0000000000243145
AUTHOR
Sotiris Droulias
Surface Plasmons for Chiral Sensing
Chiral sensitive techniques have been used to probe the fundamental symmetries of the universe, study biomolecular structures, and even develop safe drugs. The traditional method for the measurement of chirality is through optical activity, however, chiroptical signals are inherently weak and often suppressed by large backgrounds. Different techniques have been proposed to overcome the limitations of traditionally used optical polarimetry, such as cavity- and/or nanophotonic-based schemes. In this chapter we demonstrate how surface plasmon resonance can be employed as a new research tool for chiral sensing, which we term here as CHIral Surface Plasmon Resonance (CHISPR). We present how surf…
Absolute Chiral Sensing in Dielectric Metasurfaces Using Signal Reversals.
Sensing molecular chirality at the nanoscale has been a long-standing challenge due to the inherently weak nature of chiroptical signals, and nanophotonic approaches have proven fruitful in accessing these signals. However, in most cases, absolute chiral sensing of the total chiral refractive index has not been possible, while the strong inherent signals from the nanostructures themselves obscure the weak chiroptical signals. Here, we propose a dielectric metamaterial system that overcomes these limitations and allows for absolute measurements of the total chirality, and the possibility for a crucial signal reversal that enables chirality measurements without the need for sample removal. As…
Surface Plasmon Platform for Angle-Resolved Chiral Sensing
Chiral sensitive techniques have been used to probe the fundamental symmetries of the universe, study biomolecular structures, and even develop safe drugs. As chiral signals are inherently weak and...