Visible Light Generation and its Influence on Supercontinuum in Chalcogenide As2S3 Microstructured Optical Fiber

We demonstrate visible light generation in chalcogenide As2S3 microstructured optical fiber. The generated visible light causes irreversible damage to the fiber core because of the high absorption coefficient of chalcogenide glasses in the visible band. The SCs (supercontinua) are measured in both untapered and tapered As2S3 fibers, no wider SC is obtained in the tapered one. The SC growth is prevented by the visible light generation since the damage to the fiber core decreases the fiber transmission substantially. This effect can be avoided by designing the fiber to enable the pump source to work in single-mode operation.

Demonstration of Experimental Infrared Spectral Broadening in Chalcogenide As2S3 Suspended Core Microstructured Optical Fibers

International audience

Flux growth at 1230 °C of cubic Tb2O3 single crystals and characterization of their optical and magnetic properties

International audience; In this work, we present the first crystal growth of cubic Tb2O3 single crystals by a controlled atmosphere flux method which uses a heavy metal free solvent working at less than half the melting temperature of this sesquioxide. Cubic millimeter-sized crystals extracted from as-grown boules are phase (powder XRD) and chemically (GDMS) pure and exhibit a Verdet constant in the visible and near-infrared spectral ranges, which is at least three times higher than that of a commercial Tb3Ga5O12 (TGG) crystal. The 1.36 mm thick crystals display a transmission coefficient higher than 77% over the 525 nm–1.38 μm spectral range. The absorption spectrum, magnetic susceptibilit…

Microstructured Optical Fibers from As2S3 Glass for Fiber Optics Sources in the MIR range

International audience

Recent developments in chalcogenide photonic crystal fibres

Elaboration of low-losses highly non linear chalcogenide optical fibers for the generation of efficient non linear effects in the infrared remains a challenge. In recent years, much work has been devoted to the study of microstructured optical fibers (MOFs) with different designs and various elaboration processes. Their background losses were typically of several dB/m.

Second zero dispersion wavelength measurement through soliton self-frequency shift compensation in suspended core fibre

International audience; A simple experimental technique to evaluate the second zero dispersion wavelength of very small core microstrutured fibres is described. Based on the effect of soliton self-frequency shift and its subsequent compensation in the vicinity of the second zero dispersion. the proposed method is applied to both standard and suspended core microstructured fibres by simply measuring the frequency stabilised soliton spectrum, avoiding any calculation and knowledge of any experimental parameters.

Impact of optical and structural aging in As_2S_3 microstructured optical fibers on mid-infrared supercontinuum generation

We analyze optical and structural aging in As2S3 microstructured optical fibers (MOFs) that may have an impact on mid-infrared supercontinuum generation. A strong alteration of optical transparency at the fundamental OH absorption peak is measured for high-purity As2S3 MOF stored in atmospheric conditions. The surface evolution and inherent deviation of corresponding chemical composition confirm that the optical and chemical properties of MOFs degrade upon exposure to ambient conditions because of counteractive surface process. This phenomenon substantially reduces the optical quality of the MOFs and therefore restrains the spectral expansion of generated supercontinuum. This aging process …

Manipulation of fast light using photorefractive beam fanning

Light pulse group velocity manipulations due to the specific dispersion of a medium (so-called “slow” and “fast” light phenomena) can be obtained on the basis of several mechanisms. One of these techniques is two-wave mixing in a photorefractive crystal. This work presents a modification of this method, exploiting the strong beam fanning in Sb-doped Sn2P2S6 crystals. Our experimental results demonstrate a “fast light” behavior of Gaussian pulses transmitted through a Sn2P2S6:Sb sample. The phenomenon is due to the beam fanning (i.e., the self-diffraction of the incident beam on self-induced noisy photorefractive gratings) that ensures a significant depletion of the input beam. Due to the re…

Enhanced photorefractive properties of Bi-doped Sn2P2S6

International audience; Enhanced photorefractive properties of tin hypothiodiphosphate (Sn2P2S6) crystals as a result of Bi doping are presented. These new crystals were obtained by the vapor-transport technique using stoichiometric Sn2P2S6 composition with an additional amount of Bi up to 0.5 mol. % in the initial compound. The bandgap edges of the obtained crystals are located at ~750 nm and shift toward the red wavelengths with increasing Bi concentration. Sn2P2S6:Bi crystals are found to exhibit larger two-beam coupling gain coefficients (up to 17 cm−1 at a wavelength of 854 nm) as compared to (i) pure Sn2P2S6 (2.5 cm−1 at 854 nm), (ii) Sn2P2S6 crystals modified by the growth conditions…

Visible Light Generation and Its Influence to Supercontinuum in As2S3 Microstructured Fiber

We demonstrate visible light generation in As 2 S 3 microstructured fiber for the first time. It limits the spectral range of supercontinuum. The visible light generation can be avoided by designing the fiber for the single-mode operation.

Slow light with photorefractive four-wave mixing

A slowing down of light pulses using backward-wave four-wave mixing is achieved in photorefractive crystals with different coupling strength. The delay and width of the output pulse are studied as a function of the input pulse width and pump intensity ratio for the amplified transmitted beam and for the phase-conjugated beam. The delay characteristics are compared with those of the two-beam coupling. It is demonstrated that the four-wave mixing process ensures a larger slowing down of short pulses (pulses with width shorter than the photorefractive response time) as compared to the photorefractive two-beam coupling scheme and guarantees the elimination of forerunners. The delay of long puls…

Accordabilité thermique des interactions ONL: formalisme vectoriel et applications à HGS, KTP et RTP

National audience

Low losses highly non linear As2S3 suspended core microstructured optical fibers

International audience

Recent developments in chalcogenide PCF

International audience

TeO2-ZnO-La2O3 tellurite glass system investigation for mid-infrared robust optical fibers manufacturing

Abstract TeO2-ZnO-La2O3 (TZL) ternary glasses were investigated in order to manufacture step-index optical fibers with low optical losses in the near- and mid-infrared ranges and superior mechanical properties. To identify appropriate TZL glass compositions for optical fibers manufacturing, the whole vitreous domain of the ternary diagram was explored by characterizing bulk samples from thermal and optical point of view. Investigations were focused on understanding how the refractive index evolves as a function of the composition. For this, several parameters were analyzed such as density, molar volume, oxygen packing density, molar refractivity, polarizability and optical basicity. Finally…

Thiogallate de mercure (HgGa2S4) : un cristal pour les OPO dans le moyen infrarouge

Comprehensive formulation of temperature-dependent dispersion of optical materials: illustration with case of temperature tuning of a mid-IR HgGa_2S_4 OPO

The temperature dependence of refractive indices of optical materials is characterized in this work by what we call their normalized thermo-optic coefficients. These are determined experimentally through interferometric measurements of thermal expansion and of changes in optical thickness at a few laser wavelengths as function of temperature. A suitable vectorial formalism applied to these data allows predicting the thermal evolution of the refractive index all over the useful range of transparency. The validity and reliability of our methodology is demonstrated through temperature tuning of a mid-IR HgGa2S4 optical parametric oscillator (OPO) pumped at 1.0642 μm by a Nd:YAG laser. Measured…

3.5-μm bandwidth mid-infrared supercontinuum generation in a 2-cm long suspended-core chalcogenide fiber

A supercontinuum source extending from 0.6 to 4.1 µm has been successfully generated in a 2-cm long As2S3 chalcogenide suspended-core fiber by means of a nJ-level 200-fs pumping at 2.5 µm.

Optical characterization of YCa4O(BO3)3 and Nd:YCa4O(BO3)3 crystals

International audience; We report a complete optical characterization of YCa4O(BO3)3 and Nd:YCa4O(BO3)3 crystals. We studied the relative orientation between the dielectric and the crystallographic frames as a function of the wavelength and performed accurate phase-matching angles measurements for second harmonic generation, using a single crystal cut as a sphere. We also recorded polarized luminescence spectra of Nd:YCOB along the principal axes of the dielectric frame. For both crystals, we measured the gray-tracking and the thermo-optic properties as a function of temperature and wavelength using oriented slabs. Finally, we measured all their dielectric and electro-optic coefficients, as…

Slowing down of light pulses using backward-wave four-wave mixing with local response

The slowing down of light pulses is achieved using backward-wave four-wave mixing in a medium with local response. A Bi12TiO20 crystal with an external dc field is used in the experiment as a proof-of-concept material. The delay and shape transformation of output pulses are studied and compared for the transmitted and phase conjugate channels. It is shown that the phase conjugate pulse achieves a longer delay under typical experimental conditions with equal intensities of the pump beams. This advantage of the phase conjugate beam is especially pronounced for short pulses with half-widths smaller than the response time of the medium. The agreement of the experimental results with numerical c…

Atmospheric aging and surface degradation in As2S3 fibers in relation with suspended-core profile

Abstract Microstructured optical fibers (MOF) can be seen as next generation fiber of significance in advancing the compact optics because of its excellent compatibility in integrated optics. However, the degradation of their physicochemical properties limits their efficiency and lifetime. Atmospheric moisture is responsible for the degradation of amorphous systems especially chalcogenide glasses. In the light of previously reported studies, in order to clarify the aging process continuously evolving in sulfide microstructured optical fiber over time, a detailed investigation of this phenomenon has been conducted. The time-dependent transmission and glass chemical deterioration have been st…

Enhanced supercontinuum generation in tapered tellurite suspended core fiber

Abstract We demonstrate 400-THz (0.6–3.3 µm) bandwidth infrared supercontinuum generation in a 10 cm-long tapered tellurite suspended core fiber pumped by nJ-level 200-fs pulses from an optical parametric oscillator. The increased nonlinearity and dispersion engineering extended by the moderate reduction of the fiber core size are exploited for supercontinuum optimization on both frequency edges (i.e., 155-THz overall gain), while keeping efficient power coupling into the untapered fiber input. The remaining limitation of supercontinuum bandwidth is related to the presence of the high absorption beyond 3 µm whereas spectral broadening is expected to fully cover the glass transmission window…

Filament-induced visible-to-mid-IR supercontinuum in a ZnSe crystal: Towards multi-octave supercontinuum absorption spectroscopy

Abstract We report on the generation of multiple-octave supercontinuum laser source spanning from 0.5 μm to 11 μm induced by multi-filamentation in a ZnSe crystal. The generated supercontinuum is both spatially and spectrally characterized. It is then exploited in a proof-of-principle experiment for methane spectroscopy measurements by means of the supercontinuum absorption spectroscopy technique. The entire absorption spectrum is successfully recorded within the whole spectral bandwidth of the supercontinuum. Experimental results are in fairly good agreement with the HITRAN database, confirming the reliability and stability over several hours of the generated supercontinuum.

Photorefractive “camera obscura”

Abstract We demonstrate a novel scheme for lensless image formation which combines the properties of an amplifying dynamic hologram and a pinhole camera. The scheme is realized on the base of a SPS:Sb1% photorefractive crystal working at 633 nm.

Strong infrared spectral broadening in low-loss As-S chalcogenide suspended core microstructured optical fibers

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Absolute instability in backward wave four-wave mixing: spatial effects

The spatial distribution of new beams generated above the threshold of absolute instability of two counterpropagating incoherent light waves is studied and compared with the results of calculation.

Mid-infrared supercontinuum generation in suspended-core Chalcogenide and Tellurite optical fibers

We report the experimental generation of mid-infrared supercontinuum in tellurite and chalcogenide suspended-core fibers pumped close to their zero-dispersion in femtosecond regime. The resulting supercontinua extend until 2.8µm in tellurite and 3.2µm in chalcogenide fibers.

Photorefractive and photochromic effects in Sn2P2S6 at various temperatures

Abstract Photochromic effect in nominally pure and doped Sn 2 P 2 S 6 photorefractive crystals is investigated in the temperature range 120–310 K. This effect determines a mechanism of the amplitude hologram formation at low temperatures, and we show that a competition between the photorefractive (phase) and the amplitude gratings occurs at increasing temperature.

Photonic crystal fibers from chalcogenide glasses for the mid infrared

International audience

Optical hysteresis in a semilinear photorefractive coherent oscillator

International audience; High contrast optical bistability is found experimentally in the pump-ratio dependences of the output intensity of a semilinear photorefractive coherent oscillator with two counterpropagating pump waves. The data are in qualitative agreement with the results of calculation.

Multioctave midinfrared supercontinuum generation in suspended-core chalcogenide fibers

An As2S3 fiber-based supercontinuum source that covers 3500 nm, extending from near visible to the midinfrared, is successfully reported by using a 200-fs-pulsed pump with nJ-level energy at 2.5 μm. The main features of our fiber-based source are two-fold. On the one hand, a low-loss As2S3 microstructured optical fiber has been fabricated, with typical attenuation below 2 dB/m in the 1-4 μm wavelength range. On the other hand, a 20-mm-long microstructured fiber sample is sufficient to enable a spectral broadening, spreading from 0.6 to 4.1 μm in a 40 dB dynamic range.

Investigation of the Na2O/Ag2O ratio on the synthesis conditions and properties of the 80TeO2–10ZnO–[(10−x)Na2O–xAg2O] glasses

International audience; Properties of the tellurite glasses 80TeO2–10ZnO–[(10−x)Na2O–xAg2O] are investigated as a function of the substitution ratio x between Na2O and Ag2O. One observe that the variation of glass transition temperature decreases monotonously with x and that surface crystallization mechanism is favored. The assignment of the Raman bands and their relation with the underlying glass structure is discussed. While both Na2O and Ag2O oxides act as glass network modifiers, their progressive equimolar substitution does not lead to a meaningful evolution in the structure of the TZ[Na10-xAgx] glass. The refractive index and the cut-off wavelength are found to increase with x. The co…

Supercontinuum Generation in Tellurite Optical Fibers

This chapter presents a state of the art of infrared supercontinuum generation in heavy oxide tellurite optical fibers from the experimental results published by the international community. As a first part, a bibliographic table gathers the literature on which this work is based. Then, the second part briefly returns on the tellurite glass compositions, the third part presents the different fiber structures (microstructured, suspended core or step-index fibers, tapered fibers), the fourth part discusses the pumping sources in relation with the fiber chromatic dispersion as well as coupling issues, the supercontinuum performances are presented in the fifth part, and the sixth part deals wit…

Infrared Photonic Crystal Fibers from chalcogenide glasses for non linear optical applications

International audience

Dispersion and temperature dependence of thermo-optic coefficients of optical materials over their whole transparency range: vectorial formalism and application to KTiOPO4 and HgGa2S4

Recent advances in chalcogenide holey fibres

oral

Mid-infrared 2000-nm bandwidth supercontinuum generation in suspended-core microstructured Sulfide and Tellurite optical fibers

International audience; In this work, we report the experimental observation of supercontinua generation in two kinds of suspended-core microstructured soft-glass optical fibers. Low loss, highly nonlinear, tellurite and As2S3 chalcogenide fibers have been fabricated and pumped close to their zero-dispersion wavelength in the femtosecond regime by means of an optical parametric oscillator pumped by a Ti:Sapphire laser. When coupled into the fibers, the femtosecond pulses result in 2000-nm bandwidth supercontinua reaching the Mid-Infrared region and extending from 750 nm to 2.8 mu m in tellurite fibers and 1 mu m to 3.2 mu m in chalcogenide fibers, respectively.

Optical aging behaviour naturally induced on As_2S_3 microstructured optical fibres

The efficiency and the stability of As2S3 microstructured optical fibres (MOFs) are limited by the shift of their optical properties that occurs over time due to a naturally induced aging process. Such sensitivity becomes more crucial for long optical path. Among the variety of fibre designs, the MOFs are developed for promising photonics applications such as supercontinuum generation for example. In the present work, we carried out an extensive aging study on As2S3 chalcogenide MOFs in ambient atmosphere. The evolution of the fibre transmission spectrum has been studied with regards to exposure time. The analysis of the transmission line profile was performed in terms of different spectral…

Mid-infrared supercontinuum generation in suspended-core chalcogenide and tellurite optical fibers

Summary form only given. The generation of optical supercontinua in the mid-infrared region and especially their expansion beyond the intrinsic limit dictated by fused silica is currently a subject of high interest. Tellurite and chalcogenide glasses have serious advantages because of their wide transmittance window which can reach more than 10 μm while the Kerr nonlinearity can be 500 times stronger than fused silica. These different features make them serious candidates for broad mid-infrared supercontinuum generation. For example, supercontinuum as broad as 4000-nm bandwidth has been generated in a sub-cm long Tellurite microstructured fiber by Domachuk et al. in ref. [1] by means of a f…

Er3+-doped GeGaSbS glasses for mid-IR fibre laser application: Synthesis and rare earth spectroscopy

International audience; With an infrared transparency extended to 10 µm, low multiphonon relaxation rates and suitable rare earth solubility, sulphide glasses in the Ge-Ga-Sb-S system allow radiative emission from rare earth ions in the mid-IR range. The Er3+ ion, widely studied in glass fibres for optical amplification at 1.5 µm, presents an interesting transition for mid-IR applications around 4.5 µm (4I9/2→ 4I11/2). Thus, the aim of this work is to evaluate the Er3+-doped Ge20Ga5Sb10S65 glass as a potential fibre laser source operating in the 3-5 µm mid-IR spectral region. For that purpose, absorption and emission spectra were recorded from visible to mid-IR and the radiative lifetimes o…

Cristaux laser non linéaires de borates

Management of OH absorption in tellurite optical fibers and related supercontinuum generation

Abstract We report the fabrication and the characterization of low OH content and low loss tellurite optical fibers. The influence of different methods of glass fabrication on fiber losses has been investigated. The use of the purest commercial raw materials can reduce the losses below 0.1 dB/m at 1.55 μm. Incorporation of fluoride ions into the tellurite glass matrix makes the optical fibers transparent up to 4 μm. A suspended core microstructured fiber has been fabricated and pumped by nanojoule-level femtosecond pulses, thus resulting in more than 2000-nm bandwidth supercontinuum after a few centimeters of propagation.

Suspended core tellurite glass optical fibers for infrared supercontinuum generation

International audience; We report the fabrication and characterization of tellurite TeO(2)-ZnO-Na(2)O (TZN) microstructured suspended core optical fibers (MOFs). These fibers are designed for infrared supercontinuum generation with zero dispersion wavelength (ZDW) at 1.451 mu m. The measured losses at this wavelength are approximately 6 dB/m for a MOF with a 2.2 mu m diameter core. The effective area of a particular fiber is 3.5 mu m(2) and the nonlinear coefficient is calculated to be 437 W(-1)km(-1). By pumping a 20 cm long fiber at 1.56 mu m with a sub-nj femtosecond laser source, we generate a supercontinuum (SC) spanning over 800 nm in the 1-2 mu m wavelength range.

Microstructured chalcogenide optical fibers from As2S3 glass: towards new IR broadband sources

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