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RESEARCH PRODUCT
Structural and electronic elucidation of a N-heterocyclic silylene vanadocene adduct
Amgalanbaatar BaldansurenMikko M. HänninenThomas Pughsubject
piiVanadiumchemistry.chemical_elementElectronic structure010402 general chemistryPhotochemistry01 natural sciencesvanadiiniAdductlaw.inventionInorganic Chemistrychemistry.chemical_compoundlawcoordination complexesElectron paramagnetic resonanceta116010405 organic chemistryChemistryLigandBond strengthSilylenesiliconkompleksiyhdisteetVanadocene0104 chemical sciencesCrystallographyvanadiumdescription
The solid and solution state structure of the vanadium(II) N‐ heterocyclic silylene (NHSi) complex, [(SiIPr)V(Cp)2] (1) is reported ( SiIPr: 1,3‐bis(2,6‐diisopropylphenyl)‐1,3‐diaza‐2‐silacyclopent‐4‐ en‐2‐ylidene). The electronic structure of 1 is probed using combination of magnetic measurements, EPR spectroscopy and computational studies. The V–Si bond strength and complex forming mechanism between vanadocene and NHSi ligand is elucidated using computational methods. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-05-18 | Dalton Transactions |