Direct electricity production from Avgas UL91 fuel
As fuel for fuel cells can be used various substances, but generally fuel cells are powered by hydrogen. However, problems with the storage of hydrogen are the reason for the search of new fuels for fuel cells. The paper presents the possibility of using Avgas fuel as fuel for fuel cell. The Avgas does not have the feature of electrical conductivity, for this reason a detergent (nonionic surfactant) was used for dissolving fuel in an electrolyte. The work shows possible electrooxidation of Avgas fuel emulsion prepared on the basis of a nonionic surfactant on a platinum electrode in an aqueous solution of H2SO4. As non-ionic surfactant was used the detergent Syntanol DS-10. The emulsion was …
Direct electricity production from coconut oil - the electrooxidation of coconut oil in an acid electrolyte
Supplying more and more energy is an essential task of today's energy industry. In the last few decades, in addition to traditional methods of energy production, alternative energy sources have been developing at a fast rate. One of the devices that can use these sources is the fuel cell (FC). FCs can be a power source of the future mainly due to their high efficiency, their low impact on the environment and the possibility of powering with different fuels. Most often, FCs are powered by hydrogen. However, issues with its cheap production and storage are the reasons for seeking new fuels for FCs. Yet it must be a fuel that will provide a zero or low emission level. One of these fuels can be…
Direct Electricity Production from Linseed Oil
Today’s energy industry is currently facing an increasing demand for electricity. Besides to the use of coal, oil and gas, in recent years renewable energy sources have also are used. One of devices using renewable energy sources is fuel cell (FC). The most commonly used fuel for fuel cells is hydrogen. But, problems with storage of this fuel causes, that the finding new fuels for FCs are very desirable. One of these fuels can be linseed oil. Powering high efficiency power sources (like FCs) with renewable fuels (like linseed oil) will allow development of renewable energy sources and elimination or reduce of toxic substances emissions. The paper presents the research of linseed oil electro…
Possibility of fuel cell powering with grape seed oil
In the last few years alternative energy sources have been fast developing. One of technical device using these sources is fuel cell. Fuel cell performs direct conversion of chemical fuel into electrical energy, without combustion and characterized by high efficiency. Most commonly fuel cells are powered by hydrogen. However, problems with the storage of hydrogen are the reason for the search of new fuels for fuel cells. Due to development of the renewable energy sources, the powering of high efficiency power sources with bio-fuels is very important. Vegetable oil is an alternative fuel for Diesel engines and for heating oil burners. Powering high efficiency power sources (like fuel cells) …
The Membrane-Less Microbial Fuel Cell (ML-MFC) with Ni-Co and Cu-B Cathode Powered by the Process Wastewater from Yeast Production
Research related to measurements of electricity production was combined with parallel wastewater parameter reduction in a membrane-less microbial fuel cell (ML-MFC) fed with industry process wastewater (from a yeast factory). Electrodes with Ni–Co and Cu–B catalysts were used as cathodes. A carbon electrode (carbon cloth) was used as a reference due to its widespread use. It was demonstrated that all analyzed electrodes could be employed as cathodes in ML-MFC fed with process wastewater from yeast production. Electricity measurements during ML-MFC operations indicated that power (6.19 mW) and current density (0.38 mA·cm−2) were the highest for Ni–Co electrodes. In addition, during the explo…
Electricity Production from Yeast Wastewater in Membrane-Less Microbial Fuel Cell with Cu-Ag Cathode
Wastewater has high potential as an energy source. Therefore, it is important to recover even the smallest part of this energy, e.g., in microbial fuel cells (MFCs). The obtained electricity production depends on the process rate of the electrodes. In MFC, the microorganisms are the catalyst, and the cathode is usually made of carbon material (e.g., with the addition of Pt). To increase the MFC efficiency (and reduce costs by reducing use of the noble metals), it is necessary to search the new cathode materials. In this work, the electricity production from yeast wastewater in membrane-less microbial fuel cells with Cu-Ag cathode was analyzed. In the first place, the measurements of the sta…
Effect of Hydrogen and Absence of Passive Layer on Corrosive Properties of Aluminum Alloys
This paper reports the results of research on the effect of hydrogen permeation and the absence of passive layers on the variations in the corrosive properties of aluminum alloys. The study demonstrated that such variations contribute to the deterioration of corrosive properties, which in turn contributes to shortening the reliability time associated with the operation of aluminum alloy structures. The analysis involved structural aluminum alloys: EN AW-1050A, EN AW-5754, and EN AW-6060. It was demonstrated that the absorption of hydrogen by the analyzed alloys led to the shift of the electrode potential to the negative side. The built hydrogen corrosion cells demonstrate in each case the f…
Analysis of the Potential of an Increase in Yeast Output Resulting from the Application of Additional Process Wastewater in the Evaporator Station
This paper reports the results of an analysis of process wastewater streams in the context of an increase in yeast production. This research is based on the analysis of data from the biggest yeast factory in Europe. The research presented in this paper involves the analysis of the influence of direction of additional wastewater into the evaporator station on yeast production. In the process wastewater, nitrogen is mainly present in organic forms. The analysis reported in this paper involves the concentration of total nitrogen in wastewater streams, as it is the main parameter applied to determine the amount of wastewater that can be applied in agricultural fields. Directing additional waste…
Electrooxidation of coconut oil in alkaline electrolyte
Providing more and more energy is an essential task of the today’s energetic industry. In the last few years, in addition to the traditional methods of energy production, alternative energy sources have been developing fast. One of the devices that can make use of these sources is a fuel cell. The fuel cells can be a power source of future mainly due to their high efficiency, low influence on environment and the possibility of powering with different fuels. Most often, fuel cells are powered by hydrogen. However, the problems with its cheap production and storage are the reason for the search for alternative fuels for fuel cells. It is important that the new fuel will be characterized by ze…
MICROBIAL FUEL CELL WITH Cu-B CATHODE POWERING WITH WASTEWATER FROM YEAST PRODUCTION
With the increasing standard of living, energy consumption increases as well. So, waste production, including wastewater, increases as well. One of the types of waste-water is wastewater from yeast industry. Wastewater from this industry has not only a high pollutants load but it is produced in great amounts as well. Technical devices that can accomplish the wastewater treatment and electricity production from wastewater is a microbial fuel cell. In microbial fuel cells activated sludge bacteria can be used for electricity production during wastewater treatment. The possibility of using the Cu-B alloy as cathode catalyst for microbial fuel cells to wastewater treatment of wastewater from ye…
Micro bial fuel cell with Ni-Co cathode
Analysis of Possibility of Yeast Production Increase at Maintained Carbon Dioxide Emission Level
Abstract Main parameters polluting of technological wastewater (dregs from decantation and thicken of the wort) from yeast industry are: nitrogen, potassium and COD. Such wastewater are utilized mostly on agricultural fields. Unfortunately, these fields can only accept a limited amount of wastes. The basic parameter limiting there the amount of wastewater is nitrogen. When capacity of the production is large sewages are often pretreated at an evaporator station. However, due to the fairly high running costs of the evaporator station currently such a solution is applied only to a small amount of wastes (just to meet legal requirements). Replacement of the earth gas with a biomass being suppl…
Comparison of Cu-B Alloy and Stainless Steel as Electrode Material for Microbial Fuel Cell
The microbial fuel cell (MFC) is a technical devices that electricity produces during wastewater treatment. One of the problems of MFCs is a low current density. Thus, it is necessary to search for new electrodes for MFC. The comparison of Cu-B alloy and stainless steel as catalyst for MFCs cathode is presented in this paper. The research included measurements of the concentration of COD, NH4+ and NO3− in three types of reactors: without aeration, with aeration and with using a MFC (with Cu-B and stainless steel cathode). It has been shown that effectiveness of MFC with Cu-B electrode is higher than effectiveness of MFC with stainless steel electrode.
FUEL CELL POWERED WITH CANOLA OIL EMULSION
The paper presents possibility of using canola oil as active substance to fuel cell powering. For this purpose a prototype fuel cell was built. Cell was powered with canola oil emulsion. As a detergent Syntanol DS-10 was used. The mesh electrode with Pt catalyst was used as a anode, and mesh electrode with Ni-Co catalyst was used as a cathode. The measurements conducted in the temperature range 293-333K. The maximum current density reached the level of 2 mA/cm2, and maximum power reached the level of 21 mW (at temp. 333K). So, the possibility of delivery of canola oil (in emulsion form) directly to the anode was shown. The obtain power is low, but was shown that it is possible to build the …
Microbial Fuel Cell with Ni–Co Cathode Powered with Yeast Wastewater
Wastewater originating from the yeast industry is characterized by high concentration of pollutants that need to be reduced before the sludge can be applied, for instance, for fertilization of croplands. As a result of the special requirements associated with the characteristics of this production, huge amounts of wastewater are generated. A microbial fuel cell (MFC) forms a device that can apply wastewater as a fuel. MFC is capable of performing two functions at the same time: wastewater treatment and electricity production. The function of MFC is the production of electricity during bacterial digestion (wastewater treatment). This paper analyzes the possibility of applying yeast wastewate…
Wastewater treatment and electricity production in a microbial fuel cell with Cu–B alloy as the cathode
The possibility of wastewater treatment and electricity production using a microbial fuel cell with Cu&ndash
Single chamber microbial fuel cell with Ni-Co cathode
The possibility of wastewater treatment and the parallel energy production using the Ni-Co alloy as cathode catalyst for single chamber microbial fuel cells is presented in this research. The research included a preparation of catalyst and comparison of COD, NH4 + and NO3 - reduction in the reactor without aeration, with aeration and with using a single chamber microbial fuel cell with Ni-Co cathode. The reduction time for COD with the use of microbial fuel cell with the Ni-Co catalyst is similar to the reduction time with aeration. The current density (2.4 A·m-2 ) and amount of energy (0.48 Wh) obtained in MFC is low, but the obtained amount of energy allows elimination of the energy neede…
Applicability of Waste Engine Oil for the Direct Production of Electricity
New methods for the use of waste products as input for other technologies are a constant subject of research efforts. One such product is waste engine oil. Due to the constantly increasing number of motor vehicles in the world, the recycling or application of engine oils for energy production purposes is currently of considerable importance. This paper contains research regarding the analysis of the electro-oxidation potential of waste engine oil, and thus the possibility of using such oil as a material in fuel cells. The research demonstrates the basic possibility of the electro-oxidation of this oil emulsion on a platinum electrode in an acid electrolyte (aqueous solution of H2SO4). It wa…
Feasibility of Waste Engine Oil Electrooxidation with Ni-Co and Cu-B Catalysts
To implement a circular economy policy, methods of using waste products as a starting point for other technologies are constantly researched. One of the waste products that should be disposed of after use is waste engine oil (WEO). Despite the permanent introduction of the electrification of cars, the number of combustion vehicles (and, thus, the production of WEO) is constantly increasing. For these reasons, the reuse of WEOs is extremely important; e.g., to use these oils for energy purposes. One of the potential uses of this type of oil is as fuel for fuel cells (for direct electricity production). To lower the production costs of electrodes for fuel cells, catalysts that do not contain …
ELECTROOXIDATION OF USED SYNTHETIC ENGINE OIL IN AQUEOUS SOLUTION OF H2SO4
The paper presents possibility of using used synthetic engine oil to direct electricity production. The measurements conducted in the temperature range 293-333 K. Were measured electrooxidation of used synthetic engine oil emulsion on a smooth platinum electrode in an aqueous solution of H2SO4. The emulsion prepared on the basis of a nonionic surfactant Syntanol DS-10. The maximum current density reached the level of 22 mA/cm2 (temp. 333 K). Measurements shows possibility of direct electricity production from used synthetic engine oil emulsion, so powering fuel cell of this oil.
Preparation and Analysis of Ni–Co Catalyst Use for Electricity Production and COD Reduction in Microbial Fuel Cells
Microbial fuel cells (MFCs) are devices than can contribute to the development of new technologies using renewable energy sources or waste products for energy production. Moreover, MFCs can realize wastewater pre-treatment, e.g., reduction of the chemical oxygen demand (COD). This research covered preparation and analysis of a catalyst and measurements of changes in the concentration of COD in the MFC with a Ni&ndash
Deterioration of Property of Aluminum Alloys (EN AW-1050A, EN AW-5754 and EN AW-6060) by Absorbed Hydrogen
The paper reports the results of research on the effect of hydrogen penetration on the variations in the mechanical properties of selected aluminum alloys. As a result of the study, it can be observed that such variations contribute to the deterioration of mechanical properties, which, in turn, contributes to shortening the reliability time associated with the operation of aluminum alloy structures. The analysis involved structural aluminum alloys: EN AW-1050A, EN AW-5754 and EN AW-6060. Tensile strength and impact strength were measured. It was demonstrated that the absorption of hydrogen by the analyzed alloys led to the deterioration of mechanical properties of aluminum alloys. The perfo…
Possibility of Wastewater Treatment Using MFC with Ni-Co Catalyst of Fuel Electrode
Abstract One of the problems with microbial fuel cells is a low current density of those energy sources. Nonetheless, it is possible to increase the current density by using the catalyst for fuel electrode (anode) - as long as a low cost catalyst can be found. The possibility of wastewater treatment using the Ni-Co alloy as catalyst for MFC’s is presented in this paper. The alloys were obtained with different concentrations of Co (15 and 50% of Co). The increase of current density with Ni-Co catalyst is approximately 0,1 mA/cm2. So, a fundamental possibility wastewater treatment using the Ni-Co alloy as catalyst for microbial fuel cells was presented.
MICROBIAL FUEL CELL WITH Ni-Co CATHODE AND KMnO4 CATHOLYTE
The improving standard of living causes the increases in energy consumption and waste or wastewater production. The possibility of combining wastewater treatment and electricity production can be accomplished by means of a microbial fuel cell. The possibility of wastewater treatment using the Ni-Co alloy as cathode catalyst with KMnO4 catholyte for microbial fuel cells was presented in this paper. The measurements covered the comparison of changes in the concentration of COD, NH4+ and NO3- in the reactor without aeration, with aeration and using a microbial fuel cell (with Ni-Co cathode and KMnO4 catholyte). The reduction time for COD using a microbial fuel cell with the Ni-Co catalyst (and…
THE SYNTHESIS OF PLANT GROWTH STIMULATORS BY PHYTOPATHOGENIC BACTERIA AS FACTOR OF PATHOGENICITY
The environmental changes significantly influence the microorganisms and affect their properties, leading them to take uncharacteristic ecological niches. This study has focused on the ability of phytopathogenic bacteria that belongs to the genera Pseudomonas, Curtobacterium, Ralstonia, Pantoea and Xanthomonas, which are able to cause various diseases of legumes, to produce extracellular phytohormones with stimulatory action in vitro. The qualitative and quantitative composition of extracellular auxins and cytokinins has been determined by spectrodensitometric thinlayer chromatography. This research revealed that the synthesis of plant growth promoting phytohormones that are agents of diffe…
Cu-B alloy - analysis of use possibility as fuel cell cathode catalyst
In recent years there has been a development of non-conventional and renewable sources of energy. One such sources of energy are fuel cells. Fuel cells are ecological and high efficiency sources of electric energy. However, the use of fuel cells on a large scale is limited, mainly by the high cost of catalysts. Platinum is most commonly used as the catalyst. But due to the high price of platinum there’s a need for finding other catalysts. Replacement of platinum will contribute to the fast development of green energy sources. This paper presents a study of possibility of using Cu-B alloy as catalyst for oxygen electrode in fuel cells. Researches were done in glass vessel, on a copper electr…
Possibility of direct electricity production from waste canola oil
Powering high-efficiency devices, such as fuel cells, with waste products will allow for a broader development of renewable energy sources and utilisation of by- products. This publication presents the possibility of electrooxidation of the emulsion of waste rapeseed oil, prepared on the basis of the detergent Syntanol DS-10. The process of electrooxidation was carried out on platinum electrode in alkaline (KOH) and acidic (H 2 SO 4 ) electrolyte, in the temperature range of 293-333 K. In each analysed case the process of electrooxidation took place. The maximum current density obtained was 7 mA cm -2 . Thus, it has been shown that it is possible to generate electricity directly from the em…
USE OF Ni-Co ALLOY AS CATHODE CATALYST IN SINGLE CHAMBER MICROBIAL FUEL CELL
Technology of microbial fuel cells allowing for the direct production of electricity from biodegradable materials can provide only energy production, but also wastewater treatment. This technology is seen as supporting of the traditional wastewater treatment. One of the problems with microbial fuel cells is a low current density of those energy sources. Nonetheless, it is possible to increase the current density by using the catalyst for electrodes (anode and cathode). The possibility of wastewater treatment using the Ni-Co alloy as catalyst for single chamber microbial fuel cells is presented in this paper. The studies have included measurements of H2O2 reduction on Ni-Co catalyst, power o…
Electrooxidation of Sesame Oil in Acid Electrolyte
The energy industry is based mainly on coal, crude oil, natural gas or nuclear energy. However, in recent years renewable energy sources have also become increasingly used. One of the devices that uses renewable energy sources is a fuel cell (FC). The fuel cell can be powered by hydrogen, methanol, hydrazine or other substrates. Commercial fuel cells use mainly hydrogen, methanol or hydrazine. Due to the fact that water is the only by-product, hydrogen is the considered to be the best fuel for fuel cells. Problems with hydrogen storage cause, however, that new fuels for FCs are very desirable. Vegetable oil seems to be such substance, application of which as fuel in FCs is possible. But in …