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RESEARCH PRODUCT
Synthesis and molecular properties of donor–π-spacer–acceptor ynamides with up to four conjugated alkyne units
Bernhard WitulskiDieter SchollmeyerTorsten SchweikertNicolai A. Nemkovichsubject
Molecular ConformationAlkynechemistry.chemical_elementConjugated systemCrystallography X-RayPhotochemistryCatalysisMaterials ChemistryPhysics::Atomic PhysicsPhysics::Chemical Physicschemistry.chemical_classificationQuantitative Biology::BiomoleculesChemistryMetals and AlloysGeneral ChemistryTriple bondAmidesAcceptorSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsElectric dipole momentAlkynesIntramolecular forceExcited stateCeramics and CompositesSpectrophotometry Ultravioletsense organsCarbondescription
A set of push-pull ynamides with up to four conjugated triple bonds has been synthesized and the molecular properties of these new carbon rods have been characterised showing effective intramolecular charge transfers and high values for the change of the electrical dipole moment after transition from the ground to the Franck-Condon excited state.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-04-14 | Chemical Communications |