0000000000186498

AUTHOR

Andrey Shkabko

showing 4 related works from this author

Anomalous transport properties of the half-metallic ferromagnets Co 2 TiSi, Co 2 TiGe and Co 2 TiSn

2011

In this work the theoretical and experimental investigations of Co2TiZ (Z = Si, Ge, or Sn) compounds are reported. Half-metallic ferromagnetism is predicted for all three compounds with only two bands crossing the Fermi energy in the majority channel. The magnetic moments fulfill the Slater-Pauling rule and the Curie temperatures are well above room temperature. All compounds show a metallic like resistivity for low temperatures up to their Curie temperature, above the resistivity changes to semiconducting like behavior. A large negative magnetoresistance of 55% is observed for Co2TiSn at room temperature in an applied magnetic field of 4T which is comparable to the large negative magnetore…

Condensed Matter - Materials ScienceMaterials scienceCondensed matter physicsMagnetoresistanceGeneral MathematicsGeneral EngineeringMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesGeneral Physics and AstronomyAtmospheric temperature rangeFerromagnetismElectrical resistivity and conductivitySeebeck coefficientThermoelectric effectCurieCurie temperaturePhilosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
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Itinerant half-metallic ferromagnetsCo2TiZ(Z=Si, Ge, Sn):Ab initiocalculations and measurement of the electronic structure and transport properties

2010

This work reports on ab initio calculations and experiments on the half-metallic ferromagnetic Heusler compounds ${\text{Co}}_{2}\text{Ti}Z$ $(Z=\text{Si},\text{ }\text{Ge},\text{ }\text{Sn})$. Aim is a comprehensive study of the electronic-structure and thermoelectric properties. The impact of the variation in the main group element $Z$ on those properties is discussed. X-ray diffraction was performed on the compounds and the lattice parameters are compared to other ${\text{Co}}_{2}$-based compounds. Hard x-ray photoemission measurements were carried out and the results are compared to the calculated electronic structure. The experimentally determined electronic structure, magnetic propert…

PhysicsCondensed matter physicsFerromagnetismAb initio quantum chemistry methodsElectrical resistivity and conductivitySeebeck coefficientLattice (order)X-ray crystallographyCurie temperatureElectronic structureCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsPhysical Review B
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Seebeck coefficients of half-metallic ferromagnets

2009

In this report the Co2 based Heusler compounds are discussed as potential materials for spin voltage generation. The compounds were synthesized by arcmelting and consequent annealing. Band structure calculations were performed and revealed the compounds to be half-metallic ferromagnets. Magnetometry was performed on the samples and the Curie temperatures and the magnetic moments were determined. The Seebeck coefficients were measured from low to ambient temperatures for all compounds. For selected compounds high temperature measurements up to 900 K were performed.

Condensed Matter - Materials ScienceMaterials scienceMagnetic momentCondensed matter physicsAnnealing (metallurgy)Materials Science (cond-mat.mtrl-sci)FOS: Physical sciencesGeneral ChemistryCondensed Matter PhysicsSemimetalCondensed Matter::Materials ScienceMagnetizationFerromagnetismThermoelectric effectMaterials ChemistryCurie temperatureCondensed Matter::Strongly Correlated ElectronsElectronic band structureSolid State Communications
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Investigation of the Thermoelectric Properties of the Series TiCo1-xNixSnxSb1-x

2010

The effect of the simultaneous substitution of cobalt by nickel and antimony by tin in the solid solution TiCo1–xNixSnxSb1–x was systematically investigated. The number of valence electrons does not change by this substitution and therefore the resistivity stays semimetallic or semiconducting. The series were synthesized by arcmelting and the thermoelectric properties were determined. It was found out that the substitution of cobalt and antimony by nickel and tin reduces the thermal conductivity to 2 W·m–1·K–1 at 400 K. The reduction is caused by titanium rich prolate micro structures that were found by energy dispersive X-ray spectroscopy investigations. The Seebeck coefficient and the res…

Inorganic ChemistryNickelchemistryAntimonyElectrical resistivity and conductivitySeebeck coefficientThermoelectric effectMetallurgyAnalytical chemistrychemistry.chemical_elementTinCobaltSolid solutionZeitschrift für anorganische und allgemeine Chemie
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