0000000000204927

AUTHOR

A. J. Van Der Wal

Anomalous Muon Knight Shift Behavior in a Cd Single Crystal

For the positive muon implanted in a metal the precession frequency shift due to hyperfine fields can be measured with high precision. This provides means to obtain information about the local electronic structure of a hydrogen like impurity in any metal in the indefinitely dilute impurity concentration. Ref. 1 gives a summary of the muon Knight shift (KS) investigations in 18 nontransition (simple) metals and some transition metals and discusses the results in the context of the electronic structure of hydrogen in metals.

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Muon Knight shift at a structural defect in zinc crystals

The interaction of a light hydrogen isotope with a structural defect is traced for the first time by means of the temperature dependence of the muon Knight shiftKμ in the hcp metal Zn. A surprising result is the huge and negativeKμ (−520 ppm) at the defect site, probably a multivacancy cluster.

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Anisotropic muon Knight shift in the HCP single crystals of Cd, Zn and Be

In single crystal samples of Zn, Cd and Be (hcp structure) stroboscopicμSR measurements successfully revealed anisotropies in the muon Knight shift (Kμ). An anisotropic Kμ can provide information on the amount of non s-electrons screening the charge of the muon implanted in these metals as a light hydrogen isotope. In Cd, the anisotropic part depends strongly on the temperature and shows a change in sign at roughly 110 K. In Zn, the anisotropic part below 10 K turns out to comprise 4th order contributions in the direction cosines of the external field. This can be understood on the basis of an anisotropicg-factor of the conduction electrons or spin-orbit coupling, respectively.

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