0000000000230194
AUTHOR
Nicolas Murer
Numerical modelling of the galvanic coupling in aluminium alloys: A discussion on the application of local probe techniques
Abstract A discussion is proposed on the determination of the input values and the experimental validation of finite element modelling of the galvanic coupling in aluminium alloys by local probe techniques such as the Scanning Vibrating Electrode Technique (SVET) and the microcapillary electrochemical cell (microcell). Polarization curves obtained by the microcell were introduced as input conditions in the model based on Laplace or Nernst–Planck equation. SVET measurements were performed to determine the coupling current distribution on an Al/Al4%Cu bimetallic system. Agreement was found between simulated and experimental current distributions depending on the input conditions and the solve…
Contribution to the modeling of microstructural corrosion on aluminium alloys : definition of a methodology to study the bimetallic corrosion phenomena
The initiation and the propagation of aluminum alloys microstructural corrosion is mainly based on the bimetallic corrosion phenomenon. This type of corrosion is caused by galvanic coupling at a local scale between the different phases contained in the alloy. The description of the localized corrosion phenomenon has been largely studied. Their complexity can explain why they are so difficult to predict by the way of numerical tools and why the works that have been done on this subject are so scarce. The present thesis brings a new contribution to this field by suggesting a methodology based on the complementary use of local electrochemical techniques and the finite element simulation of bim…