Experimental and numerical study of anomalous thermocapillary convection in liquid gallium

Thermocapillary Marangoni convection of liquid gallium was studied experimentally and numerically. A specially designed experimental setup ensured an oxide-free surface of the liquid gallium for a very long time. The convective flow at the free surface was found to be directed opposite to both buoyancy-driven and ordinary thermocapillary convection. The anomalous direction of the thermocapillary flow was explained by the presence of a small amount of a surface-active contaminant—lead adsorbed at the free surface. Two different approaches were used to describe the observed phenomenon. First, the flow was treated as a pure thermocapillary convection with a modified dependence of the surface t…