0000000000111414
AUTHOR
S Bellomo
The fluids’ geochemistry along the "Sperchios Basin - Northern Evoikos Gulf" Graben, a geodynamically complex area of Central Greece
CHEMICAL AND MINERALOGICAL CHARACTERIZATION OF ETNEAN VOLCANIC EMISSIONS USING ACTIVE BIOMONITORING TEC HNIQUE (MOSS-BAGS)
A geochemical traverse along the “Sperchios Basin e Evoikos Gulf” graben (Central Greece): Origin and evolution of the emitted fluids
The studied area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence of a subduction slab at depth responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). A high geothermal gradient is made evident by the presence of many thermal springs with temperatures from 19 to 82 C, that discharge along the normal faults bordering the graben. In the period 2004e2012, 58 gas and 69 water samples were collected and their chemical and isotopic analysis revealed a wide range of compositions. Two main groups of thermal waters…
Active real-time analyzers vs. passive/diffusive samplers for hydrogen sulfide (H2S) in air: a critical comparison
Hydrogen sulfide (H2S) is a gas pollutant discharged in air from a large number of natural and anthropogenic sources. Its peculiar rotten-egg smell, causing odor nuisance to neighboring communities, is detectable at concentrations between 0.7 and 42 μg/m3 (Schiffman & Williams, 2005). High H2S concentrations could cause eye irritation, damage to the upper respiratory apparatus and loss of smell. The effects of long-term low level (< 2,800 μg/m3) exposures to H2S are still matter of debate (Bates et al., 2013). Hence, the development of techniques for accurate measurements of H2S in air at a wide range of concentrations is a primary issue in environmental monitoring. Two different app…
Origin and evolution of the fluids emitted along the “Sperchios Basin – Evoikos Gulf” Graben (Central Greece)
FIRST APPLICATION OF ACTIVE BIOMONITORING TECHNIQUES (MOSS-BAGS) TO MAP THE DISPERSION OF VOLCANIC EMISSIONS
Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain informations on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application o…
The use of moss-bags technique to volcanic aerosols investigation on Mt. Etna (Italy)
Biomonitoring of volcanogenic trace elements using two endemic species (Senecio aethnensis and Rumex aethnensis) on Mt. Etna.
A biomonitoring survey, above treeline level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500-3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analysed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted b…
Are the Salinelle mud volcanoes threatening human health or are anthropogenic activities threatening the Salinelle mud volcanoes?
Passive samplers were used to measure the atmospheric concentrations of SO2 naturally emitted at three volcanoes in Italy (Etna, Vulcano and Stromboli) and of H2S naturally emitted at three volcanic/geothermal areas in Greece (Milos, Santorini and Nisyros). The measured concentrations and dispersion patterns varied with the strength of the source (open conduits or fumaroles), the meteorological conditions and the area topography. At Etna, Vulcano and Stromboli, SO2 concentrations reach values that are dangerous to people affected by bronchial asthma or lung diseases (>1000 μg m−3). H2S values measured at Nisyros also exceed the limit considered safe for the same group of people (>3000 μg m−…
Environmental impact of Mt. Etna’s degassing: volcanogenic trace elements bioaccumulation in two endemic plant species (Senecio aethnensis and Rumex aethnensis)
A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis)was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500-3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the mos…
Application of the moss bag biomonitoring technique in an active volcanic environment (Mt. Etna, Italy).
This paper presents the preliminary results of a biomonitoring study based on the use of moss bags exposed at 24 sites on Etna volcano. Sphagnum mosses were used to study bioaccumulation originating from atmospheric deposition, by measuring the tissue contents of major and a large suite of trace elements. Elements, such as Tl, Bi, As, Se, Cu and Cd, display high concentrations in the exposed samples close to the active vents. This study confirms the effectiveness of the moss bags technique also in active volcanic areas.
Environmental impact of volcanic emissions at Nyiragongo (DRC)
The large amount of trace elements emitted from volcanoes has a strong impact on the close surrounding areas. Nyiragongo Volcano (Democratic Republic of Congo) belongs to the Virunga volcanic chain and is one of the most active volcanoes in Africa. It is characterized by the presence of an active and permanent lava lake with a persistent degassing activity. During a field trip in October-November 2014, we investigated the impact of the volcanogenic deposition in the surrounding of the crater by using different sampling techniques. Rain-gauges were used to collect atmospheric bulk deposition. Active and passive biomonitoring techniques (moss-bags and leaves of endemic plants – Senecio spp. a…
Active Moss biomonitoring of mercury in the mine-polluted area of Mt. Amiata (Central Italy)
In the winter 2013, mercury concentrations in air from the mine-polluted area of Mt. Amiata (1738 m a.s.l.), in southern Tuscany (Central Italy), were measured by active moss biomonitoring. This area is part of the geologic anomaly of Hg in the Mediterranean basin, which contains about 65 % of the world’s cinnabar (HgS). Mt. Amiata covers some 400 km2 and is drained by several rivers. Esploitation activity at Abbadia S. Salvatore, in the SE sector of the mountain, sprang up during the 19th century as one of the largest mercury mining and smelting plants in Europe, after those of Almaden Spain. In this area, Sphagnum moss bags were exposed for about two months, from October to December 2013.…
The use of moss-bags technique for volcanic aerosols investigation on Mt. Etna (Italy)
Explosive eruptions and volcanic passive degassing inject large quantities of gas and particles into the atmosphere that are ultimately deposited at the Earth’s surface through wet or dry deposition processes, affecting the atmosphere, the hydrosphere and the biosphere. Mount Etna (Italy) is one of the most prodigious and persistent sources of gases and particles to the troposphere. Volcanic emissions were studied at Etna volcano by using moss-bags technique. Mosses (Sphagnum species) were exposed around the volcano at different distances from the active vents to evaluate the impact of its emissions into the atmosphere and in the local surrounding. The results confirmed the huge amount of s…
A literature review and new data of trace metals fluxes from worldwide active volcanoes
Natural gadolinium discharge from volcanic sources
Although a large fraction of chemicals is provided from volcanic fluids to the environment (Oppenheimer et al., 2014) only a scarce literature was focused on the Rare Earth elements (REE) release from high temperature fumaroles (Möller et al., 2003; Gilbert & Williams-Jones, 2008; Zelenski et al., 2013). In order to fill this gap, this research was carried out mainly taking in account the REE partitioning during the emissions of fumarolic fluid between newly-forming sublimates and the remaining gas phase. The latter was collected as alkaline condensates according to Sortino et al. (2006). The investigated high temperature fumaroles (95-450°C) occur in several volcanic systems at Vulcano (Ae…
Impact of Volcanic Emissions on Trace Elements Contents Measured in Endemic Plants at Mt. Etna (Italy)
Fumarolic alteration products at Sousaki (Greece) : occurrence and environmental impact
Fumarolic alteration crusts and efflorescences have been sampled at the Sousaki solfataric field. Samples have been analysed for mineralogical (XRD) and chemical composition (HNO3 digestion and leaching with distilled water). Results show that mineralogical and chemical compositions (major, minor and trace metals) are controlled by microenvironmental conditions. The sample collected in the anoxic part of a cave is composed almost exclusively by native sulfur. The samples collected in the oxidizing part of the cave and outside in relatively sheltered position are mainly composed by very soluble sulfates. Chemical composition evidence strong enrichments in Al, Ca, Cr, Fe, Mg and Ni which are …
Preliminary data on trace element emissions from Nyiragongo volcano (DR Congo)
Tellurium in active volcanic environments: Preliminary results
Active biomonitoring (moss-bags) of volcanic emissions on Mt. Etna
Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain information on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application of…