0000000000280416
AUTHOR
Jörg A. Pfänder
MPI-DING reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios
We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Associ…
Geochemistry of ultramafic and mafic rocks from the northern Central Asian Orogenic Belt (Tuva, Central Asia) - constraints on lower and middle arc crust formation linked to late Proterozoic intra-oceanic subduction
Abstract The Agardagh Tes-Chem complex (ATCC) in Tuva, Central Asia (50.5°N, 95°E) exposes a rare mafic to ultramafic crust-mantle fragment that developed within a late Neoproterozoic (~570 Ma) intra-oceanic island arc system that was accreted to the Tuva-Mongolian microcontinent during the formation of the Central Asian Orogenic Belt. Residual mantle rocks (harzburgites and dunites) are highly refractory with high Cr# (0.59–0.83) and intermediate Mg# (0.46–0.52) in spinel and experienced high degrees of total melt extraction (up to 25%). In ultramafic cumulate rocks (wehrlites and pyroxenites), Cr# and Mg# in spinel are distinctly lower (0.22–0.45 and 0.34–0.37), and rare earth element (RE…
Coupled evolution of back-arc and island arc-like mafic crust in the late-Neoproterozoic Agardagh Tes-Chem ophiolite, Central Asia: evidence from trace element and Sr-Nd-Pb isotope data
We report major-element, trace-element and isotopic data of volcanic rocks from the late-Neoproterozoic (570 Ma) Agardagh Tes-Chem ophiolite in Central Asia, south-west of Lake Baikal (50.5°N, 95°E). The majority of samples are high-alumina basalts and basaltic andesites having island-arc affinities. They were derived from an evolved parental magma (Mg#≥0.60, Cr~180 ppm, Ni~95 ppm) by predominantly clinopyroxene fractionation. The parental magma developed from a primary mantle melt by fractionation of about 12% of an olivine+spinel assemblage. The island-arc rocks have high abundances of incompatible trace elements (light rare-earth element abundances up to 100 times chondritic, chondrite-n…