0000000000132751
AUTHOR
Adam Pietraszko
The structure and phase transition of tris(n-propylammonium) enneachlorodiantimonate (III),
The crystal structure of at 298 K has been determined (monoclinic, space group Cc, a = 19.464(2) ?, b = 17.736(2) ?, c = 8.116(2) ?, , Z = 4). The structure consists of one-dimensional polyanionic chains extended along the c-axis, and n-propylammonium cations located in elongated cavities formed by polyanions. The cations are connected to chlorine atoms by hydrogen bonds. Differential scanning calorimetry, the temperature dependence of the lattice parameters and static electric permittivity studies revealed a first-order phase transition at K of an `order - disorder' type. It is related to the ordering of n-propylammonium cations that occurs on decreasing the temperature. Debye-like dispers…
STRUCTURE AND PHASE TRANSITIONS IN [C(NH2)3]SbCl6 CRYSTALS
Abstract The crystal structure of [C(NH2)3]SbCl6 at 298 K (monoclinic, C2/m) and 240 K (monoclinic, P21/a) has been determined. The structure consists of isolated SbCl6− anions and guanidinium cations. Differential scanning calorimetry, dilatometric and dielectric studies revealed two structural phase transitions; a first-order one at 351 K and a second-order one at 265 K. One of the two crystallographically non-equivalent anions, SbCl6−(1), disordered in the room temperature phase is postulated to contribute to the phase transition mechanism at 265 K. A ferroelastic domain structure is found below 351 K.
The structure and phase transition of mixed crystals
The phase transition and molecular motions of methylammonium cations are studied in the temperature range from 110 to 450 K in the (x = 0.22, 0.345) (MACAB) crystal by x-ray DSC, dilatometric, dielectric and NMR techniques. It is shown that MACAB (x = 0.22) undergoes a structural phase transition at 222 K. The second moment of the NMR line () and the temperature dependence of spin lattice relaxation time () results are interpreted in terms of ( ion dynamics. In the high-temperature phase (I) the cations undergo isotropic reorientations. In the low-temperature phase (II) only one of three cations is still disordered, whereas the two others perform a type of reorientation about their C - N ax…
On structural phase transitions inn-butylammonium chloroantimonate(III) and chlorobismuthate(III) crystals: x-ray, differential scanning calorimetry, dilatometric and dielectric dispersion studies
Numerous structural phase transitions are detected in new crystals of the n-butylammonium compounds: , and by means of differential scanning calorimetry, dilatometric and dielectric dispersion (1 kHz - 1 MHz) studies. For the transitions the basic thermodynamic data are determined. Interesting dielectric properties are found in a metastable form of the crystals. Debye-like dispersion of the electric permittivity between 30 and 800 MHz is observed around the 310 K phase transition for this crystal. The activation energy of the reorientation of the n-butylammonium cations is found to be 16 kJ . The structure of ( form) has been refined to R = 0.0439 and shows isolated units and two non-equiva…