0000000000205244

AUTHOR

Jose M. Goicoechea

0000-0002-7311-1663

showing 51 related works from this author

Arene C−H Activation at Aluminium(I): meta Selectivity Driven by the Electronics of S N Ar Chemistry

2020

The reactivity of the electron-rich anionic Al(I) ('aluminyl') compound K 2 [(NON)Al] 2 (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di- tert -butyl-9,9-dimethylxanthene) towards mono- and disubstituted arenes is reported. C-H activation chemistry with n -butylbenzene gives exclusively the product of activation at the arene meta position. Mechanistically, this transformation proceeds in a single step via a concerted Meisenheimer-type transition state. Selectivity is therefore based on similar electronic factors to classical S N Ar chemistry, which implies the destabilization of transition states featuring electron-donating groups in either the ortho or the para positions. In the cases of tolu…

010405 organic chemistryChemistryXyleneSubstituentGeneral Chemistry010402 general chemistry01 natural sciencesMedicinal chemistryTolueneCatalysisTransition state0104 chemical sciences3. Good healthchemistry.chemical_compoundMeta-Nucleophilic aromatic substitutionReactivity (chemistry)SelectivityAngewandte Chemie International Edition
researchProduct

The Aluminyl Anion : A New Generation of Aluminium Nucleophile

2020

Trivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and laboratory-based reactions. Recently, a series of isolable aluminium(I) anions ('aluminyls') have been reported, which offer an alternative to this textbook description: these reagents behave as aluminium nucleophiles. This minireview covers the synthesis, structure and reactivity of aluminyl species reported to date, together with their associated metal complexes. The frontier orbitals of each of these species have been investigated using a common methodology to allow for a like-for-like comparison of their electronic structure a…

chemistry.chemical_elementElectronic structureorganometalliyhdisteet010402 general chemistryreaktiivisuus01 natural sciencesCatalysisMetalmain groupNucleophileAluminiumnucleophile organometallicReactivity (chemistry)Lewis acids and basesalumiini010405 organic chemistryaluminiumGeneral MedicineGeneral ChemistrykompleksiyhdisteetCombinatorial chemistry0104 chemical scienceschemistryReagentvisual_artElectrophilevisual_art.visual_art_mediumaluminylalumiiniyhdisteet
researchProduct

Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation

2020

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl) structural characterization by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to the low coordinate nature of the nitrogen centre. The Al-N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of the substrate…

010405 organic chemistrySubstrate (chemistry)General Chemistry010402 general chemistry01 natural sciencesIsocyanateCatalysis3. Good health0104 chemical scienceschemistry.chemical_compoundchemistryChemical bondReagentPolymer chemistryMoleculeImideBond cleavageCarbon monoxide
researchProduct

A nucleophilic gold complex.

2019

Solid-state auride salts featuring the negatively charged Au– ion are known to be stable in the presence of alkali metal counterions. While such electron-rich species might be expected to be nucleophilic (in the same manner as I–, for example), their instability in solution means that this has not been verified experimentally. Here we report a two-coordinate gold complex (NON)AlAuPtBu3 (where NON is the chelating tridentate ligand 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) that features a strongly polarized bond, Auδ––Alδ+. This is synthesized by reaction of the potassium aluminyl compound [K{Al(NON)}]2 with tBu3PAuI. Computational studies of the complex, includ…

chemistry.chemical_classification010405 organic chemistryChemistryLigandGeneral Chemical EngineeringAtoms in moleculesGeneral Chemistrykompleksiyhdisteetgold010402 general chemistryAlkali metal01 natural scienceskulta0104 chemical sciencesIonElectronegativityCrystallographyNucleophileCovalent bondcoordination complexesCounterionNature chemistry
researchProduct

Probing the Extremes of Covalency in M-Al bonds: Lithium and Zinc Aluminyl Compounds.

2022

Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing for the first structural characterization of an unsupported lithium-aluminium bond. Crystallographic and quantum-chemical studies are consistent with the presence of a highly polar Li-Al interaction, characterized by a low bond order and relatively little charge transfer from Al to Li. Comparison with magnesium and zinc aluminyl systems reveals changes to both the M-Al bond and the (NON)Al fragment (where NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene), consistent with a more covalent character, with the latter complex being shown to react with CO<sub>2</sub> vi…

low valent compoundssinkki (metallit)ChemistryMagnesiumaluminiumzincchemistry.chemical_elementkompleksiyhdisteetGeneral ChemistryZincGeneral MedicineBond orderCatalysiskemialliset sidoksetCrystallographylitiumNucleophilelithiumCovalent bondAluminiumaluminylPolarLithiumalumiiniAngewandte Chemie (International ed. in English)
researchProduct

Trapping and Reactivity of a Molecular Aluminium Oxide Ion

2019

Aluminium oxides constitute an important class of inorganic compound that are widely exploited in the chemical industry as catalysts and catalyst supports. Due to the tendency for such systems to aggregate via Al‐O‐Al bridges, the synthesis of well‐defined, soluble, molecular models for these materials is challenging. Here we show that reactions of the potassium aluminyl complex K 2 [( NON )Al] 2 ( NON = 4,5‐bis(2,6‐diiso‐propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethylxanthene) with CO 2 , PhNCO and N 2 O all proceed via a common aluminium oxide intermediate. This highly reactive species can be trapped by coordination of a THF molecule as the anionic oxide complex [( NON )AlO(THF)] ‐ , which …

small molecule activationOxidereduction010402 general chemistry01 natural sciencesHeterolysisCatalysischemistry.chemical_compoundPolymer chemistryMoleculeReactivity (chemistry)alumiiniBond cleavageAluminium oxides010405 organic chemistryaluminiumpelkistysGeneral MedicineGeneral Chemistrykompleksiyhdisteet0104 chemical sciencesHyponitritechemistryoksiditAluminium oxidealuminyloxide
researchProduct

Carbon Monoxide Activation by a Molecular Aluminium Imide: C−O Bond Cleavage and C−C Bond Formation

2020

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K 2 [( NON )Al(NDipp)] 2 ( NON = 4,5‐bis(2,6‐di iso propylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethyl‐xanthene; Dipp = 2,6‐di iso propylphenyl) structural characterization by X‐ray crystallography reveals a short Al‐N distance, which is thought to be due primarily to the low coordinate nature of the nitrogen centre. The Al‐N unit is highly polar, and capable of the activation of relatively inert chemical bonds, such as those found in dihydrogen and carbon monoxide. In the case of CO, uptake of two molecules of …

small molecule activation010405 organic chemistryaluminiumkompleksiyhdisteetGeneral Medicine010402 general chemistry01 natural sciencescarbon monoxide3. Good health0104 chemical sciencesaktivointiimidealuminylalumiinihiilimonoksidiAngewandte Chemie
researchProduct

Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion.

2018

The reactivity of aluminium compounds is dominated by their electron deficiency and consequent electrophilicity; these compounds are archetypal Lewis acids (electron-pair acceptors). The main industrial roles of aluminium, and classical methods of synthesizing aluminium–element bonds (for example, hydroalumination and metathesis), draw on the electron deficiency of species of the type AlR3 and AlCl31,2. Whereas aluminates, [AlR4]−, are well known, the idea of reversing polarity and using an aluminium reagent as the nucleophilic partner in bond-forming substitution reactions is unprecedented, owing to the fact that low-valent aluminium anions analogous to nitrogen-, carbon- and boron-centred…

Substitution reactionkemiallinen synteesiMultidisciplinaryanionit010405 organic chemistryaluminiumNacNacElectron deficiencyorganometalliyhdisteet010402 general chemistry01 natural sciencesOxidative additionMedicinal chemistry0104 chemical scienceschemistry.chemical_compoundNucleophilechemistryElectrophileorganometallic compoundsReactivity (chemistry)Lewis acids and basesalumiinianionschemical synthesisNature
researchProduct

Reversible, room-temperature C—C bond activation of benzene by an isolable metal complex

2019

The activation of C-C bonds is of fundamental interest in the construction of complex molecules from petrochemical feedstocks. In the case of the archetypal aromatic hydrocarbon benzene, C-C cleavage is thermodynamically disfavored, and is brought about only by transient highly reactive species generated in situ. Here we show that the oxidative addition of the C-C bond in benzene by an isolated metal complex is not only possible, but occurs at room temperature and reversibly at a single aluminium center in [(NON)Al]- (where NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene). Selectivity over C-H bond activation is achieved kinetically and allows for the generation…

chemistry.chemical_classificationchemistry.chemical_elementGeneral Chemistry010402 general chemistryCleavage (embryo)Photochemistry01 natural sciencesBiochemistryOxidative additionCatalysis3. Good health0104 chemical sciencesMetalchemistry.chemical_compoundColloid and Surface ChemistrychemistryAluminiumvisual_artvisual_art.visual_art_mediumMoleculeBenzeneSelectivityAromatic hydrocarbon
researchProduct

CCDC 2095879: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal System[N2N4-bis(246-trimethylphenyl)pentane-24-diiminato]-{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido)}-{mu-formato}-zinc-aluminium hexane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899009: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal System(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium (27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido))-aluminium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008538: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis(3-butylphenyl)-di-aluminium(iii)-di-potassium butylbenzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1854972: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Akseli Mansikkamäki, Petra Vasko, Jose M. Goicoechea,  Simon Aldridge|2019|Nature Chemistry|11|237|doi:10.1038/s41557-018-0198-1

(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-(tris(t-butyl)phosphine)-gold-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1972056: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium [14-bis(trimethylsilyl)tetra-az-2-enato]-(27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-aluminiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581596: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallography(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-iodo-gallium(iii) toluene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581598: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-hydrido-aluminium(iii) toluene solvateExperimental 3D Coordinates
researchProduct

CCDC 1972053: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-hydrido-(12-bis(26-dimethylphenylimino)-2-oxyethyl)-aluminium tetrahydrofuran solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899011: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium (hexa-135-triene-16-diyl)-(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido))-aluminium(iii) benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1972057: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-(26-di-isopropylphenylimine)-aluminium toluene solvateExperimental 3D Coordinates
researchProduct

CCDC 1899006: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal System(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium dichloro-{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-aluminium(iii) benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943804: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal Systembis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-bis(mu-hydrazine-12-diolato)-di-aluminium-di-potassium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943806: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal SystemCrystal Structurepotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(hydrido)-(hydroxy)-aluminium benzene solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1972054: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-benzyl-(trimethylsilylamide)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1972052: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

Space GroupCrystallographypotassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-hydrido-(26-dimethylanilide)-aluminium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943805: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterspotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-oxo-(tetrahydrofuran)-aluminium benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1854971: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Akseli Mansikkamäki, Petra Vasko, Jose M. Goicoechea,  Simon Aldridge|2019|Nature Chemistry|11|237|doi:10.1038/s41557-018-0198-1

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-[(propan-2-yl)azanidyl][(propan-2-yl)imino]methyl)-(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-(tris(t-butyl)phosphine)-aluminium-gold benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 2095878: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(N2N4-bis(246-trimethylphenyl)pentane-24-diiminato)-aluminium-zincExperimental 3D Coordinates
researchProduct

CCDC 2095877: Experimental Crystal Structure Determination

2021

Related Article: Matthew M. D. Roy, Jamie Hicks, Petra Vasko, Andreas Heilmann, Anne-Marie Baston, Jose M. Goicoechea, Simon Aldridge|2021|Angew.Chem.,Int.Ed.|60|22301|doi:10.1002/anie.202109416

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters{27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-bis(diethyl ether)-lithium-aluminium diethyl ether solvateExperimental 3D Coordinates
researchProduct

CCDC 1581594: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-di-gallium(i)-di-potassium(i) toluene solvateExperimental 3D Coordinates
researchProduct

CCDC 1854973: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Akseli Mansikkamäki, Petra Vasko, Jose M. Goicoechea,  Simon Aldridge|2019|Nature Chemistry|11|237|doi:10.1038/s41557-018-0198-1

Space GroupCrystallography(mu-iodo)-bis(triphenylphosphine)-(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-di-gold-aluminium diethyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899010: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallography(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium (27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminido))-phenyl-hydrido-aluminium(iii) benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581591: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal System{27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato}-iodo-aluminium toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943808: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographyCrystal Systempotassium (27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-(phenylcarbamato)-aluminium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581600: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal Systembis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-bis(mu-hydrido)-dihydrido-di-aluminium-di-potassium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581593: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(N2N4-bis(246-trimethylphenyl)pentane-24-diiminato)-(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-aluminium(i)-magnesium(ii)Experimental 3D Coordinates
researchProduct

CCDC 1581592: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

bis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-di-aluminium(i)-di-potassium(i) benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581599: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographybis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-bis(mu-hydrido)-diphenyl-di-aluminium-di-potassium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1943807: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Andreas Heilmann, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|Angew.Chem.,Int.Ed.|58|17265|doi:10.1002/anie.201910509

Space GroupCrystallographybis(mu-carbonato)-bis(mu-27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diaminato)-di-aluminium-di-potassium benzene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899005: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal SystemCrystal Structurebis(chloro)-(mu-hexa-135-triene-16-diyl)-tetramethyl-di-tin(iv)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581595: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal Structurebis(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-di-aluminium(ii) hexane pentane solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008540: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

bis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-(4-methylphenyl)methyl-hydrido-di-aluminium(iii)-di-potassium n-hexane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1854974: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Akseli Mansikkamäki, Petra Vasko, Jose M. Goicoechea,  Simon Aldridge|2019|Nature Chemistry|11|237|doi:10.1038/s41557-018-0198-1

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-formato)-(tris(t-butyl)phosphine)-(45-bis(26-diisopropylanilido)-27-di-t-butyl-99-dimethylxanthene)-gold-aluminium benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 2008537: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal Systembis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((3-methylphenyl)methyl)-di-aluminium(iii)-di-potassium toluene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1899008: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4713162124-hexaoxa-110-diazabicyclo[8.8.8]hexacosane)-potassium {27-di-t-butyl-N4N5-bis[26-bis(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-diaminato}-(hydrido)-(naphthalen-2-yl)-aluminium benzene solvateExperimental 3D Coordinates
researchProduct

CCDC 1972055: Experimental Crystal Structure Determination

2020

Related Article: Andreas Heilmann, Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|4897|doi:10.1002/anie.201916073

potassium (27-di-t-butyl-N4N5-bis[26-di-isopropylphenyl]-99-dimethyl-9H-xanthene-45-diamine)-({[26-di-isopropylphenyl]imino}acetato)-aluminium benzene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1581597: Experimental Crystal Structure Determination

2018

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2018|Nature (London)|557|92|doi:10.1038/s41586-018-0037-y

Space GroupCrystallographyCrystal SystemCrystal Structure(27-di-t-butyl-N4N5-bis[26-diisopropylphenyl]-99-dimethyl-9H-xanthene-45-diamido)-methyl-aluminium(iii) toluene solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008536: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((3-methylphenyl)methyl)-di-aluminium(iii)-di-potassium n-hexane solvateExperimental 3D Coordinates
researchProduct

CCDC 1899007: Experimental Crystal Structure Determination

2019

Related Article: Jamie Hicks, Petra Vasko, Jose M. Goicoechea, Simon Aldridge|2019|J.Am.Chem.Soc.|141|11000|doi:10.1021/jacs.9b05925

Space GroupCrystallographyCrystal Systempotassium (27-di-tert-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-ethene-aluminium benzene solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008541: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

bis(mu-methyl)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis(phenolato)-di-aluminium(iii)-di-potassium toluene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2010397: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-bromo)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-diphenyl-di-aluminium(iii)-di-potassium(i) benzene solvateCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2008539: Experimental Crystal Structure Determination

2020

Related Article: Jamie Hicks, Petra Vasko, Andreas Heilmann, Jose M. Goicoechea, Simon Aldridge|2020|Angew.Chem.,Int.Ed.|59|20376|doi:10.1002/anie.202008557

Space GroupCrystallographybis(mu-hydrido)-bis(27-di-t-butyl-N4N5-bis[26-di(propan-2-yl)phenyl]-99-dimethyl-9H-xanthene-45-bis(aminide))-bis((2-methylphenyl)methyl)-di-aluminium(iii)-di-potassium 12-xylene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct