Ellipsometric study of the physical states of phosphatidylcholines at the air-water interface

1990

Etude des couches monomoleculaires de dimyristoylphosphatidylcholine, de dipalmitoylphosphatidylcholine, de distearoyl phosphatidylcholine, de diarachidoylphosphatidylcholine a l'interface air/eau

Ellipsometric and fluorescence microscopic investigations of a cyclam derivative at the air/water interface

1993

Optical measurements of an acylated azacrown at the air-water interface

1991

In this study, a cyclame derivative bearing four aliphatic chain substituents shows, like many amphiphiles, solid-condensed as well as liquid-expanded phases. In contrast to the classical amphiphiles, the onset of its phase transition is characterized by a bump-like shape whose amplitude is a function of the compression speed. Ellipsometry which is very sensitive to the monolayer physical state changes, and fluorescence microscopy which has contributed significantly to the understanding of the phenomena occurring in the phase transition region have been used to investigate the monolayer behavior of this compound. This study shows that in the liquid-expanded state, the film is homogeneous an…