0000000000240390

AUTHOR

E.martínez Tamayo

showing 2 related works from this author

Study of the thermal decomposition of bromazepan complexes with Co(II), Ni(II), Cu(II) and Zn(II)

1984

Abstract The thermal behaviour of complexes of bromazepan with Co(II), Ni(II), Cu(II) and Zn(II) was studied by thermogravimetry (TG) and differential thermal analysis (DTA). The complexes decompose in two steps: dehydration and decomposition. A correlation between the dehydration temperatures of MB2Xn and the coordinating ability of X is observed.

Reaction mechanismChemistryThermal decompositionInorganic chemistryCondensed Matter Physicsmedicine.diseaseDecompositionThermogravimetryDifferential thermal analysisThermalmedicineDehydrationPhysical and Theoretical ChemistryInstrumentationPyrolysisThermochimica Acta
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Synthesis of high surface area perovskite catalysts by non-conventional routes

1997

Abstract The use of rare earth-containing perovskite oxides as total oxidation catalysts faces to the difficulty of obtaining high surface area materials and the need of calcination at high temperatures for its synthesis. In this work, perovskite NdCoO3 catalysts with relatively high surface areas were synthesized at soft calcination conditions by two non-conventional routes: heteronuclear organic complexes and amorphous precursors obtained by freeze-drying of nitrates solutions. Depending on the method used, different degrees of homogeneity in the bulk distribution of the component cations, oxygen non-stoichiometry as well as surface Co/Nd atomic ratios are obtained. In this way, the synth…

chemistry.chemical_classificationInorganic chemistryCatalytic combustionGeneral ChemistryHeterogeneous catalysisCatalysisCatalysisAmorphous solidlaw.inventionchemistry.chemical_compoundHydrocarbonchemistryHeteronuclear moleculeTernary compoundlawCalcinationCatalysis Today
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