0000000000132808
AUTHOR
A. R. Esteve
In-situ integrating nephelometer measurements of the scattering properties of atmospheric aerosols at an urban coastal site in western Mediterranean
Abstract Measurements of aerosol scattering properties obtained during the period from March 2006 to December 2010 at Valencia (Spain) have been analyzed. The total aerosol scattering (σsp) and backscattering (σbsp) coefficients were measured using a TSI Model 3563 three-wavelength integrating nephelometer. From the measurements of σsp and σbsp, it was possible to determine also the scattering Angstrom exponent (αs). For the entire measurement period, the mean values (±standard deviation) at 550 nm are: 80 ± 50 Mm−1 for σsp; 8 ± 5 Mm−1 for σbsp; and 1.6 ± 0.3 for αs. These results indicate a moderate polluted atmosphere characterized by fine particles. The daily variation for all seasons sh…
UV Index experimental values on vertical surfaces
UV erythemal irradiance (UVER) has been studied on a horizontal plane and on vertical surfaces with different orientations in Valencia, Spain. The evolution of the solar noon value and the maximum daily value over a year has been analysed from the instantaneous UVER taken every five minutes on the horizontal plane and on vertical surfaces with north, south, east and west orientations. The annual evolution of these values shows a sinusoidal form for all planes except for the vertical south plane with maxima in spring and autumn. The UV Index (UVI) on these planes was also determined. The percentage of coincidence of the UVI at solar noon and of the maximum daily UVER values, considering diff…
Sources of discrepancy between aerosol optical depth obtained from AERONET and in-situ aircraft profiles
Abstract. Aerosol optical properties were measured by NOAA's Airborne Aerosol Observatory over Bondville, Illinois, during more than two years using a light aircraft. Measured properties included total light scattering, backscattering, and absorption, while calculated parameters included aerosol optical depth (AOD), Ångström exponent, single-scattering albedo, hemispheric backscatter fraction, asymmetry parameter, and submicrometer mode fraction of scattering. The in-situ aircraft measurements are compared here with AERONET measurements and retrievals of the aerosol optical properties at the same location, although it is difficult to verify the AERONET retrieval algorithm at a site that is …
A case study of the radiative effect of aerosols over Europe: EUCAARI-LONGREX
Abstract. The radiative effect of anthropogenic aerosols over Europe during the 2008 European Integrated Project on Aerosol Cloud Climate and Air Quality Interactions Long Range Experiment (EUCAARI-LONGREX) campaign has been calculated using measurements collected by the Facility for Airborne Atmospheric Measurements (FAAM) BAe-146 aircraft and radiative transfer modelling. The aircraft sampled anthropogenically perturbed air masses across north-western Europe under anticyclonic conditions with aerosol optical depths ranging from 0.047 to 0.357. For one specially designed “radiative closure” flight, simulated irradiances have been compared to radiation measurements for a case of aged Europe…
Relationship between UVB and broadband solar radiation in Spain
The daily values of UVB irradiation (290–315 nm), IUVB, and the broadband total irradiation (300–2800 nm), IT, measured on a horizontal plane have been correlated for the period 2000–2008 at 16 measurement sites in Spain. The results have been compared with the daily experimental values registered at the same sites during the period 2009–2011. The coefficients of determination R2 obtained by applying a linear regression are higher than 0.88 for all sites and increase to 0.94 when using a quadratic regression. When all data are considered together, the values of R2 are 0.91 and 0.97 for the linear and quadratic regressions, respectively. Three different clearness indices, which are dimension…
Ten years of measured UV Index from the Spanish UVB Radiometric Network.
An analysis is made of the UV Index (UVI) obtained from the ultraviolet erythemal solar radiation (UVER) data measured by the Spanish UVB Radiometric Network between the years 2000 and 2009. Previously, the daily UVI has been evaluated using two different criteria: (a) the value corresponding to solar noon; and (b) the daily maximum value. The mean percentage of agreement is 92% if we consider the cases for which the difference is zero or one UVI unit. These results are similar to those obtained in a previous work where only 2 years were analyzed. In all the stations the UVI reaches very high values (8-10) in spring-summer, and the very high and extreme (≥ 11) UVI values are more dependent …
Analysis of a severe pollution episode in Valencia (Spain) and its effect on ground level particulate matter
Abstract This study analyzes the atmospheric particles concentration at ground level during a severe pollution event that took place in Valencia (Spain) from 7 to 12 February 2011. The episode was related to a subtropical anticyclone system that affected the Iberian Peninsula and western Europe. The dominant anticyclone imposed an extended low gradient pressure system and a low mixing layer height in the region that caused the accumulation of pollutants over the western Mediterranean. Moreover, the stagnant conditions led to the formation of the local sea breeze, accompanied by an increase of relative humidity and the decrease of ambient temperature. Our study is mainly focused on the analy…
Analysis of the aerosol radiative forcing over a Mediterranean urban coastal site
Abstract The aerosol radiative forcing for the period 2003–2011 has been analyzed in Burjassot, Spain, an urban coastal site on the western Mediterranean, using measurements of global solar irradiance and aerosol properties, as well as simulated data. The aerosol radiative forcing was calculated at 5 minute intervals, and then integrated over 24 h to obtain daily mean values for 200 complete days under cloud-free skies. The monthly mean values of the aerosol radiative forcing showed a clear variation during the year, associated to the annual variability of the aerosol optical depth at 500 nm, ranging from − 6 to − 29 Wm− 2 at the surface, and from − 1.5 to − 3.9 Wm− 2 at the top of the atmo…
Estimation of daily average values of the Ångström turbidity coefficient β using a Corrected Yang Hybrid Model
This paper aims to test a method for estimating daily values of atmospheric turbidity from non-specialized data, such as those obtained from agro-meteorological stations. This method allows estimating the spatial and temporal evolution of aerosols concentration in more places than just those in which direct measurements are available. The method is based on the Corrected Yang Hybrid Model (CYHM). The data used in the determination of errors between measured and estimated values of the daily Angstrom turbidity coefficient β were recorded in Valencia, Spain, during 2009 and 2011. These data were global solar irradiance, direct solar irradiance, temperature, relative humidity and Aerosol Optic…
Influence of cloudiness over the values of erythemal radiation in Valencia, Spain
The influence of cloudiness over experimental UV erythemal radiation (UVER) has been studied. This influence has been analysed considering total cloudiness and low clouds. The measurements of cloudiness correspond to the daily values registered at 13:00 GMT at the Meteorological Centre of Valencia, which is part of the State Agency of Meteorology of Spain (AEMET). The UVER measurements were made using a YES UVB-1 radiometer located on the roof terrace of the Physics Faculty at the Burjassot Campus, Valencia (latitude 39.508° , longitude − 0.418° , 60 m above sea level). First, a statistical analysis of cloudiness at 13:00 GMT in Valencia was carried out, confirming that the situation is mai…
Study of erythemal, UV (A + B) and global solar radiation in Valencia (Spain)
Although ultraviolet B radiation (UVB), the solar radiation band between 280 and 315 nm, is only a small fraction of the extraterrestrial solar radiation, it accounts for 80% of the harmful effects of exposure to the sun. In this work values of erythemal solar irradiance (UVER) measured in Valencia on a horizontal plane in the period between June 2003 and June 2005 are analysed and compared with measures of UV (A+B) and global irradiances on a horizontal plane. UV erythemal (UVER) irradiance has been measured using a YES-UVB-1 broadband radiometer; UV (A+B) irradiance has been measured using a TUVR Eppley radiometer with spectral response between 290 and 385 nm and global irradiance on a ho…
Analysis of a strong wildfire event over Valencia (Spain) during Summer 2012 – Part 1: Aerosol microphysics and optical properties
Abstract. The most intense wildfire experienced in Eastern Spain since 2004 happened in Valencia during summer 2012. Although the fire was mostly active during days 29–30 June, a longer temporal period (from 24 June to 4 July) was selected for this analysis. Column-integrated, vertical resolved and surface aerosol observations were performed continuously at the Burjassot station throughout the studied period. The aerosol optical depth at 500 nm shows values larger than 2 for the most intense part of the wildfire and an extremely high maximum of 8 was detected on 29 June. The simultaneous increase of the Ångström exponent was also observed, indicating the important contribution of small part…
The influence of ozone and aerosols on the experimental values of UV erythemal radiation at ground level in Valencia
Ultraviolet erythemal radiation (UVER) values have been simulated for different values of column ozone and aerosol optical depth (AOD) using a multiple scattering model: SBDART. The results show that UVER decreased when atmospheric ozone and aerosols increased, with the ozone having greater influence than AOD. To quantify these dependencies the influence of aerosols on the simulated values of UVER has been analysed for different ozone values. This dependence was linear. Similarly, to quantify the influence of ozone on the UVER values this was simulated for fixed values of AOD while varying the column ozone. The expression of this dependence was found to be a second-order polynomial. We also…
UV Index on Tilted Surfaces
Solar ultraviolet erythemal irradiance (UVER) has been studied on inclined planes with different orientations in Valencia, Spain. To do this a platform was designed that could turn through 90 degrees on its own axis. The radiometers were inclined at an angle close to the latitude of Valencia (39.5 degrees N). Using two timers the platform could be turned through 90 degrees every 5 min. On clear or partially cloudy days, including those with different turbidity values, it was observed that the UVER showed a maximum at 1200 h GMT, very close to solar noon, in the north and south positions, while the maximum for east and west orientations was found at approximately one hour before and one hour…
The erythemal clearness index for Valencia, Spain
The values of three clearness indices have been measured for the city of Valencia: kt, the clearness index for the whole solar spectrum, ktUV the clearness index for the ultraviolet range, and the erythemal clearness index for the erythemal radiation ktUVER, corresponding to the solar radiation weighted by the erythemal action spectrum on human skin, normalized with respect to the solar constant corresponding to that spectrum. The measurements of ktUV reached values that were approximately 54% of that corresponding to kt, while those of ktUVER were much smaller. Some statistics of the erythemal clearness index have been calculated both for monthly as well as hourly means. The shape of the d…
UVER and UV index at high altitude in Northwestern Argentina
Measurements of ultraviolet erythemal radiation (UVER) made during two years at three sites located at altitudes over 1000 m a.s.l. in Northwestern Argentina (Salta, San Carlos, and El Rosal) have been used to estimate and analyze the UV Index (UVI) and the cumulative doses at these locations. For the UVER irradiance, data of January (maximum values) and June (minimum values) have been analyzed as representative of the year for all locations. The UVI reaches extreme (> 11) values in > 20% of the analyzed days in Salta (1190 m a.s.l.), while these are reached in San Carlos (1611 m a.s.l.) and El Rosal (3355 m a.s.l.) in > 40% of the analyzed days. Finally, the cumulative doses over an averag…
Measurement and analysis of broadband UVB solar radiation in Spain.
Measurements of broadband UVB irradiance (290-315 nm) at 14 locations in Spain for the period 2000-2009 have been used to generate instantaneous, hourly and daily values of irradiance (W m(-2)) and radiant exposure (kJ m(-2)). These measurements, and its statistical indices, have been analyzed. For the UVB irradiance, the values corresponding to July (maximum) and December (minimum) have been analyzed as representative of the year during the whole period for all locations. For the UVB radiant exposure, the temporal evolution of daily values has been evaluated for all locations to estimate an average yearly behavior. The accumulated radiant exposure for an average year has also been studied …
Proposal of a simple model for the characterization of aerosols in relation to the dominant air masses
In this work, we present a simple model that allows us to easily obtain the character of the dominant air mass for any location in the Northern Hemisphere at any time. Specifically, in this article the model has been tested at Valencia, Spain, for the years from 2006 to 2009. The classification of the air masses is performed analysing their trajectories over pre-defined source regions in the Northern Hemisphere. Daily trajectories were simulated by the hybrid single-particle Lagrangian integrated trajectory model HYSPLIT and then classified by our model. In order to verify our classification results, those cases identified as African were compared with the Saharan dust intrusions reported f…
Assessment and application of MODIS ocean and land algorithms for the characterization of aerosol properties over a Mediterranean coastal site
Abstract The aerosol optical depth (AOD) and Angstrom exponent (α) obtained from MODIS Terra and Aqua over the coastal urban site of Burjassot (Spain) during the period 2002–2011 have been compared with retrievals from AERONET (AErosol RObotic NETwork) and ESR (European Skynet Radiometers) in order to investigate the performance of MODIS algorithms over land and ocean, respectively. The comparison of the MODIS aerosol products C051 over both land and ocean has been performed for a window size of 50 km × 50 km centred on the monitoring site. The correlation coefficients obtained from the comparison of the AOD from MODIS with that from ground-based measurements are 0.85 and 0.87 over land for…
Relationship between erythemal UV and broadband solar irradiation at high altitude in Northwestern Argentina
An analysis of the broadband solar irradiation, IT, and the erythemal UV irradiation, IUVER, has been performed using the measurements made from 2013 to 2015 at three sites located at altitudes over 1000 m a.s.l. In Northwestern Argentina (Salta, El Rosal, and Tolar Grande). The main objective of this paper is to determine a relationship between IT and IUVER, which would allow to estimate IUVER from IT in places with few IUVER measurements available, and especially in those where is important to establish adequate photoprotection measures given their dense population and location at high altitude. The relationship between the daily values of IUVER and IT has been fitted to a linear regressi…
Diffuse ultraviolet erythemal irradiance on inclined planes: a comparison of experimental and modeled data.
Values of measured and modeled diffuse UV erythemal irradiance (UVER) for all sky conditions are compared on planes inclined at 40 degrees and oriented north, south, east and west. The models used for simulating diffuse UVER are of the geometric-type, mainly the Isotropic, Klucher, Hay, Muneer, Reindl and Schauberger models. To analyze the precision of the models, some statistical estimators were used such as root mean square deviation, mean absolute deviation and mean bias deviation. It was seen that all the analyzed models reproduce adequately the diffuse UVER on the south-facing plane, with greater discrepancies for the other inclined planes. When the models are applied to cloud-free con…
Impact of dust and smoke mixing on column-integrated aerosol properties from observations during a severe wildfire episode over Valencia (Spain)
The most destructive wildfire experienced in Spain since 2004 occurred close to Valencia in summer 2012. A total of 48.500ha were affected by two wildfires, which were mostly active during 29-30 June. The fresh smoke plume was detected at the Burjassot measurement station simultaneously to a severe dust episode. We propose an empirical method to evaluate the dust and smoke mixing and its impact on the microphysical and optical properties. For this, we combine direct-sun measurements with a Cimel CE-318 sun-photometer with an inversion methodology, and the Mie theory to derive the column-integrated size distribution, single scattering albedo (SSA) and asymmetry parameter (g). The mixing of d…
Evaluation of a High School Practical Experience on Noise Pollution With Smartphones
This work presents the evaluation of a practical experience on noise pollution based on the use of smartphones to check if it helps students to better understand the concepts related to this phenomenon. This evaluation has been done with a pre-post design in which 112 students, enrolled in the “Physics and Chemistry” course of the 1st year of non-compulsory high school, have first filled in a diagnostics questionnaire with 5 free response questions about their knowledge on the topic and then a pre-post questionnaire with 4 free response questions. The results show that the proposed practical experience is effective since a statistically significant improvement is obtained both globally and …
Multiyear in-situ measurements of atmospheric aerosol absorption properties at an urban coastal site in western Mediterranean
Abstract In-situ aerosol absorption properties measured in Valencia (Spain) for four years, from February 2011 to February 2015, have been analysed. Spectral absorption properties have been obtained using a seven-wavelength Aethalometer AE-31 which covers the range from UV (370 nm) to IR (950 nm). In order to obtain the absorption coefficients, compensation parameters have been calculated for the Aethalometer considering seasonal and spectral differences. For this multiyear measurement period, seasonal site-specific calibration parameters have been obtained. Furthermore, estimations of the absorption Angstrom Exponent (α abs ) have been calculated using the seven Aethalometer wavelengths. T…
Ozone mini-holes over Valencia (Spain) and their influence on the UV erythemal radiation
Low ozone level episodes (also known as mini-holes) have been analysed over Valencia, Spain, during the period from 1 January 2000 to 31 December 2007. In this study, 24 episodes, lasting 1 or 2 days each, were detected. Most of them can be explained dynamically by the existence of an anticyclone over the Azores, which sends air masses coming from the Caribbean over the Iberian Peninsula. A positive anomaly in the vertical temperature profile in the high troposphere and one negative anomaly in the medium and low stratosphere are also observed in most of the analysed episodes. The total ozone column decrease is accompanied by a rise in the UV erythemal radiation levels. This increase is quan…
Validación de los datos de radiación solar UV del Ozone Monitoring Instrument (OMI) a partir de medidas con base en tierra en la costa mediterránea
<p align="justify">The erythemal UV daily dose (EDD) and the local noon UV Index (UVI) obtained from the Ozone Monitoring Instrument (OMI), on board NASA’s Aura satellite, have been validated for the period 2005-2013 using ground based measurements at 5 different sites in the Mediterranean coast: Murcia, Valencia, Palma de Mallorca, Barcelona and Rome (where only measurements of the local noon UVI were available). Ground based measurements were made using YES UVB-1 radiometers in Murcia, Valencia, Palma de Mallorca and Barcelona, and a Brewer MKIV 067 spectrophotometer in Rome. The results of the validation showed good agreement between the satellite instrument and the ground based me…
Diffuse UV erythemal radiation experimental values
[1] Measurements of diffuse UV erythemal radiation (UVER) using a shadowband have been corrected using the models proposed by Drummond (1956), LeBaron et al. (1990), and Batlles et al. (1995). Two different methods were used to validate these models: intercomparison with an Optronic OL754 spectroradiometer and comparison with the values simulated by two radiative transfer codes, SMARTS and SBDART. For this comparison only clear days have been used. The corrected experimental values were analyzed in order to study the average values of the diffuse UVER fraction in relation to the clearness index kt. These varied between 62%, for kt close to 0.8, and 93% for kt of 0.2–0.3. Finally, a study of…
Statistical evaluation of aerosol retrievals from AERONET using in-situ aircraft measurements
Abstract. Aerosol optical properties were measured by NOAA's Airborne Aerosol Observatory over Bondville, Illinois, during more than two years using a light aircraft. Measured properties included total light scattering, backscattering, and absorption, while calculated parameters included aerosol optical depth (AOD), Ångström exponent, single-scattering albedo, hemispheric backscatter fraction, asymmetry parameter, and submicrometer mode fraction of scattering. The in-situ aircraft measurements are compared here with AERONET measurements and retrievals of the aerosol optical properties at the same location. The comparison reveals discrepancies between the aerosol properties retrieved from AE…
Determining the efficiency of optical sources using a smartphone's ambient light sensor
This work reports the use of a smartphone’s ambient light sensor as a valuable tool to study and characterize the efficiency of an optical source. Here, we have measured both luminous efficacy and efficiency of several optical sources (incandescent bulb and halogen lamp) as a function of the electric power consumed and the distance to the optical detector. The illuminance of LEDs as a function of the distance to the optical detector is characterized for different wavelength emissions. Analysis of the results confirms an inverse-square law of the illuminance with the detector–source distance and shows good agreement with values obtained by classical experiments. This experience will trigger …
Regional and seasonal radiative forcing by perturbations to aerosol and ozone precursor emissions
Abstract. Dedicated model simulations by four general circulation and chemistry-transport models are used to establish a matrix of specific radiative forcing, defined as the radiative forcing per unit change in mass emitted, as a function of the near-term climate forcer emitted, its source region, and the season of emission. Emissions of eight near-term climate forcers are reduced: sulphur dioxide, the precursor to sulphate aerosols; black carbon aerosols; organic carbon aerosols; ammonia, a precursor to nitrate aerosols; methane; and nitrogen oxides, carbon monoxide, and volatile organic compounds, the precursors to ozone and to secondary organic aerosols. The focus is on two source region…
Study of the correlation between columnar aerosol burden, suspended matter at ground and chemical components in a background European environment
Although routinely monitored by ground based air quality networks, the particulate matter distribution could be eventually better described with remote sensing techniques. However, valid relationships between ground level and columnar ground based quantities should be known beforehand. In this study we have performed a comparison between particulate matter measurements at ground level at different cut sizes (10, 2.5 and 1.0 mm), and the aerosol optical depth obtained by means of a ground based sunphotometer during a multiinstrumental field campaign held in El Arenosillo (Huelva, Spain) from 28 June to 4 July 2006. All the PM fractions were very well correlated with AOD with correlation coef…
A study on the sensitivities of simulated aerosol optical properties to composition and size distribution using airborne measurements
We present a flexible framework to calculate the optical properties of atmospheric aerosols at a given relative humidity based on their composition and size distribution. The similarity of this framework to climate model parameterisations allows rapid and extensive sensitivity tests of the impact of uncertainties in data or of new measurements on climate relevant aerosol properties. The data collected by the FAAM BAe-146 aircraft during the EUCAARI-LONGREX and VOCALS-REx campaigns have been used in a closure study to analyse the agreement between calculated and measured aerosol optical properties for two very different aerosol types. The agreement achieved for the EUCAARI-LONGREX flights is…