<title>Electro-optical and fluorescence lifetime studies of aminophthalimide probes in liquids</title>

1995

The modified electro-optical absorption and emission methods are described as well as their use for measurements of electrical dipole moments of five aminophthalimides in ground and excited states. It is found that there exists a principal difference between properties of 3- aminophthalimide (3AP) and 4-amino-N-methylphthalimide (4ANMP) in different solvents. The equilibrated dipole moment of 3AP in its excited state is practically independent on the solvent polarity, in comparison with 4ANMP. The possible mechanism of this effect is discussed.© (1995) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

Dipole moments of 4′-aminoflavonols determined using electro-optical absorption measurements or molecular Stark-effect spectroscopy

2002

The electro-optical absorption measurements (EOAM) were used to measure the dipole moments of the normal form of 4 � -(methoxy)-3hydroxyflavone (FOM), 4 � -(dimethylamino)-3-hydroxyflavone (FME), and 4 � -N-(15-azacrown-5)-3-hydroxyflavone (FCR). For these probes the excited state intramolecular proton transfer (ESIPT) takes place. For comparison, the dipole moments of 4 � -(dimethylamino)-3methoxyflavone (FME3ME), for which ESIPT is lacking, were measured. In the case of FCR, FME, and FME3ME the equilibrated ground (µg) and excited Franck–Condon state (µ FC ) electrical dipole moments are parallel to each other and also parallel to the transition dipole moment. The electrical dipole moment…

<title>Coumarin fluorescent probes by electro-optical and laser spectrofluorimetry methods</title>

1997

Modified electro-optical absorption and emission methods were used to measure the dipole moments of six coumarin fluorescent probes (CU1, CU4, CU7, CU30, CU120, CU334) in the equilibrated ground, excited Franck-Condon and equilibrated excited states. The measurements were performed in cyclohexane and dioxane at room temperature. The equilibrated ground and excited states dipole measured by electro-optical methods are compared with those derived from other measurements techniques and from semiempirical calculations. Experiments and calculations performed in this work reveal a set of anomalous and interesting properties of CU7 and CU30 in solutions. The spectral dependence of some electro-opt…

Synthesis and molecular properties of donor–π-spacer–acceptor ynamides with up to four conjugated alkyne units

2010

A set of push-pull ynamides with up to four conjugated triple bonds has been synthesized and the molecular properties of these new carbon rods have been characterised showing effective intramolecular charge transfers and high values for the change of the electrical dipole moment after transition from the ground to the Franck-Condon excited state.

Dipole moments of aminophthalimides determined by modified electro-optical absorption and emission measurements

1995

Modified electro-optical absorption and emission methods were used to measure the electric dipole moments of five aminophthalimides in their ground and excited states. The equilibrated ground and excited state dipole moments measured by these methods are in reasonable agreement with those derived from other measurement techniques, confirming the general validity of these methods. A difference is observed between the properties of 3-aminophthalimide (3AP) and 4-amino-N-methylphthalimide (4ANMP) in different solvents. The equilibrated dipole moment of 3AP in its excited state is practically independent of the solvent polarity in contrast with 4ANMP. The possible mechanism of this effect is di…

Site selectivity in excited-state intramolecular proton transfer in flavonols

2001

Abstract To investigate 4′-(diethylamino) (FET) and 4′-N-(15-azacrown-5) (FCR) derivatives of 3-hydroxyflavone in binary solvents and erythrocyte ghosts, we used the red-edge excitation spectroscopy (REES). The results obtained prove the existence of spectral heterogeneity of flavonols in the studied systems. The effect manifests itself in the dependence of the efficiency of excited-state intramolecular proton transfer (ESIPT) on the excitation frequency. The electro-optical absorption method (EOAM) was used to measure the dipole moments of the normal form of FET. The electric dipole moments in the ground (μg) and excited Franck–Condon ( μ e FC ) states have the values 22.7×10−30 and 53.3×1…

Electro-optical and laser spectrofluorimetry study of coumarins 7 and 30: evidence for the existence of the close-lying electronic states and conform…

1997

Our experiments and calculations reveal a set of anomalous and interesting properties of coumarin 7 (CU7) and coumarin 30 (CU30) in solution. The spectral dependence of electro-optical coefficients and, consequently, dipole moments indicates that the absorption band is a superposition of several (at least two) electronic transitions. Probably, there are two close-lying π,π* singlet electronic excited states which contribute to the first absorption band. The calculations using the MM2 program show that both dyes in the ground state have two stable plane anti conformers. From time-resolved spectrofluorimetric measurements we obtained evidence for the existence of conformers in paraffin oil so…

Use of the red-edge excitation effect for investigation of dielectric interactions in biomembranes

1999

Dipole moments of the fluorescent probes 1-phenylnaphthylamine (1-AN) and 1-anilinonaphthalene-8-sulfonate (1,8-ANS) are measured using electro-optical absorption and emission methods. Dipole moments in the ground and excited states were measured in cyclohexane and dioxane. It is shown that the charge distributions in the 1-AN and 1,8-ANS molecules differ substantially. The spectral dependence of the electro-optical coefficients suggests that the absorption spectrum of 1,8-ANS is due to a superposition of (at least two) electronic transitions. It is found that spectra of 1-AN in erythocyte ghosts are inhomogeneously broadened. The above effect makes it possible to selectively excite probe m…

Molecular Stark-effect spectroscopy of Prodan and Laurdan in different solvents and electric dipole moments in their equilibrated ground and Franck–C…

2007

Abstract The results from electrooptical absorption measurements (EOAM) on the ground and excited Franck–Condon state dipole moments of Prodan and Laurdan in 1,4-dioxane and cyclohexane are presented. The ground and excited Franck–Condon state electric dipole moments as well as the respective transition moment of both probes are parallel. The electric dipole moments of Prodan and Laurdan in the ground state in cyclohexane and 1,4-dioxane have values within the range (15.7–16.5) × 10 −30  C m. On optical excitation the dipole moments increase by (42.1–49.5) × 10 −30  C m. The obtained results are compared with the values of the dipole moments of Prodan and Laurdan determined by other methods.

Dipole moments of aminophthalimides in the ground and excited electronic states

1995