Anomalous Muon Knight Shift Behavior in a Cd Single Crystal

For the positive muon implanted in a metal the precession frequency shift due to hyperfine fields can be measured with high precision. This provides means to obtain information about the local electronic structure of a hydrogen like impurity in any metal in the indefinitely dilute impurity concentration. Ref. 1 gives a summary of the muon Knight shift (KS) investigations in 18 nontransition (simple) metals and some transition metals and discusses the results in the context of the electronic structure of hydrogen in metals.

Muon Knight shift studies of the valence transition in Ce0�74Th0�26

Muon Knight shift at a structural defect in zinc crystals

The interaction of a light hydrogen isotope with a structural defect is traced for the first time by means of the temperature dependence of the muon Knight shiftKμ in the hcp metal Zn. A surprising result is the huge and negativeKμ (−520 ppm) at the defect site, probably a multivacancy cluster.

Muon Knight shift studies in single crystals of Zn and Cd

Recently f i r s t resul ts have been reported on the muon Knight s h i f t in high pu r i t y (6N) spherical s ingle crys ta ls of Cd and Zn [ l ] . These measurements, using a stroboscopic ~SR-technique [2 ] , are extensions of e a r l i e r ~+ Knight s h i f t measurements in nontrans i t ion metals [3 ,4] in which the pos i t i ve muon is used as a "hydrogen" subs t i tu te in the study of i t s local e lec t ron ic s t ructure in a metal environment. Since the s o l u b i l i t y of hydrogen in these metals is general ly very small , no proton-NMR measurements have ever been performed in th is class of metals. To the extent that the mass d i f ference between the proton and the muon is…

Muon spin rotation studies in single crystals of Zn and Cd

Anisotropic muon Knight shift in the HCP single crystals of Cd, Zn and Be

In single crystal samples of Zn, Cd and Be (hcp structure) stroboscopicμSR measurements successfully revealed anisotropies in the muon Knight shift (Kμ). An anisotropic Kμ can provide information on the amount of non s-electrons screening the charge of the muon implanted in these metals as a light hydrogen isotope. In Cd, the anisotropic part depends strongly on the temperature and shows a change in sign at roughly 110 K. In Zn, the anisotropic part below 10 K turns out to comprise 4th order contributions in the direction cosines of the external field. This can be understood on the basis of an anisotropicg-factor of the conduction electrons or spin-orbit coupling, respectively.