showing 9 related works from this author
Effect of Mn doping on the low-temperature synthesis of tricalcium phosphate (TCP) polymorphs
2019
Abstract Effect of Mn doping on the low-temperature synthesis of tricalcium phosphate (TCP) polymorphs was demonstrated in α- and β-TCP polymorphs prepared by wet precipitation method under identical conditions and annealed at 700 °C. Calcium phosphates with Mn doping level in the range from 1 to 5 mol% were studied and the formation of desired polymorph was controlled by varying Mn content in as-prepared precipitates. It was found that increasing Mn content resulted in the formation of β-TCP, while α-TCP was obtained with low Mn doping level, whereas a mixture of two polymorphs was obtained for intermediate Mn concentrations. Moreover, doping with Mn ions allowed the synthesis of β-TCP at …
Heterogeneous fenton oxidation using magnesium ferrite nanoparticles for ibuprofen removal from wastewater: optimization and kinetics studies
2020
In this study, the catalytic properties of Fenton-like catalyst based on magnesium ferrite nanoparticles for IBP degradation were examined. Structural and morphological studies showed the low crystallinity and mesoporous structure for the catalyst obtained via a glycine-nitrate method. The influences of catalyst dosage, oxidant concentration, and solution pH on the pollutant degradation were investigated. The pseudo-first-order model describes kinetic data, and under optimal condition (catalyst dose of 0.5 g L-1, H2O2 concentration of 20.0 mM, and pH of 8.0), apparent rate constant reached 0.091 min-1. It was shown that Fenton reaction was mainly induced by iron atoms on the catalyst surfac…
Impact of gadolinium on the structure and magnetic properties of nanocrystalline powders of iron oxides produced by the extraction-pyrolytic method
2020
The work has been done in frame of the TransFerr project. It has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 778070. This research was also supported by Latvian Research Council project lzp-2018/1-0214. A.I.P. appreciates support from the Estonian Research Council grant (PUT PRG619).
Morphological and optical property study of Li doped ZnO produced by microwave-assisted solvothermal synthesis
2021
Abstract ZnO materials have been at the centre of many studies for decades. Doping of ZnO by lithium atoms is a prospective approach for compensation of n-type conductivity in the unintentionally doped ZnO aimed at obtaining p-type semiconductor. In this study, we have synthesized ZnO rod-like powders doped with lithium ions (0–0.65 atom%) by the new microwave-assisted solvothermal method in order to obtain greater photoluminescence intensity of ZnO emissions in the UV region. The obtained powders contain nanoparticles from 20 nm up to 250 nm depending on Li content. X-ray diffractometry and Raman spectroscopy were employed to characterise the structure of ZnO powders, scanning electron mic…
Synthesis, structural and luminescent properties of Mn-doped calcium pyrophosphate (Ca2P2O7) polymorphs
2022
The study was partially funded by the Swedish Research Council FORMAS project “Utilization of solid inorganic waste from the aquaculture industry as wood reinforcement material for flame retardancy” (grant no. 2018-01198). Vilnius University is highly acknowledged for financial support from the Science Promotion Foundation (MSF-JM-5/2021). This project has also received funding from European Social Fund (project No 09.3.3-LMT-K-712-19-0069) under grant agreement with the Research Council of Lithuania (LMTLT). The authors acknowledge the Center of Spectroscopic Characterization of Materials and Electronic/Molecular Processes ("SPECTROVERSUM" www.spectroversum.ff.vu.lt ) at the Lithuanian Nat…
Investigation of lanthanum substitution effects in yttrium aluminium garnet: importance of solid state NMR and EPR methods
2020
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Synthesis and luminescent properties of Mn-doped alpha-tricalcium phosphate
2021
This project has received funding from European Social Fund (project No 09.3.3-LMT-K-712-19-0069) under grant agreement with the Research Council of Lithuania (LMTLT). Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART². The World Federation of Scientists is highly acknowledged for the National Scholarship to AZ. © 2021. This work is licensed under a CC BY-NC-ND 4.0 license.
Fe and Zn co-substituted beta-tricalcium phosphate (β-TCP): Synthesis, structural, magnetic, mechanical and biological properties
2020
This work was supported by the European Social Fund under the No. 09.3.3- LMT-K-712 “Development of Competences of Scientists, other Researchers and Students through Practical Research Activities” measure. AK would like to express sincere gratitude for Fellowship administrated by The Japan Society for the Promotion of Science (JSPS). Fellow’s ID No.: L12546. Authors are grateful to R. Vargalis (Vilnius University) for taking SEM images. © 2020. This work is licensed under a CC BY-NC-ND license.
The influence of Fe3+ doping on thermally induced crystallization and phase evolution of amorphous calcium phosphate
2021
The present study investigates thermally induced crystallization and phase evolution of amorphous calcium phosphate (ACP) partially substituted with Fe3+ ions (M/P = 1.5 : 1). It was demonstrated that the presence of Fe3+ ions radically changes the crystallization behavior of ACP and completely prevents the formation of α-tricalcium phosphate (α-TCP, Ca3(PO4)2), which is the first crystalline phase obtained from non-substituted ACP upon thermal treatment. Surprisingly, calcium deficient hydroxyapatite (CDHA) was obtained instead of α-TCP. Such unusual crystallization behavior was observed with a doping level as low as 0.1 mol% with respect to Ca ions. Moreover, it was shown that the presenc…