First volatile inventory for Gorely volcano, Kamchatka

We report here the very first assessment of volatile flux emissions from Gorely, an actively degassing volcano in Kamchatka. Using a variety of in situ and remote sensing techniques, we determined the bulk plume concentrations of major volatiles (H2O 93.5%, CO2, 2.6%, SO2 2.2%, HCl 1.1%, HF 0.3%, H2 0.2%) and trace-halogens (Br, I), therefore estimating a total gas release of 11,000 tons·day−1 during September 2011, at which time the target was non-eruptively degassing at 900°C. Gorely is a typical arc emitter, contributing 0.3% and 1.6% of the total global fluxes from arc volcanism for CO2 and HCl, respectively. We show that Gorely's volcanic gas (H2O/SO2 43, CO2/SO2 1.2, HCl/SO2 0.5) is a…

High-spectral-resolution Fabry-Pérot interferometers overcome fundamental limitations of present volcanic gas remote sensing techniques

Remote sensing (RS) of volcanic gases has become a central tool for studying volcanic activity. For instance, ultraviolet (UV) skylight spectroscopy with grating spectrographs (GS) enables SO2 (and, under favourable conditions, BrO) quantification in volcanic plumes from autonomous platforms at safe distances. These measurements can serve volcanic monitoring and they cover all stages of volcanic activity in long measurement time series, which substantially contributes to the refinement of theories on volcanic degassing. Infrared (IR) remote sensing techniques are able to measure further volcanic gases (e.g., HF, HCl, CO2, CO). However, the employed Fourier transform spectrometers (FTSs) are…

New clues on the contribution of Earth's volcanism to the global mercury cycle

Magmatic gas flux emissions from Gorelyi volcano, Kamchatka, and implications for volatile recycling in the NW Pacific

The Kamchatka peninsula, in the north-western part of the Pacific ’Ring of Fire’, is one of the most active volcanic realms on Earth, with 29 historically erupting volcanoes along its 700 km-long Eastern Volcanic Belt (EVB). This notwithstanding, volatile input and output fluxes along this arc sector have remained poorly characterised until very recently. We here report on the very first assessment of volatile flux emissions from Gorelyi, a large (25 km3, 1830 m high) and most active shield-like Holocene volcano located on the southern segment of the Kamchatka EVB. By combing results from a variety of in situ and remote sensing techniques (MultiGAS, filter packs, and UV camera), we determine the…

Volcanic gas monitoring of quiescent volcanoes using permanent Multi-GAS networks

The Multi-component Gas Analyzer System (Multi-GAS) has recently consolidated as a standard technique for the nearly real-time in-situ observation of major volcanogenic components (H2O, CO2, SO2, H2S,H2) in volcanic gas plumes. The Multi-GAS has been initially operated at open-vent volcanoes, where it has revealed ideal for long-term continuous observations at for instance Etna and Stromboli volcanoes in Italy, therein paving the way to the acquisition of unprecedentedly long and continuous volcanic gas time-series. We here initially review the present state of the expanding network of permanent Multi-GAS instruments, now covering about 10 volcanoes worldwide. We then specifically focus on …

Forecasting Etnean eruptions by real-time observations of volcanic gas composition.

It is generally accepted but not experimentally proven that a quantitative prediction of volcanic eruptions is possible from the evaluation of volcanic gas data. By discussing the results of two years of real-time observation of H2O, CO2 and SO2 in volcanic gases from Mt. Etna volcano, we unambiguously demonstrate that increasing CO2/SO2 ratios can allow detecting the pre-eruptive degassing of uprising magmas. Quantitative modeling by the use of a saturation model allows us to relate the pre-eruptive increases of the CO2/SO2 ratio to the refilling of Etna’s shallow conduits with CO2-rich deep-reservoir magmas, leading to pressurization and eruption triggering. The advent of real-time observ…

First observational evidence for the CO2-driven origin of Stromboli’s major explosions

Bromine chemistry of volcanic plumes

Volcanic gas studies are an established tool for volcanic monitoring and enhance the understanding of volcanic manifestations. The central question of the project, which we will introduce here, is whether the ratio between bromine monoxide (BrO) to sulphur dioxide (SO2) can potentially serve as indicator for volcanic activity. Both species have the advantage that they can be remotely measured by Differential Optical Absorption Spectroscopy (DOAS) at safe distances from the emission source. To answer the question above, it is of great importance to link the measurements of halogen oxides to the total emission flux of individual halogen species and to understand the influences of meteorologic…