0000000000115137
AUTHOR
Aliotta
About entangled networks of worm-like micelles: a rejected hypothesis
We report new results from small-angle neutron scattering on d(1 2)-cyclohexane/lecithin/water micellar solutions performed as a function of the water content (w(o)), temperature (T) and dispersed phase volume fraction (phi). The data from dilute samples are interpretable in terms of the existence of giant cylindrical reverse micelles and are well fit with a core-shell model (that provides the micelle structure and dimensions) with values of 28 and 45 Angstrom for the inner core and the outer shell radii, almost independent on temperature and concentration. Such a result could appear consistent with the current idea that worm-like micelles are living polymers. On the contrary, the appearanc…
Incoherent quasi-elastic neutron scattering in isomeric alcohols
Abstract Incoherent quasi-elastic neutron scattering (IQENS) data on liquid isomeric alcohols normal-pentanol (n-PeOH) and 2-methyl-2-butanol (2M-2BuOH) and on their mixture are presented. The diffusive motion of protons, as a function of temperature, is analyzed in the framework of the random jump diffusion model. The temperature dependence of the parameters obtained confirms the more “fragile” behaviour of the more sterically hindered 2M-2BuOH with respect to that of the linear n-PeOH.
Small-angle neutron scattering from lecithin reverse micelles
Abstract We report new results of small-angle neutron scattering from cyclohexane- d 12 /lecithin/water micellar solutions, performed as a function of the water content, w 0 , the temperature, T and the dispersed-phase volume fraction, ф. The data from dilute samples can be interpreted in terms of the existence of giant cylindrical reverse micelles, in good agreement with the current idea of an unlimited micellar growth with ф. In contrast, the appearance of a sharp interference maximum at high concentrations ( ф > 0.15 ) suggests that the current hypothesis of a gel structure interpreted as a random network of entangled micelles can be assumed to be incorrect, and that there must be some c…
Relaxation phenomena in mixed isomeric alcohols by Mandelstam-Brillouin scattering
Mandelstam-Brillouin scattering data in mixed isomeric alcohols n-pentanol (nPe-OH) and 2-methyl-2-butanol (2Me-2BuOH) are presented. The hypersonic velocity and normalized absorption are measured as a function of the scattering angle, in the temperature range from - 15-degrees-C to + 45-degrees-C, and as a function of n-PeOH molar fraction going from the pure n-PeOH to the pure 2Me-2BuOH. The experimental results confirm the existence of a shear relaxation phenomenon in the GHz region, that has been previously detected in pure liquids. The temperature dependence of the relaxation time tau-s and of the shear modulus G-infinity evaluated within viscoelastic liquid models, support the existen…