Zircon M257 - a homogeneous natural reference material for the ion microprobe U-Pb analysis of zircon
We introduce and propose zircon M257 as a future reference material for the determination of zircon U-Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS-determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U-Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ∼ 840 μg g−1 U (Th/U ∼ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of…
Mineral chemical and geochronological constraints on the age and provenance of the eastern Circum-Rhodope Belt low-grade metasedimentary rocks, NE Greece
Abstract In north-eastern Greece the mid-greenschist facies Makri Unit and the anchizonal Melia Formation belong to the eastern Circum-Rhodope Belt that forms the uppermost tectonostratigraphic unit of the Rhodope metamorphic nappe pile. The two metasedimentary successions had different source areas, although they now lie in close proximity in the Rhodope Massif. The U–Pb isotopic ages of detrital zircons from a metasandstone of the Makri Unit analysed using LA–SF–ICP–MS and SHRIMP-II gave age clusters at ca. 310–290 Ma and at ca. 240 Ma for magmatic zircons, which may have been derived from Carboniferous–Permian basement rocks of the Thracia Terrane (Lower Tectonic Unit of the Rhodope Mass…
Geochemistry, provenance and stratigraphic age of metasedimentary rocks from the eastern Vardar suture zone, northern Greece
Abstract Uppermost Palaeozoic and Mesozoic sediments from the Vardar suture zone in northern Greece record a cycle of Neotethyan oceanic basin opening and closure and their analysis places tight constraints on the geotectonic evolution of the area. The oldest post-Carboniferous sedimentary unit in the study area is the Examili Formation, which comprises mainly metaarkoses and metaquartzites, and was deposited in an intracontinental rift-related sedimentary basin in proximity to the Vertiskos Terrane during the Permian–Triassic. The Melissochori Formation (former Svoula flysch) comprises predominantly metasandstones with significant carbonate content and was deposited in front of a Carbonife…