0000000000170456
AUTHOR
R. Denig
Trennung von Spaltprodukten durch Extraktionschromatographie
The possibilities for the separation of a complex fission product mixture by extraction chromatography have been investigated. Here the partition coefficients between three solvents and hydrochloric acid are reported for the following elements: Zn(II), Ge(IV), As(III), As(V), Se(IV), Zr(IV), Nb(V), Mo(VI), Tc(IV) Ru(III), Ru(IV), Rh(III), Ag(I), Cd(II), In(III), Sn(IV), Sb(III), Sb(V), Te(IV), I(oxidized), Cs(I), Ce(III), Tb(III), Tm(III), Ac(III), Th(IV), Pa(V), U(VI), Np(IV), Np(VI). As solvents tri-n-butylphosphate (TBP), tri-n-octylamine (TOA) and di-(2-ethylhexyl)-orthophosphoric acid (HDEHP) have been used. The partition coefficients have been measured by batch-experiments in which th…
The decay of 8.7 min237Pa
The beta and gamma radiations of237Pa have been investigated employing semiconductor and scintillation spectrometers and coincidence techniques. Sources of237Pa were obtained after bombardments of238U with bremsstrahlung and 14-MeV neutrons and subsequent chemical separation. From the total of 18γ-rays following the decay of 8.7±0.2 min237Pa 17 transitions, representing 99.9% of theγ-ray intensity, could be placed in a level scheme of237U. AQ β- value of 2.25±0.1 MeV has been determined.
Trennung von spaltprodukten durch Extraktionschromatographie
The separation of fission products which form anionic species in mineral acids and of uranium and neptunium from samples of neutron-irradiated uranium is described. The method used is extraction chromatography with tri-n-butylphosphate (TBP) and di-(2-ethylhexyl)-orthophosphoric acid (HDEHP) as extractants and polytrifluoromonochloroethylene powder as the solid support. In the first column Zr, U and Np are extracted with TBP from 8N HNO3/NaClO3. In the second column, HDEHP is applied as extractant and 9N HCl/NaClO3 as the mobile phase for the isolation of Nb, Sb, and I, and in the third column (HDEHP), the rare earths and Mo are extracted from 0.1N HCl. Finally with the fourth column (TBP),…
The decay of 31 sec98Zr, 2.9 sec98Nb and 51 min98Nb
TheΒ- andγ-radiations of98Zr and98m, g Nb have been investigated employing scintillation and semiconductor spectrometers and coincidence techniques. Sources of98Nb were produced by the98Mo(n, p)98Nb reaction, sources of98Zr by fission of235U with thermal neutrons applying chemical separations. For98Zr, a half-life of 30.7±0.4 sec and aQ β-value of 2.3±0.2 MeV were obtained, for the98Nb isomers, half-lives of 2.86±0.06 sec and 51.3±0.4 min, andQ β-values of 4.8±0.2 MeV and 4.5±0.2 MeV, respectively. Noγ-rays were observed in the decay of98Zr. The decay of 2.9 sec98Nb was found to involve 11γ-ray transitions. In the decay of 51 min98Nb, 54γ-transitions were detected. Spin and parity of 1+ and…