0000000000139600
AUTHOR
J. Musielok
Experimental investigations of two doubly excited NI multiplets
Experimental Stark-broadening studies of two NI multiplets ( 1 D)3s 2 D - ( 1 D)3p 2 D° and ( 1 D)3s 2 D - ( 1 D) 3 p 2 F° are reported. Measurements were performed using a wall-stabilized arc operated at atmospheric pressure in helium with small amounts of nitrogen and hydrogen. The Stark broadening parameters: the electron impact width (w e ) and shift (d e ) have been determined.
Measurements of transition probabilities for two N I infrared transitions and their application for diagnostics of low temperature plasmas
Abstract Spectra emitted from a wall-stabilized arc, running in a gas mixture of helium, argon, nitrogen, oxygen and traces of hydrogen have been studied. Intensities of selected spectral transitions of neutral nitrogen and oxygen have been measured. Applying the Boltzmann plot method and using a reliable set of O I transition probabilities of spectral lines, originating from levels considerably spread in excitation energies, the temperatures of arc plasmas have been determined. Line intensities of two N I infrared transitions, originating from doubly excited terms 3p′ 2 F o and 3p′ 2 G have been measured. In order to obtain the corresponding transition probabilities ( A ki ) for these line…
Relative Transition Probability Measurements for Prominent Infrared Spectral Lines of NI
Applying a high-current wall-stabilized arc operated either in helium or in argon always with some admixtures of nitrogen, relative transition probabilities for more than 100 individual spectral lines (fine structure components) have been measured. The studied lines belong mainly to the 3p–3d and 3p–4s transition arrays. Ten lines of the measured set are intersystem transitions. Our data are compared with other experimental results (for about one half of the studied set there are available), with evaluated on the basis of the LS coupling scheme, with semiempirical data, and with recent CIV3 calculations. Some of our results are compared also with experimental data for the next member of the…
Transition probabilities for some infrared O I spectral lines—Application for determining excitation temperatures in low temperature plasmas
Intensities of selected spectral transitions of neutral oxygen emitted from a wall-stabilized arc have been measured. Applying reliable transition probability data taken from literature, Boltzmann plots have been constructed and the temperatures of the plasma have been obtained. At arc plasma conditions ensuring partial local thermal equilibrium, transition probabilities for 4 O I spectral lines from the near infrared spectral range have been obtained. These new results, together with data for two other studied O I spectral lines taken from the National Institute of Standards and Technology data base, are proposed as a suitable set of transition probabilities applicable for diagnostics of l…
Experimental studies of longitudinal demixing of plasma components in a wall-stabilized arc
We report observations of demixing effects caused by the electric field in a wall-stabilized arc operated at atmospheric pressure in helium with small admixture of CO 2 introduced in the central part of the arc column.
J-File Sum Rule Tests for the 3s-3p Transition Array in Singly Ionized Nitrogen - Comparison of Measured and Calculated Data
1. IntroductionIn recent years quite a large number of transition probabilities of spectrallines of light elements have been determined including data for singly ionizednitrogen [1{7]. Some of these experimental as well as theoretical studies providealso data for a few triplet{singlet intersystem transitions, being very interestinge.g. from astrophysical point of view. The energy level system of NII has adistinguished feature compared to the neighboring two members of the carbonisoelectronic sequence (CI, OIII) | the energy difierence between the excitedterms 3
Experimental and theoretical Stark broadening studies of the hydrogen Paschen beta line.
Experimental and theoretical Stark broadening studies of the Paschen beta line of hydrogen (lambda=1.28 microm) are reported. Line shape measurements were performed at electron densities of the plasma between 3.5 x 10(15) cm(-3) and 7.5 x 10(15) cm(-3), applying as the light source a wall-stabilized arc operated at atmospheric pressure in a helium-hydrogen gas mixture. The radiation of the plasma, emitted from nearly homogeneous plasma layers in the end-on direction, was registered with the use of a grating spectrometer equipped with a charge coupled device detector. The measured light outputs were calibrated against signals obtained from a tungsten strip radiation standard. The experimenta…
A new approach to determination of the asymmetry parameter of Stark-broadened isolated spectral lines
A new approach to evaluation of asymmetry parameters of Stark-broadened isolated spectral lines is presented. The procedure is discussed on the example of the N I line at λ = 9822.75 A. Line shape measurements were performed using a wall-stabilized arc, operated at atmospheric pressure. The radiation of the plasma, emitted from homogeneous plasma layers in end-on direction, was measured using a grating spectrometer equipped with a two-dimensional CCD detector. Griem-like profiles, convoluted with the corresponding Doppler and apparatus profiles, were fitted to experimental data. In this way the Stark broadening parameters (electron impact widths, shifts and asymmetry) have been determined. …
Calibration of the width of the NI spectral line at for electron density determination
Abstract The Stark broadening of a NI spectral line at 7915.42 A has been calibrated for electron density determination of low temperature plasmas. The determined simple formula based on measured FWHM is applicable in the electron density range from 3×1015 to 10 16 cm −3 .
Experimental Stark broadening studies of the CI transition 3s 1 P 1o − 3p 1 S 0 at 833.5 nm
AbstractExperimental Stark broadening studies of the infrared CI transition 3s 1 P 1o − 3p 1 S 0 at 833.5 nm are reported for the first time. A high-current wall-stabilized arc, operated in a mixture of helium, argon, carbon dioxide and hydrogen, was applied as the plasma source. Radiation emitted from homogeneous and optically thin plasma layers was analyzed. Stark broadening studies of the selected CI transition and the hydrogen Balmer β line were performed. As expected from theoretical considerations, the CI line width depends linearly on the electron density of the plasma. Applying theoretical Stark broadening data for the Hgb line, the measured Stark widths of the CI line were calibrat…
Diagnostics of Helium-Argon Arc Discharge Plasma Based on Spectral Line Shape Measurements
Electron densities and ion (gas) temperatures on the axis of an arc discharge plasma, produced at atmospheric pressure in a gas mixture of 95% helium and 5% argon, are determined at two arc currents. The evaluation of both main plasma parameters is based on line shape measurements, the ion temperature on the Doppler broadening of selected ArII lines, while the electron density on the Stark broadening of the hydrogen Hp line which appear in the spectrum due to hydrogen traces in the applied gases. The significance of reliable plasma diagnostics for determination of atomic structure data is discussed.
Paschen β line shape studies in low-temperature plasmas
Line shape calculations and measurements of the Paschen β line of hydrogen (λ=12818 Å) are reported. Measurements were performed at electron densities of the plasma between 1015 cm-3 and 1016 cm-3. A wall-stabilized arc operated at atmospheric pressure in a helium-hydrogen gas mixture was applied as the excitation source. The radiation of the plasma, originating from nearly homogeneous plasma layers, in the end-on direction, was analyzed. A grating spectrometer equipped with a CCD detector was used for the radiation detection. The measured line profiles are compared with results of available experimental and theoretical Stark broadening data e.g. based on simulation techniques, applied also…
Experimental Stark-broadening studies of the NI multiplet $\mathsf{(^{1}D) 3s^{2}D - (^{1}D)3p^{2}P^{o}}$ at 7904.5 �
Experimental Stark-broadening studies of the NI multiplet $(^{1}{\rm D})3s$ $^{2}{\rm D} - (^{1}{\rm D})3p$ $^{2}{\rm P}^{\rm o}$ are reported. Line shape measurements were performed using a wall-stabilized arc operated at atmospheric pressure in helium with small amounts of nitrogen and hydrogen. The radiation of the plasma emitted from nearly homogeneous plasma layers in end-on direction was measured using a grating spectrometer equipped with a charge-coupled device (CCD) detector. The arc current was varied from 35 to 50 A in order to obtain different plasma conditions (electron densities and temperatures). The so-called j(x) profiles of Griem, convoluted with the corresponding Doppler a…
NEW SPECTROSCOPIC DATA FOR DIAGNOSTICS OF LOW TEMPERATURE PLASMAS
Calculation of Population Densities of Excited CI and CII Levels in Helium and Argon Plasmas Containing Small Admixtures of CO2- Importance to Analysis of Radiation Emitted from Plasmas of Axial Symmetry
Measurements of relative line strengths in N I multiplets for transition arrays 3s–np (n=3, 4, 5)
Abstract Applying the emission method, intensities of 60 spectral lines of neutral nitrogen (N I) belonging to 15 multiplets originating from 3s–np (n=3, 4, 5) transition arrays have been measured. A wall-stabilized arc, operated at atmospheric pressure in helium with some admixture of nitrogen was applied as the excitation source. From measured line intensities, relative line strengths within multiplets have been evaluated. For transitions with Δn=1 and 2, significantly larger discrepancies from LS coupling results are found if compared to transitions 3s–3p (Δn=0). The measured relative line strengths within 3s–3p multiplets are compared with older measurements, recent calculations and wit…
Stark broadening of the hydrogen Paschen ? transition at electron densities of the order of $ \mathsf {10^{15}}$ cm $ \mathsf {^{-3}}$
Stark broadening measurements and calculations of the Paschen γ spectral line of hydrogen ( λ = 1.094[: MU :] m) are reported. Investigations have been performed at plasma electron densities between 1.4×10 15 cm -3 and 3.7×10 15 cm -3 . As the light source a wall-stabilized arc operated in a helium-hydrogen gas mixture at atmospheric pressure has been applied. The radiation of the plasma emitted from nearly homogeneous plasma layers in end-on direction, was measured with the use of a grating spectrometer equipped with a charge coupled device (CCD) detector. The radiance calibration was carried out against light outputs originating from a tungsten strip radiation standard. The measured FWHM …
Regularities of Line Strengths in Spectra of NI, FI, and NeII
Recently experimentally determined individual (fine structure) line strengths for the spectra of NI, FI, and NeII are analysed, searching for regu- larities resulting from similarities in the structure of these species. Strengths of spectral lines of the prominent 3S-3p and 3p-3d transition arrays are investigated. The absolute scales of these experimentally derived data are based on independently determined lifetimes for excited levels of NI, FI, and NeII. The simple Coulomb approximation method was applied for calcula- tions of the matrix elements for the "jumping" electron in order to obtain an average trend in line strengths of the studied emitters. In the case of the isoelectronic spec…