)UV camera010502 geochemistry & geophysics01 natural sciencesSequence (geology)Basaltic paroxysmsImpact craterBasaltic paroxysms; Etna; OMI; Thermal remote sensing; UV camera; Volcanic SO ; 2High spatial resolutionlcsh:ScienceThermal remote sensing0105 earth and related environmental sciences/dk/atira/pure/subjectarea/asjc/1900BasaltVolcanic SOgeographygeography.geographical_feature_categoryOMIGas fluxBasaltic paroxysmEtna volcanoVolcanoMagmavolcanic SO2General Earth and Planetary SciencesEtnalcsh:QSeismologyGeology
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