0000000000171940
AUTHOR
Fabian Klautzsch
showing 4 related works from this author
Ein Selbstordnungsschema für Tetraharnstoffcalix[4]arene
2009
Grose und Form sind wichtig: Eine aquimolare Mischung aus elf unterschiedlich substituierten Tetraharnstoff-Calix[4]arenen bildet in unpolaren Losungsmitteln nur 6 von 35 moglichen Homo- und Heterodimeren. Da das Calixarengerust und die vier Harnstoffreste in allen Fallen gleich sind, wird dieser Prozess der Selbstorganisation allein durch das Zusammenwirken von sterischen und stochiometrischen Randbedingungen bestimmt.
A Self-Sorting Scheme Based on Tetra-Urea Calix[4]arenes
2009
Size and shape do matter: When dimerized in nonpolar solvents, an equimolar mixture of eleven tetra-urea calix[4]arenes with different wide-rim substituents self-sorts into only six out of 35 different homo- and heterodimers (see picture). Since the calixarene scaffold and the four urea units are the same in all cases, the self-sorting process is driven only by the cooperative action of steric requirements and stoichiometry.
Chelate Cooperativity and Spacer Length Effects on the Assembly Thermodynamics and Kinetics of Divalent Pseudorotaxanes
2011
Homo- and heterodivalent crown-ammonium pseudorotaxanes with different spacers connecting the two axle ammonium binding sites have been synthesized and characterized by NMR spectroscopy and ESI mass spectrometry. The homodivalent pseudorotaxanes are investigated with respect to the thermodynamics of divalent binding and to chelate cooperativity. The shortest spacer exhibits a chelate cooperativity much stronger than that of the longer spacers. On the basis of crystal structure, this can be explained by a noninnocent spacer, which contributes to the binding strength in addition to the two binding sites. Already very subtle changes in the spacer length, i.e., the introduction of an additional…
Thermodynamic and electrochemical study of tailor-made crown ethers for redox-switchable (pseudo)rotaxanes
2020
Crown ethers are common building blocks in supramolecular chemistry and are frequently applied as cation sensors or as subunits in synthetic molecular machines. Developing switchable and specifically designed crown ethers enables the implementation of function into molecular assemblies. Seven tailor-made redox-active crown ethers incorporating tetrathiafulvalene (TTF) or naphthalene diimide (NDI) as redox-switchable building blocks are described with regard to their potential to form redox-switchable rotaxanes. A combination of isothermal titration calorimetry and voltammetric techniques reveals correlations between the binding energies and redox-switching properties of the corresponding ps…