0000000000146984

AUTHOR

Yeshayahu Talmon

showing 3 related works from this author

Complexes of star-shaped cationic polyelectrolytes with anionic liposomes: Towards multi-liposomal assemblies with controllable stability

2016

Abstract Complexes were formed via the electrostatic interaction between 30–50 nm anionic liposomes and a star-shaped polyelectrolyte, poly{[2-(methacryloyloxy)ethyl]trimethyl ammonium iodide}, having cationic arms that radiate from a silicon-based central core. The complexation was investigated with attention given to assessing the capacity of the cationic stars for the anionic liposomes (both liquid and solid); the integrity of the complexed liposomes; and the stability of the resulting star/liposome complexes in aqueous salt solutions. We have found that by changing the content of anionic groups in the liposomal membrane as well as the phase-state of membrane, the stability of star/lipos…

chemistry.chemical_classificationendocrine systemLiposomeAqueous solutionPolymers and PlasticsChemistryOrganic ChemistryCationic polymerizationSalt (chemistry)02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesPolyelectrolyteAmmonium iodide0104 chemical scienceschemistry.chemical_compoundMembranePolymer chemistryMaterials ChemistryOrganic chemistrySelf-assembly0210 nano-technologyPolymer
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The Largest Synthetic Structure with Molecular Precision: Towards a Molecular Object

2010

Pushing the limits: A 200A - 10 Da structurally defined, linear macromolecule (PG5) has a molar mass, cross-section dimension, and cylindrical shape that are comparable to some naturally occurring objects, such as amyloid fibrils or certain plant viruses. The macromolecule is resistant against flattening out on a surface; the picture shows PG5 embracing the tobacco mosaic virus (TMV).

Macromolecular SubstancesPolymersStereochemistryviruses02 engineering and technologyMicroscopy Atomic Force010402 general chemistry01 natural sciencesCatalysisFlatteningPlant virusScattering Small AngleTobacco mosaic virus[SDV.IB.BIO]Life Sciences [q-bio]/Bioengineering/BiomaterialsComputingMilieux_MISCELLANEOUSMESH: Scattering Small Anglechemistry.chemical_classificationMESH: Microscopy Atomic ForceMolar mass010405 organic chemistryMacromolecular SubstancesGeneral ChemistryPolymerMESH: Macromolecular SubstancesGeneral Medicine021001 nanoscience & nanotechnologyAmyloid fibrilMESH: Polymers0104 chemical sciencesTobacco Mosaic ViruschemistryChemical physicsMESH: Tobacco Mosaic Virus0210 nano-technologyMacromoleculeAngewandte Chemie
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Electron Diffraction and Imaging of Uncompressed Monolayers of Amphiphilic Molecules on Vitreous and Hexagonal Ice

1993

A new approach is described for probing domains of ordered self-assemblies of amphiphilic monolayers at the aqueous solution interface. The method has potential importance for the study of membrane structure, Langmuir-Blodgett films, and nucleation processes of two-and three-dimensional crystals. Electron diffraction (ED) patterns indicative of two-dimensional crystalline self-assembly were obtained from samples, which were examined by cryo-electron microscopy, of monolayers of water-insoluble amphiphiles on vitrified aqueour substrates. The apparent hexagonal symmetry of an ED pattern from a C(16)H(33)OH monolayer was interpreted in terms of multiple twinning. Monolayers of the CL(31)H(63)…

CrystallographyMultidisciplinaryAqueous solutionElectron diffractionChemistryStereochemistryMonolayerMicroscopyNucleationCrystalliteCrystal twinningEpitaxyScience
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