Real-Time Measurements of Hg0 and H2S at Solfatara Crater (Campi Flegrei, Southern Italy): an Innovative Approach to Investigate the Distribution of …

2014

Real-time measurements of Hg0 and H2S at La Solfatara Crater (Campi Flegrei, Southern Italy) and Mt. Amiata volcano (Siena, Central Italy): a new geo…

2014

Active real-time analyzers vs. passive/diffusive samplers for hydrogen sulfide (H2S) in air: a critical comparison

2015

Hydrogen sulfide (H2S) is a gas pollutant discharged in air from a large number of natural and anthropogenic sources. Its peculiar rotten-egg smell, causing odor nuisance to neighboring communities, is detectable at concentrations between 0.7 and 42 μg/m3 (Schiffman & Williams, 2005). High H2S concentrations could cause eye irritation, damage to the upper respiratory apparatus and loss of smell. The effects of long-term low level (< 2,800 μg/m3) exposures to H2S are still matter of debate (Bates et al., 2013). Hence, the development of techniques for accurate measurements of H2S in air at a wide range of concentrations is a primary issue in environmental monitoring. Two different app…

Measurements of Hg0 (and H2S) at the Solfatara Crater (Southern Italy): Estimating the atmospheric distribution with a real-time approach

2015

Volcanic and geothermal areas are important emitters of natural gas compounds into the atmosphere, which can be of concern when discharging close to densely, populated sites. Mercury has a strong environmental impact, its organic and inorganic complexes being toxic. The dominant form of Hg in the atmosphere is gaseous elemental mercury (GEM), which has high volatility and residence time of 1-2 years. Volcanic degassing accounts for a significant part of the natural mercury emissions. No mercury limits or target values in ambient air are present in the EU legislations, whereas US-EPA and ATSDR impose 300 and 200 ng/m3, respectively, as a limit for chronic exposure. WHO has proposed the annua…

Do patients' and referral centers' characteristics influence multiple sclerosis phenotypes? Results from the Italian multiple sclerosis and related d…

2022

Abstract Background Multiple sclerosis (MS) is characterized by phenotypical heterogeneity, partly resulting from demographic and environmental risk factors. Socio-economic factors and the characteristics of local MS facilities might also play a part. Methods This study included patients with a confirmed MS diagnosis enrolled in the Italian MS and Related Disorders Register in 2000–2021. Patients at first visit were classified as having a clinically isolated syndrome (CIS), relapsing–remitting (RR), primary progressive (PP), progressive-relapsing (PR), or secondary progressive MS (SP). Demographic and clinical characteristics were analyzed, with centers’ characteristics, geographic macro-ar…

Measurements of gaseous elemental mercury (GEM) in diffuse soil emission using the static closed-chamber method

2015

Measurements aimed to evaluate the contribution of natural and anthropogenic gaseous elemental mercury (GEM) to the atmosphere are critical for monitoring and mitigating the impact of this highly toxic air contaminant. Notwithstanding, the amounts of GEM originating from different sources are difficult to be estimated, since specific protocols dictating the most appropriate sampling and analytical techniques are lacking. This study was aimed to test a methodological approach enables to measure GEM released through diffuse degassing from the soil, a mechanism that in volcanic and geothermal areas significantly contributes to the discharge of geogenic fluids to the atmosphere. A static closed…

A new geochemical approach to estimate the distribution of air pollutants from natural and anthropogenic sources: examples from Solfatara Crater (Cam…

2015

Volcanic and geothermal systems significantly contribute to the input of volatile contaminants, such as mercury and hydrogen sulfide, into the atmosphere. Mercury has a strong environmental impact. In the atmosphere the prevalent elemental form is Hg0 (~98 %), whose main physical-chemical features are: high volatility, low solubility and chemical inertness. Hydrogen sulfide (H2S), one of the most abundant gas compounds in volcanic fluids, is highly poisoning and corrosive and unpleasantly smells of rotten eggs. Measurements of Hg0 and H2S concentrations in air are commonly performed by means of passive samplers. However, real-time measurements, coupled with monitoring of local atmospheric c…

The Italian multiple sclerosis register

2019

The past decade has seen extraordinary increase in worldwide availability of and access to several large multiple sclerosis (MS) databases and registries. MS registries represent powerful tools to provide meaningful information on the burden, natural history, and long-term safety and effectiveness of treatments. Moreover, patients, physicians, industry, and policy makers have an active interest in real-world observational studies based on register data, as they have the potential to answer the questions that are most relevant to daily treatment decision-making. In 2014, the Italian MS Foundation, in collaboration with the Italian MS clinical centers, promoted and funded the creation of the …

Real-time measurements of Hg0 in volcanic, geothermal and anthropogenic systems: a multi-methodological approach using Lumex® instrumentation

2015

Mercury represents a pollutant of global concern and strong environmental impact since is highly toxic. Hg is present in air in the oxidation states of 0 and +2, the former being the dominant species with a residence time of 1-2 years due to its high volatility, relatively low solubility and chemical inertness. Both volcanic/geothermal and anthropogenic systems are crucial contributor to the release of Hg0 in the atmosphere. In this work, a Lumex® (RA-915M) was used to evaluate the environmental impact in air of Hg0 from: i) the abandoned Hg mining site and geothermal areas from Mt. Amiata (Siena, Central Italy) and ii) selected Mediterranean volcanic and geothermal systems. The Lumex® inst…