Zircon M257 - a homogeneous natural reference material for the ion microprobe U-Pb analysis of zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U-Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS-determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U-Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ∼ 840 μg g−1 U (Th/U ∼ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of…

Palaeoproterozoic ancestry of Pan-African high-grade granitoids in southernmost India: Implications for Gondwana reconstructions

Abstract SHRIMP dating of magmatic zircons from granitoid gneisses and charnockites of the Trivandrum and Nagercoil Blocks in the granulite terrane of southernmost India yielded well-defined protolith emplacement ages between 1765 and ca. 2100 Ma and also document variable recrystallization and/or lead-loss during the late Neoproterozoic Pan-African event at around 540 Ma. Hf-in-zircon and whole rock Nd isotopic data suggest that the granitoid host rocks were derived from mixed crustal sources, and Hf–Nd model ages vary between 2.2 and 2.8 Ga. A gabbroic dyke, emplaced into a charnockite protolith and deformed together with it, only contained metamorphic zircon whose mean age of 542.3 ± 4.0…

Geochemistry and SHRIMP U-Pb Zircon Dating of Mafic Rocks North of Zunhua City, Eastern Hebei, North China Craton: Paleoproterozoic Gabbro rather than Neoarchean Ophiolite

Generation of early Archaean grey gneisses through melting of older crust in the eastern Kaapvaal craton, southern Africa

Abstract We report zircon ages, Hf-in-zircon isotopes as well as whole-rock geochemistry and Hf–Nd isotopic systematics for Palaeoarchaean grey gneisses of the Ancient Gneiss Complex of Swaziland, the oldest components of the Kaapvaal craton, southern Africa. The Hf-in-zircon isotopic compositions in these compositionally heterogeneous, multicomponent, migmatitic gneisses are highly variable, even in the oldest zircons dating back to 3.66 Ga, suggesting growth of zircon from melts representing a mix of juvenile and anatectic material derived from differentiated continental crust of Eoarchean to late Hadean age. In contrast, the initial Nd and Hf whole-rock isotopic compositions are frequent…

Generation of early Archaean felsic greenstone volcanic rocks through crustal melting in the Kaapvaal, craton, southern Africa

Abstract High-potassium felsic volcanic rocks interlayered with basalt and komatiite in early Archaean greenstone sequences in the Barberton Greenstone Belt of South Africa and Swaziland, previously considered to be derived from melting of mafic precursors, are shown to be the result of melting of significantly older felsic crust. This is documented by a combination of SHRIMP zircon dating with Hf-in-zircon and whole-rock Lu–Hf and Sm–Nd isotopic data. Zircons from felsic rocks of the oldest Barberton unit, the 3.53 Ga Theespruit Formation, yielded predominantly negative e Hf ( t ) -values, whereas whole-rock e Hf ( t ) - and e Nd ( t ) -data are slightly negative to slightly positive. Simi…

The complexities of zircon crystllazition and overprinting during metamorphism and anatexis: An example from the late Archean TTG terrane of western Shandong Province, China

Abstract There are different viewpoints on metamorphic and anatectic zircons recording ages of 2.45–2.48 Ga or even younger in some areas of the North China Craton where both late Neoarchean and late Paleoproterozoic tectono-thermal events are well developed. These are: 1) partial resetting of the U-Pb isotopic system in the late Neoarchean zircons, 2) metamorphism lasting from the late Neoarchean to the earliest Paleoproterozoic, and 3) earliest Paleoproterozoic metamorphism as separate different event. Western Shandong Province is an area where the late Neoarchean tectono-thermal event is widely developed but the late Paleoproterozoic event has not been identified. This provides an opport…

Zircon geochronology and metamorphic evolution of mafic dykes in the Hengshan Complex of northern China: Evidence for late Palaeoproterozoic extension and subsequent high-pressure metamorphism in the North China Craton

Abstract Magmatic and metamorphic zircons have been dated from ductilely deformed gabbroic dykes defining a dyke swarm and signifying crustal extension in the northern part of the Hengshan Complex of the North China Craton. These dykes now occur as boudins and deformed sheets within migmatitic tonalitic, trondhjemitic, granodioritic and granitic gneisses and are conspicuous due to relics of high-pressure granulite or even former eclogite facies garnet + pyroxene-bearing assemblages. SHRIMP ages for magmatic zircons from two dykes reflect the time of dyke emplacement at ∼1915 Ma, whereas metamorphic zircons dated by both SHRIMP and evaporation techniques are consistently in the range 1848–18…

Late Palaeoproterozoic depositional age for khondalite protoliths in southern India and tectonic implications

Abstract SHRIMP dating of detrital zircons from garnet–sillimanite–cordierite paragneisses (khondalites) of the Trivandrum Block, southern India, revealed nanometer-scale Pb isotopic inhomogeneity in most grains that we ascribe to annealing processes during ultra-high-temperature metamorphism at ca. 570 Ma. Our age data for zircons from six representative khondalite samples do not document any Neo- or Mesoproterozoic detrital grains, and we conclude from the concordant ages and discordant minimum 207Pb/206Pb ages that the khondalite precursor sediments were deposited more than 2.1 Ga ago and were subsequently intruded by granitoid rocks at ca. 1765–2100 Ma. Some detrital zircons in the khon…

Late Neoarchean synchronous TTG gneisses and potassic granitoids in southwestern Liaoning Province, North China Craton: Zircon U-Pb-Hf isotopes, geochemistry and tectonic implications

Abstract Abundant late Neoarchean granitoids occur in southwestern Liaoning Province, part of the Eastern Ancient Terrane of the North China Craton. These rocks include intermediate gneiss, TTG gneisses and potassic granitoids, and we report on the geochemistry and zircon SHRIMP ages as well as Hf-in-zircon isotopes of these granitoids in order to determine their petrogenesis. Field relationships suggest that most of these granitoids experienced widespread metamorphism and deformation, associated with anatexis at some localities. The intermediate gneisses, TTG gneisses and potassic granitoids were all emplaced at the end of the Neoarchean (2.50–2.53 Ga), and CL images document widespread re…

Two orogenic events separated by 2.6Ga mafic dykes in the Central Zone, Limpopo Belt, southern Africa

Abstract The Limpopo Belt of southern Africa is a typical early Precambrian orogen that experienced two high-grade metamorphic events which are a key for understanding its tectonic evolution. There has been a long-standing debate on whether the Neoarchean (c. 2.65 Ga) or the Palaeoproterozoic (c. 2.0 Ga) tectono-thermal event records continental collision. The clear field relationship between deformed mafic dykes and the surrounding rocks is a powerful tool to help reconstructing the deformation history. Mafic dykes intruded the 3.3–3.1 Ga Sand River Gneiss Suite in the Central Zone of the Limpopo Belt near Musina, South Africa, and were classified in the past into older Causeway dykes and …