0000000000222714
AUTHOR
María Bayona-andrés
Slow Relaxation of the Magnetization in Anilato-Based Dy(III) 2D Lattices.
The search for two- and three-dimensional materials with slow relaxation of the magnetization (single-ion magnets, SIM and single-molecule magnets, SMM) has become a very active area in recent years. Here we show how it is possible to prepare two-dimensional SIMs by combining Dy(III) with two different anilato-type ligands (dianions of the 3,6-disubstituted-2,5-dihydroxy-1,4-benzoquinone: C6O4X22−, with X = H and Cl) in dimethyl sulfoxide (dmso). The two compounds prepared, formulated as: [Dy2(C6O4H2)3(dmso)2(H2O)2]·2dmso·18H2O (1) and [Dy2(C6O4Cl2)3(dmso)4]·2dmso·2H2O (2) show distorted hexagonal honeycomb layers with the solvent molecules (dmso and H2O) located in the interlayer space and…
CCDC 2054148: Experimental Crystal Structure Determination
Related Article: Samia Benmansour, Antonio Hernández-Paredes, María Bayona-Andrés, Carlos J. Gómez-García|2021|Molecules|26|1190|doi:10.3390/molecules26041190