Search results for "3-Diaminopropane"

showing 10 items of 16 documents

New, Multi‐Dimensional Cu(tn)‐[M(CN) 6 ] n – Cyano‐Bridged, Bimetallic Coordination Materials (M = Fe II , Co III , Cr III and tn = 1,3‐Diaminopropan…

2005

Reaction of the [Fe I I I (CN) 6 ] 3 - anion with [Cu I I (tn)(H 2 O) n ] 2 + (tn = 1,3-diaminopropane) affords the compounds [{Cu I I (tn)} 2 -{Fe I I (CN) 6 }].KCl.5H 2 O (1), [(Cu"(tn))2(Fe"(CN) 6 )].4H 2 O (2), and [{Cu I I (tnH) 2 (H 2 O) 2 }{Fe I I (CN) 6 }].2H 2 O (3). Each iron center in 1 and 2 is linked to six copper(II) ions by six cyanide bridges, while each copper ion is linked to three equivalent iron(II) ions. Despite these resemblances, the two compounds present large structural differences caused by two different orientations of the Cu-NC-Fe bridges: compound 1 has a 2D structure which can be described as successions of "Cu 4 Fe 3 " defective cubane units, while compound 2 …

010405 organic chemistrychemistry.chemical_element13-DiaminopropaneBridging ligandProtonation010402 general chemistry01 natural sciencesCopper0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundParamagnetismCrystallographychemistryCubaneAntiferromagnetismBimetallic stripEuropean Journal of Inorganic Chemistry
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[Cu(tn)]3[Cr(CN)6]2·3H2O: A unique two-dimensional Cu-Cr cyano-bridged ferromagnet (tn = 1,3-diaminopropane)

2002

Reaction of the two-coordinate ‘assembling complex-ligand’ [Cu(tn)]2+ with the building block [Cr(CN)6]32 leads to a unique two-dimensional Cu–Cr cyano-bridged ferromagnet with unusual m3- and m4-bridging [Cu(tn)]2+ units. Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es

Materials scienceReactionUNESCO::QUÍMICAAssembling complex-ligand13-Diaminopropane010402 general chemistry:QUÍMICA [UNESCO]01 natural sciencesCatalysisReaction ; Cu ; Cr ; H2O ; Assembling complex-ligand ; Cyano-bridged ferromagnetchemistry.chemical_compoundBlock (telecommunications)[CHIM] Chemical SciencesMaterials ChemistryH2O[CHIM]Chemical SciencesCrCuCondensed matter physics010405 organic chemistryMetals and AlloysGeneral ChemistryUNESCO::QUÍMICA::Química macromolecular0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryFerromagnetismCyano-bridged ferromagnetCeramics and Composites:QUÍMICA::Química macromolecular [UNESCO]
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Heptanuclear hydroxo-bridged copper cluster of the dicubane-like type: structural and magnetic characterisations of [Cu7(OH)6Cl2(pn)6(H2O)2](C(CN)3)4…

2002

A new polynuclear copper(II) complex [Cu7(OH)6Cl2- (pn)6(H2O)2](C(CN)3)4Cl2 with hydroxo-bridging ligands has been prepared; the centrosymmetric cluster cation can be described as two Cu4O3Cl distorted cubane units sharing one copper cation. Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es ; Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es ; Coronado Miralles, Eugenio, Eugenio.Coronado@uv.es

Polynuclear copperUNESCO::QUÍMICAchemistry.chemical_element13-Diaminopropane010402 general chemistry01 natural sciences:QUÍMICA [UNESCO]Catalysischemistry.chemical_compoundMaterials ChemistryCluster (physics)CuDiaminopropaneMagnetic characterisation010405 organic chemistryMetallurgyMetals and AlloysGeneral ChemistryUNESCO::QUÍMICA::Química macromolecularCopperStructural characterization3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsPolynuclear copper ; Structural characterization ; Magnetic characterisation ; Cu ; DiaminopropaneCrystallographychemistryCubaneCeramics and Composites:QUÍMICA::Química macromolecular [UNESCO]
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CCDC 739723: Experimental Crystal Structure Determination

2010

Related Article: S.Thakurta, C.Rizzoli, R.J.Butcher, C.J.Gomez-Garcia, E.Garribba, S.Mitra|2010|Inorg.Chim.Acta|363|1395|doi:10.1016/j.ica.2009.12.053

Space GroupCrystallographyCrystal SystemCrystal Structure(NN'-bis(3-Ethoxysalicylideneimino)-13-diaminopropane)-copper(ii) monohydrateCell ParametersExperimental 3D Coordinates
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CCDC 699605: Experimental Crystal Structure Determination

2010

Related Article: M.Jung, A.Sharma, D.Hinderberger, S.Braun, U.Schatzschneider, E.Rentschler|2009|Inorg.Chem.|48|7244|doi:10.1021/ic9006857

Space GroupCrystallographyCrystal SystemCrystal Structure(mu2-4-(4455-Tetramethylimidazolidinyl-1-oxyl-3-oxide radical)benzoato-OO')-(mu2-NNN'N'-tetrakis(1-n-propyl-2-benzimidazolylmethyl)-2-oxy-13-diaminopropane)-di-copper(ii) diperchlorate acetonitrile solvateCell ParametersExperimental 3D Coordinates
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CCDC 699685: Experimental Crystal Structure Determination

2010

Related Article: M.Jung, A.Sharma, D.Hinderberger, S.Braun, U.Schatzschneider, E.Rentschler|2009|Inorg.Chem.|48|7244|doi:10.1021/ic9006857

Space GroupCrystallographyCrystal SystemCrystal Structure(mu~2~-4-(t-Butylaminoxyl)benzoato-OO')-(mu~2~-NNN'N'-tetrakis(1-n-propyl-2-benzimidazolylmethyl)-2-oxy-13-diaminopropane)-di-copper(ii) bis(hexafluorophosphate) methanol solvate dihydrateCell ParametersExperimental 3D Coordinates
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CCDC 699686: Experimental Crystal Structure Determination

2010

Related Article: M.Jung, A.Sharma, D.Hinderberger, S.Braun, U.Schatzschneider, E.Rentschler|2009|Inorg.Chem.|48|7244|doi:10.1021/ic9006857

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(mu~2~-4-Nitrobenzoato-OO')-(mu~2~-NNN'N'-tetrakis(1-n-propyl-2-benzimidazolylmethyl)-2-oxy-13-diaminopropane)-di-copper(ii) bis(tetrafluoroborate) acetonitrile solvate hemihydrate
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CCDC 175834: Experimental Crystal Structure Determination

2002

Related Article: F.Thetiot, S.Triki, J.-S.Pala|2002|New J.Chem.|26|196|doi:10.1039/b108521m

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(Potassium hexakis(mu~2~-cyano)-iron(ii)-bis((13-diaminopropane-NN')-copper(ii)) chloride pentahydrate)
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CCDC 175842: Experimental Crystal Structure Determination

2002

Related Article: S.Triki, J.Sala-Pala, F.Thetiot, C.J.Gomez-Garcia, J.-C.Daran|2006|Eur.J.Inorg.Chem.||185|doi:10.1002/ejic.200500626

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(decakis(mu~2~-Cyano)-tris(13-diaminopropane-NN')-dicyano-di-chromium(iii)-tri-copper(ii) trihydrate)
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CCDC 739722: Experimental Crystal Structure Determination

2010

Related Article: S.Thakurta, C.Rizzoli, R.J.Butcher, C.J.Gomez-Garcia, E.Garribba, S.Mitra|2010|Inorg.Chim.Acta|363|1395|doi:10.1016/j.ica.2009.12.053

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu~2~-NN'-bis(3-Methoxysalicylideneimino)-13-diaminopropane)-diaqua-tri-copper(ii) diperchlorateExperimental 3D Coordinates
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