Carbon, iron and sulphur cycling in the sediments of a Mediterranean lagoon (Ghar El Melh, Tunisia)

Coastal lagoon sediments are important for the biogeochemical carbon cycle at the land-ocean transition, as they form hotspots for organic carbon burial, as well as potential sites for authigenic carbonate formation. Here, we employ an early diagenetic model to quantify the coupled redox cycling of carbon, iron and sulphur in the sediments of the shallow Ghar El Melh (GEM) lagoon (Tunisia). The model simulated depth profiles show a good correspondence with available pore water data (dissolved inorganic carbon, NH 4 + , total alkalinity, Ca 2+ , Fe 2+ and SO 4 2− ) and solid phase data (organic matter, pyrite, calcium carbonate and iron (oxyhydr)oxides). This indicates that the model is abl…