0000000000187968
AUTHOR
Mouhamadou Birame Diop
Propane-1,3-diammonium molybdate
The reaction between equimolar amounts of propane-1,3-diamine and molybdenum trioxide in water led to the formation of single crystals of the title salt, (C3H12N2)[MoO4]. The asymmetric unit is comprised of one propane-1,3-diammonium cation and one molybdate anion. The latter is isolated in the structure and has a slightly distorted tetrahedral configuration. An extensive network of N—H...O hydrogen bonds connects anions and cations, giving rise to a compact three-dimensional packing.
Crystal structure of 2-methyl-1H-imidazol-3-ium hydrogen oxalate dihydrate
In the title molecular salt 2-methyl-1H-imidazol-3-ium hydrogen oxalate dihydrate, N—H⋯(O,O) and O—H⋯O hydrogen bonds link the components into a bilayer-like assembly.
Crystal structure of bis(2-methyl-1H-imidazol-3-ium) dihydroxidobis(oxalato-κ2 O 1,O 2)stannate(IV) monohydrate
The SnIV atom in the anion of the title compound is six-coordinated by two OH groups and four O atoms from two chelating oxalate ligands. Several N—H⋯O and O—H⋯O hydrogen bonds involving the stannate dianions, the cations and the water molecules result into a three-dimensional network structure.
Bromide hydrogen oxalate salts with the diprotonated 1,4-diazabicyclo[2.2.2]octane counterion
Abstract Two new salts composed of the diprotonated 1,4-diazabicyclo[2.2.2]octane (DABCO) molecule as the cations and bromide and hydrogen oxalate as the anions have been isolated and structurally characterized by X-ray diffraction analysis. The salt [DABCOH2]{[HC2O4][Br]} (1) crystallizes in the orthorhombic system, space group P212121 with a = 9.0809(7), b = 9.5156(7), c = 12.3558(9) Å, V = 1067.67(14) Å3 and Z = 4. The salt [DABCOH2]2{[HC2O4][Br]3}·H2O (2) crystallizes in the orthorhombic system, space group Pnma with a = 26.6554(17), b = 7.3711(4), c = 10.7421(7) Å, V = 2110.6(2) Å3 and Z = 4. The compounds were prepared from ethanolic solutions of [DABCOH2][HC2O4]2 (L 1 ) and ZnBr2 in …
Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-κ2O,O′)stannate(IV)
N—H⋯O, N—H⋯Cl and O—H⋯O hydrogen bonds between cations and anions in the complex salt (C4H7N2)+[Sn(H2O)Cl3(C2O4)]− are responsible for the formation of a three-dimensional network structure.
CCDC 1835271: Experimental Crystal Structure Determination
Related Article: Mamadou Ndiaye, Mouhamadou Birame Diop, Abdoulaye Samb, Libasse Diop, Allen G. Oliver, Laurent Plasseraud|2020|Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie, Organische Chemie|75|815 |doi:10.1515/znb-2020-0097
CCDC 1835272: Experimental Crystal Structure Determination
Related Article: Mamadou Ndiaye, Mouhamadou Birame Diop, Abdoulaye Samb, Libasse Diop, Allen G. Oliver, Laurent Plasseraud|2020|Zeitschrift fuer Naturforschung, Teil B. Anorganische Chemie, Organische Chemie|75|815 |doi:10.1515/znb-2020-0097