0000000000166796

AUTHOR

Chiara Di Garbo

Photoelectric valuation of highly efficient Dye-Sensitized Solar Cells

Nowadays, a growing demand for free and clean energy requires the study and the development of new low-cost solar photovoltaic (PV) cells. Among them, Dye Sensitized Solar Cells (DSSCs) based on ruthenium complexes as sensitizers are assuming a great importance. The DSSCs under study are composed placing in succession a transparent conductive glass on which is screen-printed a mesoporous TiO2 thin film sensitized by a ruthenium based dye (N719) , an electrolytic solution containing a redox couple (I-/I3-) and another conductive glass covered by a thin transparent catalyst platinum film. In this work, we have measured the main photoelectrochemical parameters of the above mentioned DSSCs at d…

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Fabrication and Characterization of Dye-Sensitized Solar Cells

Among the next-generation solar cells, a predominant role is played by Dye sensitized solar cells (DSSC) based on ruthenium complexes as sensitizers. They take advantage of a photoelectrochemical system to transform solar radiation into electric energy. In fact, DSSCs represent a cost-effective alternative to traditional silicon-based photovoltaic devices and they do not require expensive and sophisticated apparatus for their fabrication. In this work, we have produced and tested ruthenium DSSCs. In particular, we have measured the main parameters of these cells, such as the electrical and power performances and the efficiency levels, at different irradiance levels and at different incident…

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Fabrication and electro-optical characterization of Ruthenium-based Dye-Sensitized Solar Cells

In this paper, we measure the main photoelectrical parameters of Dye Sensitized Solar Cells (DSSCs) based on ruthenium complexes at different irradiance levels, incident wavelengths, temperatures and hours of light soaking

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Characterization of Ruthenium-based Dye-Sensitized solar cells

In this paper, we measure the main photoelectrical parameters of Dye Sensitized Solar Cells (DSSCs) based on ruthenium complexes at different irradiance levels, incident wavelengths, temperatures and hours of light soaking.

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Electrochemical and chemical synthesis of CIS/Zn(S,O,OH) for thin film solar cells

In this work, we are reporting results on the electrodeposition of the CuInSe2 thin films on molybdenum thin foil substrates. We have used an aqueous non-buffered electrolyte and a careful choice of deposition parameters to ensure a good quality and composition of the deposited films. In addition, CdS was replaced in the buffer layer with a wider bandgap Zn(S,O,OH) film obtained by chemical bath deposition. The deposited films were annealed in inert atmosphere at different temperatures. The influence of annealing temperature on the properties of the films is briefly discussed. Films were also characterized by photoelectrochemical and I-V measurements. Structural characterization was carried…

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Optical Nanoantennas for Energy Harvesting

In the last decade, the increasing demand for renewable energy has been leading to the development of new devices, which overcome the disadvantages of the traditional photovoltaic conversion and exploit the thermal radiation created by the Sun, that is transferred in the form of electromagnetic waves into free space and finally absorbed by the surface of the Earth [1-2]. These new devices, called nanoantennas, have only recently been considered thanks to the development of electron beam lithography and similar techniques. Nanoantennas operate at nanometers wavelengths and their dimensions range from a few hundred nanometres to a few microns. They exhibit potential advantages in terms of pol…

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Review of Infrared Nanoantennas for Energy Harvesting

The Sun is the greatest source of energy providing a continuous stream of power; its exploitation has stimulated several approaches and technologies to directly or indirectly achieve renewable energy. New devices, which exploit the thermal radiation created by the Sun, that is transferred in the form of electromagnetic waves into free space, and finally absorbed by the surface of the Earth, are under study. The aim of this contribution is to critically compare advantages and disadvantages of new types of suitable antennas operating at nanometers wavelengths, called nanoantennas, for infrared energy harvesting, focusing on the state of the art and its perspectives.

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Electro-optical characterization of highly efficient Dye-Sensitized solar cells

Nowadays, a growing demand for free and clean energy requires the study and the development of new low-cost solar photovoltaic (PV) cells. Among them, Dye Sensitized Solar Cells (DSSCs) based on ruthenium complexes as sensitizers are assuming a great importance. The DSSCs under study are composed placing in succession a transparent conductive glass on which is screen-printed a mesoporous TiO2 thin film sensitized by a ruthenium based dye (N719), an electrolytic solution containing a redox couple (I-/I3-) and another conductive glass covered by a thin transparent catalyst platinum film. In this work, we have measured the main photoelectrochemical parameters of the above mentioned DSSCs at di…

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Solar Nanoantennas energy based characterization

Solar nanoantennas appear a very interesting solution to exploit solar radiation, as a matter of fact, their operating principle allows heat losses to be lessened compared to traditional photovoltaic cells and efficiency to be increased. Anyway, some technological issues are to be overcome. Literature often proposes a characterization by radiation efficiency typical of traditional antennas. Since the aim of solar nanoantennas is to harvest energy, in this paper the most promising devices are characterized by the upper bound of deliverable power density calculated in the whole operating wavelengths range.

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