0000000000172266

AUTHOR

Stéphane Golhen

showing 3 related works from this author

Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4…

2002

A new polynuclear copper(II) complex [Cu7(OH)6Cl2- (pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation. Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es ; Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es ; Coronado Miralles, Eugenio, Eugenio.Coronado@uv.es

Polynuclear copperUNESCO::QUÍMICAchemistry.chemical_element13-Diaminopropane010402 general chemistry01 natural sciences:QUÍMICA [UNESCO]Catalysischemistry.chemical_compoundMaterials ChemistryCluster (physics)CuDiaminopropaneMagnetic characterisation010405 organic chemistryMetallurgyMetals and AlloysGeneral ChemistryUNESCO::QUÍMICA::Química macromolecularCopperStructural characterization3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsPolynuclear copper ; Structural characterization ; Magnetic characterisation ; Cu ; DiaminopropaneCrystallographychemistryCubaneCeramics and Composites:QUÍMICA::Química macromolecular [UNESCO]
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[Cu(tn)]3[Cr(CN)6]2·3H2O: A unique two-dimensional Cu-Cr cyano-bridged ferromagnet (tn = 1,3-diaminopropane)

2002

Reaction of the two-coordinate ‘assembling complex-ligand’ [Cu(tn)]2+ with the building block [Cr(CN)6]32 leads to a unique two-dimensional Cu–Cr cyano-bridged ferromagnet with unusual m3- and m4-bridging [Cu(tn)]2+ units. Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es

Materials scienceReactionUNESCO::QUÍMICAAssembling complex-ligand13-Diaminopropane010402 general chemistry:QUÍMICA [UNESCO]01 natural sciencesCatalysisReaction ; Cu ; Cr ; H2O ; Assembling complex-ligand ; Cyano-bridged ferromagnetchemistry.chemical_compoundBlock (telecommunications)[CHIM] Chemical SciencesMaterials ChemistryH2O[CHIM]Chemical SciencesCrCuCondensed matter physics010405 organic chemistryMetals and AlloysGeneral ChemistryUNESCO::QUÍMICA::Química macromolecular0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryFerromagnetismCyano-bridged ferromagnetCeramics and Composites:QUÍMICA::Química macromolecular [UNESCO]
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Charge transfer salts containing a paramagnetic cyano-complex and iodine substituted organic donor involving –I(donor)···N(anion)-interactions

2005

Abstract The preparation, crystal structures, EHT band calculation and optical properties of two new charge transfer salts, namely (DIET)2[Fe(bpca)(CN)3] (1) and (DIEDO)2[Fe(bpca)(CN)3] (2), where bpca = bis(2-pyridylcarbonyl)amide anion, DIET = diiodoethylenedithotetrathiavalene and DIEDO = diiodoethylenedioxotetrathiavalene are reported. The magnetic properties of 2 and those of the low-spin iron(III) precursor of formula (PPh4)[Fe(bpca)(CN)3]·H2O (3) were also investigated in the temperature range 1.9–205 K. Crystal data; (1): monoclinic P21, a = 8.8238(2)A, b = 13.2891(3) A, c = 18.5042(5) A, β = 91.115(1)°, Z = 2, R = 0.0710 for 7021 independent reflections with I > 2 σ(I) and (2): Mon…

StereochemistryGeneral Chemical EngineeringInfrared spectroscopyGeneral ChemistryCrystal structureAtmospheric temperature rangeParamagnetismchemistry.chemical_compoundCrystallographychemistryAmideMoleculeAntiferromagnetismMonoclinic crystal systemComptes Rendus Chimie
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