6533b7d2fe1ef96bd125f5b6

RESEARCH PRODUCT

Propane-1,3-diammonium molybdate

Alioune WaneMouhamadou Birame DiopHélène CatteyAntoine Blaise KamaLaurent PlasseraudLibasse Diop

subject

chemistry.chemical_classificationcrystal structure010405 organic chemistryHydrogen bondSalt (chemistry)General MedicineCrystal structureMolybdate010402 general chemistry01 natural sciences0104 chemical sciencesIonMolybdenum trioxidechemistry.chemical_compoundCrystallographychemistryPropanemolybdate saltpropane-13-diammoniumhydrogen bondslcsh:QD901-999[CHIM.CRIS]Chemical Sciences/Cristallography[CHIM]Chemical Scienceslcsh:CrystallographyComputingMilieux_MISCELLANEOUS

description

The reaction between equimolar amounts of propane-1,3-diamine and molybdenum trioxide in water led to the formation of single crystals of the title salt, (C3H12N2)[MoO4]. The asymmetric unit is comprised of one propane-1,3-diammonium cation and one molybdate anion. The latter is isolated in the structure and has a slightly distorted tetrahedral configuration. An extensive network of N—H...O hydrogen bonds connects anions and cations, giving rise to a compact three-dimensional packing.

10.1107/s2414314619005005https://hal.archives-ouvertes.fr/hal-02122722