0000000000136629
AUTHOR
Antonella Iadecola
showing 2 related works from this author
Local structure of ball-milled LaNi5 hydrogen storage material by Ni K-edge EXAFS
2010
Abstract Local structure of the nanostructured LaNi5 hydrogen storage alloys, prepared by ball-milling, has been studied using Ni K-edge extended X-ray absorption fine structure spectroscopy. Results indicate that the ball-milling up to 100 h results in the production of nanoparticles characterized by large atomic disorder and slightly reduced unit-cell volume, compared to the bulk LaNi5. High temperature annealing appears to help in partial recovery of atomic order in the ball-milled samples; however, long-time ball-milled samples retain large disorder even after the high temperature annealing. The results suggest that the large disorder and the reduced unit-cell volume might be causing a …
Large atomic disorder in nanostructured LaNi5 alloys: A la L3-edge extended X-ray absorption fine structure study
2010
Abstract Local structure of the nanostructured LaNi 5 alloys, prepared by ball-milling, has been studied using La L 3 -edge extended X-ray absorption fine structure spectroscopy. The near-neighbor distances tend to decrease with the ball-milling, and the mean square relative displacements (MSRD) show substantial increase suggesting an increased atomic disorder. High temperature annealing helps in partial recovery of atomic order in the ball-milled samples for milling times upto 20 h, however, the long-time ball-milled samples seems to gain only a local random order. The results suggest that reduced unit-cell volume together with large atomic-disorder might be causing a higher energy-barrier…