0000000000269763

AUTHOR

Garry J. Mcintyre

showing 5 related works from this author

Photostimulated luminescence properties of neutron image plates

2016

Abstract The luminescence properties of two commercial neutron-sensitive image-plates based on Gd 2 O 3 -doped BaFBr:Eu 2 + storage phosphors are examined. These are white Fuji plates and blue Fuji plates (BAS-ND) with Gd 2 O 3 content by weight of 34% and 50%, respectively. Both plates show two maxima in the photostimulation spectrum near 500 nm and 600 nm, with the ratio of the peak responses ( I 600 nm / I 500 nm ) 1.39 and 0.53 for the white and blue plates respectively. The optimum wavelengths for photostimulation for the two phosphors are therefore different. The response of the blue plate is only 25% that of the white plate, if each is stimulated at its optimum wavelength.

Materials sciencePhotostimulated luminescenceAnalytical chemistryPhosphor02 engineering and technology01 natural sciencesPhotostimulationInorganic ChemistryNeutronenOptics0103 physical sciencesNeutronElectrical and Electronic EngineeringPhysical and Theoretical Chemistry010306 general physicsSpectroscopybusiness.industryOrganic ChemistryDoping021001 nanoscience & nanotechnologyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsWavelengthStorage phosphorPhotolumineszenzLumineszenz0210 nano-technologybusinessLuminescenceOptical Materials
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Elastic and quasielastic neutron scattering studies in KBr:KCN mixed crystals

1989

Neutron scattering studies in (KBr)1–x(KCN)x mixed crystals are presented utilizing powder diffraction, single crystal diffraction and time-of-flight techniques. Forx>0.6 (KBr)1–x(KCN)x crystals exhibit ferroelastic and ferroelectric low-temperature phases. Crystals withx<0.6 undergo transitions into an orientational glass state. Here we present a detailed phase diagram including new results for x=0.85 and x=0.65. For the latter system a stable rhombohedral low-temperature phase has been detected where the orientational disorder of the plastic phase is only partly removed and quadrupolar relaxations between three body diagonals are still possible. From the powder diffraction experimen…

Materials scienceCondensed matter physicsDynamic structure factorNeutron scatteringCondensed Matter Physics530Electronic Optical and Magnetic MaterialsPhase (matter)Quasielastic neutron scatteringGeneral Materials ScienceGlass transitionOrientational glassPowder diffractionPhase diagram
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Temperature- and pressure-dependent structural study of {Fe(pmd) 2[Ag(CN)2 ]2}n spin-crossover compound by neutron Laue diffraction

2014

The effect of pressure (up to 0.17GPa) on the spin-crossover compound {Fe(pmd)2[Ag(CN)2]2} n [orthorhombic isomer (II), pmd = pyrimidine] has been investigated by temperature- and pressure-dependent neutron Laue diffraction and magnetometry. The cooperative high-spin ↔ low-spin transition, centred at ca 180K at ambient pressure, is shifted to higher temperatures as pressure is applied, showing a moderate sensitivity of the compound to pressure, since the spin transition is displaced by ca 140KGPa-1. The space-group symmetry (orthorhombic Pccn) remains unchanged over the pressure-temperature (P-T) range studied. The main structural consequence of the high-spin to low-spin transition is the c…

Pressure-temperatureChemistryMetals and AlloysSpin transitionChromophoreChromophoresAtomic and Molecular Physics and OpticsSpin-crossover compoundsElectronic Optical and Magnetic MaterialsCrystallographyOctahedronSpin crossoverX-ray crystallographyMaterials ChemistryNeutronOrthorhombic crystal systemMagnetic materialsAmbient pressure
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Neutron diffraction experiments on UCu4+xAl8−x

1992

Abstract Neutron diffraction experiments are reported on UCu4+xAl8−x for concentrations 0.1≤ x ≤1.9 and temperatures 1.6 K≤T≤300 K. For x ≤ 1 these compounds undergo antiferromagnetic phase transitions into a collinear AF I-type structure. with the magnetic moments aligned along the tetragonal c-axis and alternating order within the a−b planes. With increasing concentration the ordering temperatures decrease and moment compensation due to a Kondo-type interaction develops for x>1.

Phase transitionTetragonal crystal systemMaterials scienceCondensed matter physicsMagnetic momentMoment (physics)Neutron diffractionAntiferromagnetismCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsJournal of Magnetism and Magnetic Materials
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Magnetic order in UCu4+xAl8−x

1992

Abstract A neutron diffraction study has been performed on UCu4+xAl8−x. The compound was chosen as an example of a uranium-based system, which goes from a magnetically ordered state to a pure heavy-fermion state. In the range x = 0.25–1, UCu4+xAl8−x orders in a simple collinear antiferromagnetic structure. With increasing concentration of Cu, the ordering temperature decreases and moment compensation develops due to the increasing hybridization of the 5f electrons.

Range (particle radiation)Materials scienceCondensed matter physicsMagnetic orderNeutron diffractionchemistry.chemical_elementElectronState (functional analysis)UraniumCondensed Matter PhysicsElectronic Optical and Magnetic MaterialschemistryMoment (physics)Antiferromagnetism
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