0000000000215245
AUTHOR
Martha F. Koziol
Bone Scaffolds Based on Degradable Vaterite/PEG‐Composite Microgels
Vaterite, a metastable modification of calcium carbonate, embedded in a flexible microgel packaging with adjustable mechanical properties, functionality, and biocompatibility, provides a powerful scaffolding for bone tissue regeneration, as it is easily convertible to bone-like hydroxyapatite (HA). In this study, the synthesis and physical analysis of a packaging material to encapsulate vaterite particles and osteoblast cells into monodisperse, sub-millimeter-sized microgels, is described whereby a systematic approach is used to tailor the microgel properties. The size and shape of the microgels is controlled via droplet-based microfluidics. Key requirements for the polymer system, such as …
Origin of the low-frequency plateau and the light-scattering slow mode in semidilute poly(ethylene glycol) solutions
A low-frequency plateau is often found in the rheological spectra of various kinds of semidilute solutions of polymers and other colloids; also, many such solutions have been reported to show slow-modes in their dynamic light scattering autocorrelation functions. Both these observations may lead to the hypothesis of weak associative network structures built by the dissolved polymer chains or colloidal building blocks. To challenge this hypothesis, we conduct a series of comparative studies on semidilute solutions of poly(ethylene glycol) by using classical rheology as well as passive microrheology based on dynamic light scattering, along with structural studies using static light scattering…
Structural and Gelation Characteristics of Metallo-Supramolecular Polymer Model-Network Hydrogels Probed by Static and Dynamic Light Scattering
Supramolecular polymer gels are a promising class of materials whose polymer components are connected by transient bonds such as metal–ligand interactions, thereby spanning a dynamic network throug...