0000000000223279

AUTHOR

Amgalanbaatar Baldansuren

showing 2 related works from this author

Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct

2017

The solid and solution state structure of the vanadium(II) N‐ heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported ( SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐ en‐2‐ylidene). The electronic structure of 1 is probed using combination of magnetic measurements, EPR spectroscopy and computational studies. The V–Si bond strength and complex forming mechanism between vanadocene and NHSi ligand is elucidated using computational methods.   peerReviewed

piiVanadiumchemistry.chemical_elementElectronic structure010402 general chemistryPhotochemistry01 natural sciencesvanadiiniAdductlaw.inventionInorganic Chemistrychemistry.chemical_compoundlawcoordination complexesElectron paramagnetic resonanceta116010405 organic chemistryChemistryLigandBond strengthSilylenesiliconkompleksiyhdisteetVanadocene0104 chemical sciencesCrystallographyvanadiumDalton Transactions
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CCDC 1485743: Experimental Crystal Structure Determination

2017

Related Article: Mikko M. Hänninen, Amgalanbaatar Baldansuren, Thomas Pugh|2017|Dalton Trans.|46|9740|doi:10.1039/C7DT01226H

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(13-bis(26-bis(propan-2-yl)phenyl)-132-diazasilol-2-ylidene)-bis(eta5-cyclopentadienyl)-vanadiumExperimental 3D Coordinates
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