0000000000144636
AUTHOR
Francisco Guinea
Strain Switching in van der Waals Heterostructures triggered by a Spin-Crossover Metal Organic Framework
Van der Waals heterostructures (vdWHs) combine different layered materials with properties of interest,1 such as two-dimensional (2D) semimetals, semiconductors, magnets or superconductors. These heterostructures provide the possibility of engineering new materials with emergent functionalities that are not accessible in another way. Beyond inorganic 2D materials, layered molecular materials remain still rather unexplored, with only few examples regarding their isolation as atomically thin-layers. By a proper chemical design, the physical properties of these systems can be tuned, as illustrated by the so-called spin-crossover (SCO) compounds, in which a spin transition can be induced by app…
Enhanced superconductivity in atomically thin TaS2
The ability to exfoliate layered materials down to the single layer limit has presented the opportunity to understand how a gradual reduction in dimensionality affects the properties of bulk materials. Here we use this top–down approach to address the problem of superconductivity in the two-dimensional limit. The transport properties of electronic devices based on 2H tantalum disulfide flakes of different thicknesses are presented. We observe that superconductivity persists down to the thinnest layer investigated (3.5 nm), and interestingly, we find a pronounced enhancement in the critical temperature from 0.5 to 2.2 K as the layers are thinned down. In addition, we propose a tight-binding …
Zero-bias conductance peak in detached flakes of superconducting 2H-TaS2probed by scanning tunneling spectroscopy
We report an anomalous tunneling conductance with a zero-bias peak in flakes of superconducting 2$H$-${\mathrm{TaS}}_{2}$ detached through mechanical exfoliation. To explain the observed phenomenon, we construct a minimal model for a single unit cell layer of superconducting 2$H$-${\mathrm{TaS}}_{2}$ with a simplified two-dimensional Fermi surface and a sign-changing Cooper-pair wave function induced by Coulomb repulsion. Superconductivity is induced in the central $\ensuremath{\Gamma}$ pocket, where it becomes nodal. We show that weak scattering at the nodal Fermi surface, produced by nonperturbative coupling between tip and sample, gives Andreev states that lead to a zero-bias peak in the…