0000000000246173

AUTHOR

Jens Linnek

showing 3 related works from this author

Cycloartane Glycosides from Three Species of Astragalus (Fabaceae)

2011

Nine cycloartane-type glycosides were isolated from three species of the genus Astragalus (Fabaceae): From the aerial parts of A. cicer L., two new saponins, cicerosides A and B (1 and 2, resp.), i.e., a tetradesmosidic and tridesmosidic cycloartane-type glycosides besides one known compound, from the roots of A. sempervirensLam., one known saponin, and from the roots of A. ptilodesBoiss. var. cariensisBoiss., five known compounds. Their structures were established mainly by 600-MHz 2D-NMR techniques (1H,1H-COSY, TOCSY, NOESY, HSQC, and HMBC) and mass spectroscopy.

chemistry.chemical_classificationbiologyAstragalus speciesOrganic ChemistrySaponinGlycosideFabaceaebiology.organism_classificationBiochemistryCatalysisInorganic ChemistryAstragaluschemistryGenusDrug DiscoveryBotanyPhysical and Theoretical ChemistryTwo-dimensional nuclear magnetic resonance spectroscopyHelvetica Chimica Acta
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Two new triterpenoid saponins fromPittosporum senaciaPutterlick (Pittosporaceae)

2012

From the branches of Pittosporum senacia Putterlick (Pittosporaceae), two new triterpenoid saponins, senaciapittosides A and B (1, 2), were isolated. Their structures were elucidated by extensive analysis of one- and two-dimensional nuclear magnetic resonance spectroscopy, high-resolution electrospray ionization mass spectrometry (HR-ESIMS) and chemical evidence as 3-O-[β-d-glucopyranosyl-(1  2)]-[α-l-arabinopyranosyl-(1  3)]-[α-l-arabinofuranosyl-(1  4)]-β-d-glucuronopyranosyl oleanolic acid 28-O-β-d-glucopyranosyl ester (1) and 3-O-[β-d-glucopyranosyl-(1  2)]-[α-l-arabinopyranosyl-(1  3)]-[α-l-arabinofuranosyl-(1  4)]-β-d-glucuronopyranosyl-22-O-α-l-arabinopyranosyl-21-acetoxy R1-barrigen…

GlycosylationbiologyStereochemistryElectrospray ionizationPittosporaceaeGeneral ChemistryNuclear magnetic resonance spectroscopybiology.organism_classificationchemistry.chemical_compoundAglyconechemistryGeneral Materials SciencePittosporum senaciaOleanolic acidTwo-dimensional nuclear magnetic resonance spectroscopyMagnetic Resonance in Chemistry
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Cycloartane-type Glycosides from Two Species of Astragalus (Fabaceae)

2009

Three known cycloartane-type glycosides were isolated from the roots of two different species of Astragalus, A. glycyphyllos, A. sempervirens. The identification of these compounds were mainly achieved by 2D NMR spectroscopic techniques and FAB-MS. The results of our studies confirm that triterpene saponins from the cycloartane-type skeleton might be chemotaxonomically significant to the genus Astragalus.

Pharmacologychemistry.chemical_classificationTraditional medicinebiologyChemistryPlant compositionGlycosidePlant ScienceGeneral MedicineFabaceaebiology.organism_classificationAstragalusComplementary and alternative medicineTriterpeneGenusDrug DiscoveryNatural Product Communications
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