0000000000280201

AUTHOR

L. Soto

showing 16 related works from this author

Electronic properties and crystal structure of aqua (mepirizole-oxalato)copper(II)monohydrate: [Cu(C11H14N4O2)C2O4·H2O]H2O

1988

Abstract A Cu(ll) complex with mepirizole: 4-methoxy-2-(5-methoxy-3-methyl-pyrazoll-yl)-6-methylpyrimidine (L) and oxalate as ligands with the formula [CuL(C2O4)(H2O)]·H2O has been synthesized. The crystal structure has been determined by X-ray diffraction analysis: monoclinic, space group P21/n, Z = 4, a = 7.707(1), b = 14.951(3), c = 14.986(2) A,β = 92.40(2)°, V = 1725.2(8) A3, Dm = 1.61(1) g cm−3, Dc = 1.62 g cm−3, R = 0.032 and Rw = 0.035 for 2016 observed reflections. The CuN2O2O′chromophore can be described as square pyramidal strongly distorted towards trigonal bipyramidal. The basal coordination positions are occupied by the two oxygen atoms of the bidentate oxalate group, the coord…

DenticityStereochemistryCrystal structureOxalateSquare pyramidal molecular geometryInorganic Chemistrychemistry.chemical_compoundTrigonal bipyramidal molecular geometryCrystallographychemistryX-ray crystallographyMaterials ChemistryCarboxylatePhysical and Theoretical ChemistryMonoclinic crystal systemPolyhedron
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Crystal structure of copper(II) cimetidine sulphate nonahydrate. Cation distortion and structure isomerism in three copper(II) cimetidine complexes

1988

Abstract In the crystalline state, the complex [Cu(CM) 2 ]SO 4 ·9H 2 O (CM = cimetidine) is constituted of two-dimensional cations[Cu(CM) 2 2+ ] n separated by SO 4 2− anions and water molecules. As in the related complexes [Cu(CM) 2 ](ClO 4 ) 2 and [Cu(CM) 2 ](NO 3 ) 2 , the copper atom lies in a strongly distorted octahedral CuN 4 S 2 environment. The distortion is quite different from one complex to another (cation distortion isomerism). In the title compound the CuS bond is unusually long (2.91 A). Unlike the title compound, the [Cu(CM) 2 2+ ] n cations in the perchlorate and nitrate salts are one-dimensional infinite chains characterized by different conformations of the cimetidine mo…

chemistry.chemical_classificationHydrogen bondInorganic chemistrychemistry.chemical_elementCrystal structureCopperInorganic ChemistryCrystallographyPerchloratechemistry.chemical_compoundchemistryOctahedronX-ray crystallographyMaterials ChemistryPhysical and Theoretical ChemistryHydrateInorganic compoundPolyhedron
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CCDC 654606: Experimental Crystal Structure Determination

2008

Related Article: H.Nunez, J.Server-Carrio, E.Escriva, L.Soto, J.Garcia-Lozano, A.Sancho, B.Verdejo, E.Garcia-Espana|2008|Polyhedron|27|633|doi:10.1016/j.poly.2007.10.026

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesDiammonium bis(2-(bis(1H-imidazol-2-yl)methyl)malonate-NN'O)-copper(ii) tetrahydrate
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CCDC 654607: Experimental Crystal Structure Determination

2008

Related Article: H.Nunez, J.Server-Carrio, E.Escriva, L.Soto, J.Garcia-Lozano, A.Sancho, B.Verdejo, E.Garcia-Espana|2008|Polyhedron|27|633|doi:10.1016/j.poly.2007.10.026

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersAqua-(2-(bis(1H-imidazol-2-yl)methyl)malonate-NN'O)-(ethylenediamine-NN')-copper(ii) pentahydrateExperimental 3D Coordinates
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CCDC 212724: Experimental Crystal Structure Determination

2005

Related Article: H.Nunez, L.Soto, J.Server-Carrio, J.Garcia-Lozano, A.Sancho, R.Acerete, E.Escriva|2005|Inorg.Chem.|44|4644|doi:10.1021/ic048234x

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(mu~3~-bis(2(1H)-Imidazolyl)methylmalonato)-tetrakis(mu~2~-aqua)-hexa-aqua-tetra-sodium
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CCDC 177331: Experimental Crystal Structure Determination

2002

Related Article: Y.Akhriff, J.Server-Carrio, A.Sancho, J.Garcia-Lozano, E.Escriva, L.Soto|2001|Inorg.Chem.|40|6832|doi:10.1021/ic0106571

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-((mu~4~-Squarato)-tetrakis(mu~2~-33-bis(2-imidazolyl)propionato-NN'O)-tetra-aqua-tetra-copper(ii) diperchlorate tetrahydrate)Cell ParametersExperimental 3D Coordinates
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CCDC 212725: Experimental Crystal Structure Determination

2005

Related Article: H.Nunez, L.Soto, J.Server-Carrio, J.Garcia-Lozano, A.Sancho, R.Acerete, E.Escriva|2005|Inorg.Chem.|44|4644|doi:10.1021/ic048234x

Space GroupCrystallographybis(bis(2(1H)-Imidazolyl)methylmalonato)-copper(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 168232: Experimental Crystal Structure Determination

2001

Related Article: H.Nunez, J.-J.Timor, J.Server-Carrio, L.Soto, E.Escriva|2001|Inorg.Chim.Acta|318|8|doi:10.1016/S0020-1693(01)00390-5

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu~2~-Oxalato)-bis(bis(2-imidazolyl)-bis(methoxycarbonyl)methylmethane-NN'O)-di-copper(ii) tetrahydrateCell ParametersExperimental 3D Coordinates
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CCDC 996415: Experimental Crystal Structure Determination

2014

Related Article: C. J. Gómez-García, E. Escrivà, G. Mínguez Espallargas, J. J. Borrás-Almenar, L. Soto, A. Sancho, J. García-Lozano, C. Ramírez de Arellano|2014|Dalton Trans.|43|11371|doi:10.1039/C4DT01099J

catena-[(mu2-(bis(1H-imidazol-2-yl)methyl)malonato)-triaqua-di-nickel(ii) dihydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 212726: Experimental Crystal Structure Determination

2005

Related Article: H.Nunez, L.Soto, J.Server-Carrio, J.Garcia-Lozano, A.Sancho, R.Acerete, E.Escriva|2005|Inorg.Chem.|44|4644|doi:10.1021/ic048234x

Space GroupCrystallographyCrystal Systembis(mu~2~-bis(2(1H)-Imidazolyl)methylmalonato)-diaqua-di-copper(ii) dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 228622: Experimental Crystal Structure Determination

2004

Related Article: E.Escriva, J.Garcia-Lozano, J.Martinez-Lillo, H.Nunez, J.Server-Carrio, L.Soto, R.Carrasco, J.Cano|2003|Inorg.Chem.|42|8328|doi:10.1021/ic034126j

Space GroupCrystallography(mu~2~-Hydroxo)-(mu~2~-pyrazol-12-diyl)-bis(4-methoxy-2-(5-methoxy-3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine)-dibromo-di-copper(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 886172: Experimental Crystal Structure Determination

2013

Related Article: H.Sanchez, J.Server-Carrio, E.Escriva, L.Soto, J.Garcia-Lozano, A.Sancho, C.R.de Arellano|2013|Polyhedron|50|383|doi:10.1016/j.poly.2012.11.024

Space GroupCrystallography(mu~2~-oxalato)-bis(dimethyl (bis(1H-imidazol-2-yl)methyl)malonate)-di-copper(ii) squarate hexahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 280155: Experimental Crystal Structure Determination

2005

Related Article: H.Nunez, L.Soto, J.Server-Carrio, J.Garcia-Lozano, A.Sancho, R.Acerete, E.Escriva|2005|Inorg.Chem.|44|4644|doi:10.1021/ic048234x

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(2(1H)-Imidazolyl)methylmalonic acid monohydrateExperimental 3D Coordinates
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CCDC 293074: Experimental Crystal Structure Determination

2006

Related Article: L.Soto, N.Ruiz, H.Nunez, J.Server-Carrio, E.Escriva, A.Sancho, J.Garcia-Lozano|2006|Inorg.Chim.Acta|359|3221|doi:10.1016/j.ica.2006.03.039

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(bis((mu~2~-Squarato-OO')-chloro-(bis(imidazol-2-yl)methylaminomethane-NN'))-di-copper(ii) dihydrate)Cell ParametersExperimental 3D Coordinates
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CCDC 886171: Experimental Crystal Structure Determination

2013

Related Article: H.Sanchez, J.Server-Carrio, E.Escriva, L.Soto, J.Garcia-Lozano, A.Sancho, C.R.de Arellano|2013|Polyhedron|50|383|doi:10.1016/j.poly.2012.11.024

Space GroupCrystallographybis(dimethyl (bis(1H-imidazol-2-yl)methyl)malonate)-copper(ii) diperchlorateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 177330: Experimental Crystal Structure Determination

2002

Related Article: Y.Akhriff, J.Server-Carrio, A.Sancho, J.Garcia-Lozano, E.Escriva, L.Soto|2001|Inorg.Chem.|40|6832|doi:10.1021/ic0106571

Space GroupCrystallographycatena-((mu~2~-33-bis(2-Imidazolyl)propionato-NN'O)-(33-bis(2-imidazolyl)propionic acid-NN')-copper(ii) hemikis(squarate) dihydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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