0000000000246795
AUTHOR
Andreas Scholl
Temperature-induced martensite in magnetic shape memory Fe2MnGa observed by photoemission electron microscopy
The magnetic domain structure in single crystals of a Heusler shape memory compound near the composition Fe2MnGa was observed during phase transition by photoelectron emission microscopy at Beamline 11.0.1.1 of the Advanced Light Source. The behavior is comparable with recent observations of an adaptive martensite phase in prototype Ni2MnGa, although the pinning in the recent work is an epitaxial interface and in this work the effective pinning plane is a boundary between martensitic variants that transform in a self-accommodating way from the single crystal austenite phase present at high temperatures. Temperature dependent observations of the twinning structure give information as to the …
Lateral versus perpendicular segregation in mixed polymer brushes.
Grafting of incompatible polymers on a substrate prevents macrophase separation and the chains self-assemble laterally. Mixed brushes are exposed to different solvents and the morphology is observed via atomic force and x-ray photoemission microscopy. In a nonselective solvent the different species segregate into parallel cylinders ("ripple structure"). Upon exposure to a selective solvent, we encounter a transition to a "dimple" structure, in which the unfavored component forms clusters. Simultaneously, we observe an enhanced perpendicular segregation. The experimental observations are compared to self-consistent field calculations, where qualitative agreement is found.
Nanostructured Polymer Brushes With Reversibly Changing Properties
AbstractWe investigated the interplay between different mechanisms of the lateral and vertical segregation in the synthesized via “grafting from” approach symmetric A/B (where A and B are poly(styrene-co-2,3,4,5,6-pentafluorostyrene) and poly(methylmethacrylate), respectively) polymer brushes upon exposure to different solvents. We used X-ray photoemission electron spectroscopy and microscopy (X-PEEM), AFM, water contact angle measurements, and oxygen plasma etching to study morphology of the brushes. The ripple morphology after toluene (nonselective solvent) revealed elongated lamellar-like domains of A and B polymers alternating across the surface. The dimple-A morphology consisting of ro…