0000000000225177

AUTHOR

Chong-wen Zhou

0000-0003-0845-988x

showing 2 related works from this author

Oxidation of pentan-2-ol -Part II: Experimental and modeling study

2021

International audience; The oxidation of pentan-2-ol was investigated at high-pressure in a jet-stirred reactor and in a shock tube. Experiments in the JSR were carried out at 10 atm, between 500-1180 K, for five different equivalence ratios of = 0.35, 0.5, 1, 2, 4 and 1000 ppm of fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were quantified using Fourier transform infrared spectrometry (FTIR) and gas chromatography (GC). Ignition delay times were measured for pentan-2-ol/O 2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1070-1460 K and for equivalence ratios of = 0.5, 1 and 2. Ignition delay times of a…

Materials scienceGeneral Chemical Engineeringpentan-2-olAnalytical chemistrychemistry.chemical_element02 engineering and technologyshock tube010402 general chemistryMole fraction01 natural sciences020401 chemical engineeringAb initio quantum chemistry methods0204 chemical engineeringPhysical and Theoretical ChemistryFourier transform infrared spectroscopyShock tubeArgonMechanical Engineering[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environmentdetailed mechanismAtmospheric temperature rangebiofuels0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistrychemistrykineticsjet-stirred reactorGas chromatographyStoichiometry
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Methyl-3-Hexenoate Combustion Chemistry: Experimental Study and Numerical Kinetic Simulation

2020

International audience; This work represents a detailed investigation of combustion and oxidation of methyl-3-hexenoate (CAS Number 2396-78-3), including experimental studies of combustion and oxidation characteristics, quantum chemistry calculations and kinetic model refinement. Following experiments have been carried out: Speciation measurements during oxidation in a jet-stirred reactor at 1 atm; chemical speciation measurements in a stoichiometric premixed flame at 1 atm using molecular-beam mass-spectrometry; ignition delay times measurements in a shock tube at 20 and 40 bar; and laminar burning velocity measurements at 1 atm using a heat-flux burner over a range of equivalence ratios. …

Materials scienceGeneral Chemical EngineeringFlame structureGeneral Physics and AstronomyEnergy Engineering and Power TechnologyThermodynamics02 engineering and technologyKinetic energyCombustion01 natural sciences7. Clean energylaw.invention020401 chemical engineeringlawOxidation mechanisms0103 physical sciencesOxidationJet stirred reactor0204 chemical engineeringShock tubePremixed flame010304 chemical physics[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environmentBurning velocityLaminar flowGeneral Chemistrykinetic modelingIgnitionbiofuelsIgnition system[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryFuel TechnologyFlame structureCombustorMethyl-3-hexenoate
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