Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

6533b7d2fe1ef96bd125e089

RESEARCH PRODUCT

Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4Cl2 (pn = 1,3-diaminopropane)

Jean Sala Pala Smail Triki Juan M. Clemente-juan Eugenio Coronado Stéphane Golhen Carlos J. Gómez-garcía Franck Thétiot

subject

Polynuclear copper UNESCO::QUÍMICA chemistry.chemical_element 1 3-Diaminopropane 010402 general chemistry 01 natural sciences :QUÍMICA [UNESCO]Catalysis chemistry.chemical_compound Materials Chemistry Cluster (physics)Cu Diaminopropane Magnetic characterisation 010405 organic chemistry Metallurgy Metals and Alloys General Chemistry UNESCO::QUÍMICA::Química macromolecular Copper Structural characterization 3. Good health 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Polynuclear copper ; Structural characterization ; Magnetic characterisation ; Cu ; Diaminopropane Crystallography chemistry Cubane Ceramics and Composites :QUÍMICA::Química macromolecular [UNESCO]

description

A new polynuclear copper(II) complex [Cu7(OH)6Cl2- (pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation. Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es ; Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es ; Coronado Miralles, Eugenio, Eugenio.Coronado@uv.es

year	journal	country	edition	language
2002-09-21

10.1039/b105231b http://dx.doi.org/10.1039/b105231b

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